Oxidation of cyclohexane catalyzed by bis-(2-pyridylmethyl)amine Cu(II) complexes

In this work, it is showed the cyclohexane oxidation catalyzed by the copper(II) complexes, [Cu(BMPA)Cl 2] ( 1) and {[Cu(BMPA)Cl 2][Cu(BMPA)(H 2O)Cl] [Cu(BMPA)Cl][CuCl 4]} ( 2), using hydrogen peroxide or tert-butyl hydroperoxide as terminal oxidants and acetonitrile as solvent. Although the complex...

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Bibliographic Details
Published in:	Applied catalysis. A, General Vol. 317; no. 2; pp. 154 - 160
Main Authors:	Silva, Aires C., Fernández, Tatiana Lopez, Carvalho, Nakédia M.F., Herbst, Marcelo H., Bordinhão, Jairo, Jr, Adolfo Horn, Wardell, James L., Oestreicher, Enrique G., Antunes, O.A.C.
Format:	Journal Article
Language:	English
Published:	Amsterdam Elsevier B.V 07-02-2007 Elsevier
Subjects:	Adipic acid Catalysis Chemistry Cu(II) complexes Cu(II) enzymes Cyclic voltammetry Cyclohexanol Cyclohexanone Cyclohexyl hydroperoxide EPR Exact sciences and technology General and physical chemistry Hydrogen peroxide Oxidation pMMO tert-Butyl hydroperoxide Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Cyclic voltammetry Cu(II) complexes Hydrogen peroxide Cyclohexanone Cyclohexyl hydroperoxide EPR Oxidation Cu(II) enzymes pMMO Cyclohexanol Adipic acid tert-Butyl hydroperoxide Catalytic reaction Enzyme EPR spectrometry Hydroperoxide Complexes Heterogeneous catalysis Amine Cyclohexane
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