Preliminary study of synthesis gas production from water electrolysis, using the ELECTROFUEL® concept

This paper describes preliminary work on the generation of synthesis gas from water electrolysis using graphite electrodes without the separation of the generated gases. This is an innovative process, that has no similar work been done earlier. Preliminary tests allowed to establish correlations bet...

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Published in:	Energy (Oxford) Vol. 89; pp. 1050 - 1056
Main Authors:	Guerra, L., Gomes, J., Puna, J., Rodrigues, J.
Format:	Journal Article
Language:	English
Published:	Elsevier Ltd 01-09-2015
Subjects:	Alternative energy sources Carbon Electrodes Electrofuel Electrolysis Methanol Methyl alcohol Mountains Product innovation Renewable energy Syngas Synthesis gas Water electrolysis Water electrolysis Electrofuel Renewable energy Syngas Methanol
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Abstract	This paper describes preliminary work on the generation of synthesis gas from water electrolysis using graphite electrodes without the separation of the generated gases. This is an innovative process, that has no similar work been done earlier. Preliminary tests allowed to establish correlations between the applied current to the electrolyser and flow rate and composition of the generated syngas, as well as a characterisation of generated carbon nanoparticles. The obtained syngas can further be used to produce synthetic liquid fuels, for example, methane, methanol or DME (dimethyl ether) in a catalytic reactor, in further stages of a present ongoing project, using the ELECTROFUEL® concept. The main competitive advantage of this project lies in the built-in of an innovative technology product, from RE (renewable energy) power in remote locations, for example, islands, villages in mountains as an alternative for energy storage for mobility constraints. •Generation of synthesis gas from water electrolysis without separation of gases.•Obtained syngas: 7.7% CO; 10.3% O2 and 2.0% CO2.•Syngas can further be used to produce synthetic liquid fuels.
AbstractList	This paper describes preliminary work on the generation of synthesis gas from water electrolysis using graphite electrodes without the separation of the generated gases. This is an innovative process, that has no similar work been done earlier. Preliminary tests allowed to establish correlations between the applied current to the electrolyser and flow rate and composition of the generated syngas, as well as a characterisation of generated carbon nanoparticles. The obtained syngas can further be used to produce synthetic liquid fuels, for example, methane, methanol or DME (dimethyl ether) in a catalytic reactor, in further stages of a present ongoing project, using the ELECTROFUEL(R) concept. The main competitive advantage of this project lies in the built-in of an innovative technology product, from RE (renewable energy) power in remote locations, for example, islands, villages in mountains as an alternative for energy storage for mobility constraints. This paper describes preliminary work on the generation of synthesis gas from water electrolysis using graphite electrodes without the separation of the generated gases. This is an innovative process, that has no similar work been done earlier. Preliminary tests allowed to establish correlations between the applied current to the electrolyser and flow rate and composition of the generated syngas, as well as a characterisation of generated carbon nanoparticles. The obtained syngas can further be used to produce synthetic liquid fuels, for example, methane, methanol or DME (dimethyl ether) in a catalytic reactor, in further stages of a present ongoing project, using the ELECTROFUEL® concept. The main competitive advantage of this project lies in the built-in of an innovative technology product, from RE (renewable energy) power in remote locations, for example, islands, villages in mountains as an alternative for energy storage for mobility constraints. •Generation of synthesis gas from water electrolysis without separation of gases.•Obtained syngas: 7.7% CO; 10.3% O2 and 2.0% CO2.•Syngas can further be used to produce synthetic liquid fuels.
Author	Gomes, J. Rodrigues, J. Guerra, L. Puna, J.
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Cites_doi	10.1016/S0360-3199(97)00109-2 10.1016/j.egypro.2013.06.599 10.1023/A:1003477305336 10.1016/S0378-7753(03)00077-6 10.1016/j.jpowsour.2011.11.080 10.1016/S0378-3820(01)00140-0 10.1016/j.energy.2004.07.004 10.1016/j.ijhydene.2004.01.016 10.1016/S0360-3199(99)00098-1 10.1016/j.cattod.2008.08.039 10.1016/j.energy.2012.08.047 10.1016/j.jpowsour.2007.01.060
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Title	Preliminary study of synthesis gas production from water electrolysis, using the ELECTROFUEL® concept
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