Syntheses and Electronic Behaviors of Novel Networked Alternating Organic Moiety-Ruthenium Hybrid Copolymers

The reaction of ruthenium chloride with organic dithiols gave ruthenium-organic moiety hybrid copolymers. ESR and XPS spectral examinations showed that an electron transfer from the organic moiety to the ruthenium atom took place.

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Bibliographic Details
Published in:	Journal of macromolecular science. Part A, Pure and applied chemistry Vol. 42; no. 10; pp. 1463 - 1468
Main Authors:	Matsui, Hideo, Kawahara, Tetsuro, Kajita, Hideki, Yoshihara, Masakuni
Format:	Journal Article
Language:	English
Published:	Colchester Taylor & Francis Group 01-10-2005 Taylor & Francis
Subjects:	Applied sciences electron transfer Exact sciences and technology hybrid copolymer Inorganic and organomineral polymers Physicochemistry of polymers Preparation ruthenium Solution polycondensation Dithiol Organometallic copolymer Ruthenium compound Experimental study Sulfide copolymer Crosslinked copolymer ruthenium electron transfer Butene sulfide copolymer Morphology Preparation Electron state Olefin sulfide copolymer Alternating copolymer EPR spectrum Ruthenium III Chlorides hybrid copolymer Phenylene sulfide copolymer
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Description
Summary:	The reaction of ruthenium chloride with organic dithiols gave ruthenium-organic moiety hybrid copolymers. ESR and XPS spectral examinations showed that an electron transfer from the organic moiety to the ruthenium atom took place.
Bibliography:	ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23
ISSN:	1060-1325 1520-5738
DOI:	10.1080/10601320500207752