Thermodynamic Properties of the First-Generation Hybrid Dendrimer with "Carbosilane Core/Phenylene Shell" Structure

The molar heat capacity of the first-generation hybrid dendrimer with a "carbosilane core/phenylene shell" structure was measured for the first time in the temperature range = 6-600 K using a precise adiabatic vacuum calorimeter and DSC. In the above temperature interval, the glass transit...

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Published in:	Entropy (Basel, Switzerland) Vol. 23; no. 12; p. 1557
Main Authors:	Sologubov, Semen S, Markin, Alexey V, Smirnova, Natalia N, Chamkina, Elena S, Krasnova, Irina Yu, Milenin, Sergey A, Serenko, Olga A, Shifrina, Zinaida B, Muzafarov, Aziz M
Format:	Journal Article
Language:	English
Published:	Switzerland MDPI AG 23-11-2021 MDPI
Subjects:	adiabatic calorimetry Catalysis Composite materials Decomposition Dendrimers DSC Enthalpy Entropy of formation glass transition Glass transition temperature Heat heat capacity hybrid dendrimers Investigations Molecular structure Resistance thermometers Specific heat Temperature thermodynamic functions Thermodynamic properties heat capacity adiabatic calorimetry thermodynamic functions hybrid dendrimers glass transition DSC
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Abstract	The molar heat capacity of the first-generation hybrid dendrimer with a "carbosilane core/phenylene shell" structure was measured for the first time in the temperature range = 6-600 K using a precise adiabatic vacuum calorimeter and DSC. In the above temperature interval, the glass transition of the studied compound was observed, and its thermodynamic characteristics were determined. The standard thermodynamic functions (the enthalpy, the entropy, and the Gibbs energy) of the hybrid dendrimer were calculated over the range from = 0 to 600 K using the experimentally determined heat capacity. The standard entropy of formation of the investigated dendrimer was evaluated at = 298.15 K. The obtained thermodynamic properties of the studied hybrid dendrimer were compared and discussed with the literature data for some of the first-generation organosilicon and pyridylphenylene dendrimers.
AbstractList	The molar heat capacity of the first-generation hybrid dendrimer with a "carbosilane core/phenylene shell" structure was measured for the first time in the temperature range T = 6-600 K using a precise adiabatic vacuum calorimeter and DSC. In the above temperature interval, the glass transition of the studied compound was observed, and its thermodynamic characteristics were determined. The standard thermodynamic functions (the enthalpy, the entropy, and the Gibbs energy) of the hybrid dendrimer were calculated over the range from T = 0 to 600 K using the experimentally determined heat capacity. The standard entropy of formation of the investigated dendrimer was evaluated at T = 298.15 K. The obtained thermodynamic properties of the studied hybrid dendrimer were compared and discussed with the literature data for some of the first-generation organosilicon and pyridylphenylene dendrimers. The molar heat capacity of the first-generation hybrid dendrimer with a “carbosilane core/phenylene shell” structure was measured for the first time in the temperature range T = 6–600 K using a precise adiabatic vacuum calorimeter and DSC. In the above temperature interval, the glass transition of the studied compound was observed, and its thermodynamic characteristics were determined. The standard thermodynamic functions (the enthalpy, the entropy, and the Gibbs energy) of the hybrid dendrimer were calculated over the range from T = 0 to 600 K using the experimentally determined heat capacity. The standard entropy of formation of the investigated dendrimer was evaluated at T = 298.15 K. The obtained thermodynamic properties of the studied hybrid dendrimer were compared and discussed with the literature data for some of the first-generation organosilicon and pyridylphenylene dendrimers. The molar heat capacity of the first-generation hybrid dendrimer with a "carbosilane core/phenylene shell" structure was measured for the first time in the temperature range = 6-600 K using a precise adiabatic vacuum calorimeter and DSC. In the above temperature interval, the glass transition of the studied compound was observed, and its thermodynamic characteristics were determined. The standard thermodynamic functions (the enthalpy, the entropy, and the Gibbs energy) of the hybrid dendrimer were calculated over the range from = 0 to 600 K using the experimentally determined heat capacity. The standard entropy of formation of the investigated dendrimer was evaluated at = 298.15 K. The obtained thermodynamic properties of the studied hybrid dendrimer were compared and discussed with the literature data for some of the first-generation organosilicon and pyridylphenylene dendrimers.
Author	Shifrina, Zinaida B Muzafarov, Aziz M Markin, Alexey V Smirnova, Natalia N Chamkina, Elena S Serenko, Olga A Sologubov, Semen S Krasnova, Irina Yu Milenin, Sergey A
AuthorAffiliation	3 Enikolopov Institute of Synthetic Polymeric Materials of Russian Academy of Sciences, 70 Profsoyuznaya St., 117393 Moscow, Russia; cephe@mail.ru 2 Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, 28 Vavilov St., 119334 Moscow, Russia; elena.serkova@ineos.ac.ru (E.S.C.); irina7krasnova@yandex.ru (I.Y.K.); oserenko@yandex.ru (O.A.S.); z_shifrina@yahoo.com (Z.B.S.); aziz@ispm.ru (A.M.M.) 1 Chemistry Department, National Research Lobachevsky State University of Nizhny Novgorod, 23/5 Gagarin Av., 603950 Nizhny Novgorod, Russia; s.slg90@gmail.com (S.S.S.); smirnova@ichem.unn.ru (N.N.S.)
AuthorAffiliation_xml	– name: 1 Chemistry Department, National Research Lobachevsky State University of Nizhny Novgorod, 23/5 Gagarin Av., 603950 Nizhny Novgorod, Russia; s.slg90@gmail.com (S.S.S.); smirnova@ichem.unn.ru (N.N.S.) – name: 3 Enikolopov Institute of Synthetic Polymeric Materials of Russian Academy of Sciences, 70 Profsoyuznaya St., 117393 Moscow, Russia; cephe@mail.ru – name: 2 Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, 28 Vavilov St., 119334 Moscow, Russia; elena.serkova@ineos.ac.ru (E.S.C.); irina7krasnova@yandex.ru (I.Y.K.); oserenko@yandex.ru (O.A.S.); z_shifrina@yahoo.com (Z.B.S.); aziz@ispm.ru (A.M.M.)
Author_xml	– sequence: 1 givenname: Semen S surname: Sologubov fullname: Sologubov, Semen S organization: Chemistry Department, National Research Lobachevsky State University of Nizhny Novgorod, 23/5 Gagarin Av., 603950 Nizhny Novgorod, Russia – sequence: 2 givenname: Alexey V surname: Markin fullname: Markin, Alexey V organization: Chemistry Department, National Research Lobachevsky State University of Nizhny Novgorod, 23/5 Gagarin Av., 603950 Nizhny Novgorod, Russia – sequence: 3 givenname: Natalia N surname: Smirnova fullname: Smirnova, Natalia N organization: Chemistry Department, National Research Lobachevsky State University of Nizhny Novgorod, 23/5 Gagarin Av., 603950 Nizhny Novgorod, Russia – sequence: 4 givenname: Elena S surname: Chamkina fullname: Chamkina, Elena S organization: Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, 28 Vavilov St., 119334 Moscow, Russia – sequence: 5 givenname: Irina Yu surname: Krasnova fullname: Krasnova, Irina Yu organization: Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, 28 Vavilov St., 119334 Moscow, Russia – sequence: 6 givenname: Sergey A orcidid: 0000-0001-6887-3711 surname: Milenin fullname: Milenin, Sergey A organization: Enikolopov Institute of Synthetic Polymeric Materials of Russian Academy of Sciences, 70 Profsoyuznaya St., 117393 Moscow, Russia – sequence: 7 givenname: Olga A orcidid: 0000-0003-4195-8058 surname: Serenko fullname: Serenko, Olga A organization: Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, 28 Vavilov St., 119334 Moscow, Russia – sequence: 8 givenname: Zinaida B surname: Shifrina fullname: Shifrina, Zinaida B organization: Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, 28 Vavilov St., 119334 Moscow, Russia – sequence: 9 givenname: Aziz M orcidid: 0000-0002-3050-3253 surname: Muzafarov fullname: Muzafarov, Aziz M organization: Enikolopov Institute of Synthetic Polymeric Materials of Russian Academy of Sciences, 70 Profsoyuznaya St., 117393 Moscow, Russia
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Cites_doi	10.1016/S0079-6700(00)00011-3 10.1021/cr900327d 10.1134/S0036024418010260 10.1007/978-1-4020-8174-3 10.1134/S0036024417110279 10.1002/adma.200802016 10.1016/S0040-4020(97)00967-8 10.1021/ma051802n 10.1016/S0040-6031(99)00009-X 10.1021/ja01623a024 10.1021/cr990116h 10.1007/978-3-7091-1206-9 10.1021/cr970414j 10.1063/1.1725086 10.1002/adhm.201400291 10.1039/D0CC02486D 10.1021/acs.macromol.0c01453 10.1021/ma300957d 10.1002/anie.199706311 10.1007/978-3-662-06710-9 10.1021/cr500542t 10.1021/cr60135a002 10.1016/j.apsusc.2019.05.141 10.1515/pac-2015-0305 10.1039/a700032d 10.1039/C1NJ20449A 10.1007/s10973-019-08693-9 10.1016/j.polymer.2018.01.047 10.1007/s11172-013-0326-4 10.1016/S0040-6031(97)00066-X 10.1002/cbic.201700079 10.1007/s11172-011-0018-x 10.1006/jcht.1996.0173 10.1007/3-540-46577-4_2 10.1039/C6RA27064F 10.1016/j.jct.2020.106318 10.1021/cm00010a006 10.1002/andp.19123441404 10.1016/j.addr.2012.09.030 10.1002/0470845821 10.1351/pac200678071455 10.1039/c4ra00878b 10.1134/S0036024420020260 10.1021/acs.chemrev.5b00515 10.1070/RC2007v076n08ABEH003671 10.1063/1.1696442 10.1021/cr0103874 10.1007/11603788 10.1039/b309043b 10.1002/3527600612 10.1023/A:1023977916394 10.1017/CBO9781139048859 10.1039/B711745K 10.1016/0040-6031(89)85253-0 10.1021/cr2000724 10.1021/cm502336n
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Keywords	heat capacity adiabatic calorimetry thermodynamic functions hybrid dendrimers glass transition DSC
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References	Hammer (ref_22) 2016; 116 Lebedev (ref_36) 2003; 52 Shifrina (ref_24) 2005; 38 Kaisersberger (ref_50) 1989; 148 Sologubov (ref_40) 2019; 138 Smirnova (ref_37) 2017; 91 Boas (ref_7) 2004; 33 ref_58 Hammer (ref_23) 2017; 18 Serenko (ref_29) 2017; 7 ref_56 ref_11 Sologubov (ref_38) 2018; 92 Carlmark (ref_13) 2009; 38 Rebrov (ref_16) 2012; 45 Miller (ref_18) 1990; 2 Alford (ref_51) 1955; 77 Rajadurai (ref_25) 2007; 76 ref_17 Sologubov (ref_41) 2021; 153 Yang (ref_12) 2015; 115 Frey (ref_15) 2000; 210 Morgenroth (ref_21) 1997; 53 Varushchenko (ref_46) 1997; 29 Adam (ref_52) 1965; 43 Schmaltz (ref_31) 2009; 21 Sabbah (ref_47) 1999; 331 Milenin (ref_35) 2020; 53 Astruc (ref_9) 2010; 110 Morgenroth (ref_20) 1997; 7 Meija (ref_45) 2016; 88 Lebedev (ref_57) 1997; 297 Morgenroth (ref_19) 1997; 36 Serkova (ref_44) 2018; 138 Stangenberg (ref_33) 2015; 4 NSmirnova (ref_43) 2013; 62 Bronstein (ref_26) 2011; 111 Inoue (ref_4) 2000; 25 Nguyen (ref_32) 2012; 36 Markin (ref_39) 2020; 94 Bestul (ref_54) 1964; 40 Smirnova (ref_42) 2011; 60 Svenson (ref_10) 2012; 64 ref_1 Kuchkina (ref_28) 2014; 26 ref_3 Wagner (ref_34) 2020; 56 ref_2 Richardson (ref_49) 2006; 78 ref_48 Debye (ref_55) 1912; 344 Grayson (ref_5) 2001; 101 Kamer (ref_6) 2002; 102 ref_8 Kauzmann (ref_53) 1948; 43 Majoral (ref_14) 1999; 99 Kuchkina (ref_27) 2014; 4 Sorokina (ref_30) 2019; 488
References_xml	– volume: 25 start-page: 453 year: 2000 ident: ref_4 article-title: Functional dendrimers, hyperbranched and star polymers publication-title: Prog. Polym. Sci. doi: 10.1016/S0079-6700(00)00011-3 contributor: fullname: Inoue – volume: 110 start-page: 1857 year: 2010 ident: ref_9 article-title: Dendrimers Designed for Functions: From Physical, Photophysical, and Supramolecular Properties to Applications in Sensing, Catalysis, Molecular Electronics, Photonics, and Nanomedicine publication-title: Chem. Rev. doi: 10.1021/cr900327d contributor: fullname: Astruc – volume: 92 start-page: 235 year: 2018 ident: ref_38 article-title: Thermodynamic properties of a first-generation carbosilane dendrimer with terminal phenylethyl groups publication-title: Russ. J. Phys. Chem. A doi: 10.1134/S0036024418010260 contributor: fullname: Sologubov – ident: ref_17 doi: 10.1007/978-1-4020-8174-3 – volume: 91 start-page: 2317 year: 2017 ident: ref_37 article-title: Thermodynamic properties of first- and third-generation carbosilane dendrimers with terminal phenyldioxolane groups publication-title: Russ. J. Phys. Chem. A doi: 10.1134/S0036024417110279 contributor: fullname: Smirnova – volume: 21 start-page: 1067 year: 2009 ident: ref_31 article-title: Polyphenylene-based materials: Control of the electronic function by molecular and supramolecular complexity publication-title: Adv. Mater. doi: 10.1002/adma.200802016 contributor: fullname: Schmaltz – ident: ref_58 – volume: 53 start-page: 15349 year: 1997 ident: ref_21 article-title: Dendritic and hyperbranched polyphenylenes via a simple Diels–Alder route publication-title: Tetrahedron doi: 10.1016/S0040-4020(97)00967-8 contributor: fullname: Morgenroth – volume: 38 start-page: 9920 year: 2005 ident: ref_24 article-title: Poly(phenylene-pyridyl) dendrimers: Synthesis and templating of metal nanoparticles publication-title: Macromolecules doi: 10.1021/ma051802n contributor: fullname: Shifrina – volume: 331 start-page: 93 year: 1999 ident: ref_47 article-title: Reference materials for calorimetry and differential thermal analysis publication-title: Thermochim. Acta doi: 10.1016/S0040-6031(99)00009-X contributor: fullname: Sabbah – volume: 77 start-page: 4774 year: 1955 ident: ref_51 article-title: Specific heat of synthetic high polymers. VI. A study of the glass transition in polyvinyl chloride publication-title: J. Am. Chem. Soc. doi: 10.1021/ja01623a024 contributor: fullname: Alford – ident: ref_56 – volume: 101 start-page: 3819 year: 2001 ident: ref_5 article-title: Convergent dendrons and dendrimers: From synthesis to applications publication-title: Chem. Rev. doi: 10.1021/cr990116h contributor: fullname: Grayson – ident: ref_11 doi: 10.1007/978-3-7091-1206-9 – volume: 99 start-page: 845 year: 1999 ident: ref_14 article-title: Dendrimers Containing Heteroatoms (Si, P, B, Ge, or Bi) publication-title: Chem. Rev. doi: 10.1021/cr970414j contributor: fullname: Majoral – volume: 40 start-page: 3731 year: 1964 ident: ref_54 article-title: Excess Entropy at Glass Transformation publication-title: J. Chem. Phys. doi: 10.1063/1.1725086 contributor: fullname: Bestul – volume: 4 start-page: 377 year: 2015 ident: ref_33 article-title: A polyphenylene dendrimer drug transporter with precisely positioned amphiphilic surface patches publication-title: Adv. Healthc. Mater. doi: 10.1002/adhm.201400291 contributor: fullname: Stangenberg – volume: 56 start-page: 8663 year: 2020 ident: ref_34 article-title: Amphiphilic dendrimers control protein binding and corona formation on liposome nanocarriers publication-title: Chem. Commun. doi: 10.1039/D0CC02486D contributor: fullname: Wagner – volume: 53 start-page: 9706 year: 2020 ident: ref_35 article-title: Influence of the growing flexible shell on the molecular behavior of hybrid dendrimers publication-title: Macromolecules doi: 10.1021/acs.macromol.0c01453 contributor: fullname: Milenin – volume: 45 start-page: 8796 year: 2012 ident: ref_16 article-title: Synthesis of carbosilane dendrimers with variable distance between branching nodes publication-title: Macromolecules doi: 10.1021/ma300957d contributor: fullname: Rebrov – volume: 36 start-page: 631 year: 1997 ident: ref_19 article-title: Polyphenylene dendrimers: From three-dimensional to two-dimensional structures publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.199706311 contributor: fullname: Morgenroth – ident: ref_48 doi: 10.1007/978-3-662-06710-9 – volume: 115 start-page: 5274 year: 2015 ident: ref_12 article-title: Surface-Engineered Dendrimers in Gene Delivery publication-title: Chem. Rev. doi: 10.1021/cr500542t contributor: fullname: Yang – volume: 43 start-page: 219 year: 1948 ident: ref_53 article-title: The Nature of the Glassy State and the Behavior of Liquids at Low Temperatures publication-title: Chem. Rev. doi: 10.1021/cr60135a002 contributor: fullname: Kauzmann – volume: 488 start-page: 865 year: 2019 ident: ref_30 article-title: Pyridylphenylene dendrons immobilized on the surface of chemically modified magnetic silica as efficient stabilizing molecules of Pd species publication-title: Appl. Surf. Sci. doi: 10.1016/j.apsusc.2019.05.141 contributor: fullname: Sorokina – volume: 88 start-page: 265 year: 2016 ident: ref_45 article-title: Atomic weights of the elements 2013 (IUPAC Technical Report) publication-title: Pure Appl. Chem. doi: 10.1515/pac-2015-0305 contributor: fullname: Meija – volume: 7 start-page: 1207 year: 1997 ident: ref_20 article-title: Nanosized polyphenylene dendrimers based upon pentaphenylbenzene units publication-title: J. Mater. Chem. doi: 10.1039/a700032d contributor: fullname: Morgenroth – volume: 36 start-page: 282 year: 2012 ident: ref_32 article-title: Uniquely versatile: Nano-site defined materials based on polyphenylene dendrimers publication-title: New J. Chem. doi: 10.1039/C1NJ20449A contributor: fullname: Nguyen – volume: 138 start-page: 3301 year: 2019 ident: ref_40 article-title: Calorimetric study of siloxane dendrimer of the third generation with trimethylsilyl terminal groups publication-title: J. Therm. Anal. Calorim. doi: 10.1007/s10973-019-08693-9 contributor: fullname: Sologubov – volume: 138 start-page: 83 year: 2018 ident: ref_44 article-title: Core/shell hybrid dendrimers: Controllable rigidity determines molecular behaviour publication-title: Polymer doi: 10.1016/j.polymer.2018.01.047 contributor: fullname: Serkova – volume: 62 start-page: 2258 year: 2013 ident: ref_43 article-title: Thermodynamics of hard poly(phenylene-pyridyl) dendrimers publication-title: Russ. Chem. Bull. doi: 10.1007/s11172-013-0326-4 contributor: fullname: NSmirnova – volume: 297 start-page: 143 year: 1997 ident: ref_57 article-title: Application of precise calorimetry in study of polymers and polymerization processes publication-title: Thermochim. Acta doi: 10.1016/S0040-6031(97)00066-X contributor: fullname: Lebedev – volume: 18 start-page: 960 year: 2017 ident: ref_23 article-title: Controlling cellular uptake and toxicity of polyphenylene dendrimers by chemical functionalization publication-title: ChemBioChem doi: 10.1002/cbic.201700079 contributor: fullname: Hammer – volume: 60 start-page: 132 year: 2011 ident: ref_42 article-title: Thermodynamic properties of pyridine-containing polyphenylene dendrimers of the first–fourth generations publication-title: Russ. Chem. Bull. doi: 10.1007/s11172-011-0018-x contributor: fullname: Smirnova – volume: 29 start-page: 623 year: 1997 ident: ref_46 article-title: Low-temperature heat capacity of 1-bromoperfluorooctane publication-title: J. Chem. Thermodyn. doi: 10.1006/jcht.1996.0173 contributor: fullname: Varushchenko – volume: 210 start-page: 69 year: 2000 ident: ref_15 article-title: Silicon-based dendrimers publication-title: Top. Curr. Chem. doi: 10.1007/3-540-46577-4_2 contributor: fullname: Frey – volume: 7 start-page: 7870 year: 2017 ident: ref_29 article-title: Adsorption properties of pyridylphenylene dendrimers publication-title: RSC Adv. doi: 10.1039/C6RA27064F contributor: fullname: Serenko – volume: 153 start-page: 106318 year: 2021 ident: ref_41 article-title: Thermodynamic investigation of G2 and G4 siloxane dendrimers with trimethylsilyl terminal groups publication-title: J. Chem. Thermodyn. doi: 10.1016/j.jct.2020.106318 contributor: fullname: Sologubov – volume: 2 start-page: 346 year: 1990 ident: ref_18 article-title: Convergent synthesis of monodisperse dendrimers based upon 1,3,5-trisubstituted benzenes publication-title: Chem. Mater. doi: 10.1021/cm00010a006 contributor: fullname: Miller – volume: 344 start-page: 789 year: 1912 ident: ref_55 article-title: Zur Theorie der spezifischen Wärmen publication-title: Ann. Phys. doi: 10.1002/andp.19123441404 contributor: fullname: Debye – volume: 64 start-page: 102 year: 2012 ident: ref_10 article-title: Dendrimers in biomedical applications—Reflections on the field publication-title: Adv. Drug Deliv. Rev. doi: 10.1016/j.addr.2012.09.030 contributor: fullname: Svenson – ident: ref_1 doi: 10.1002/0470845821 – volume: 78 start-page: 1455 year: 2006 ident: ref_49 article-title: Standards, calibration, and guidelines in microcalorimetry. Part 2. Calibration standards for differential scanning calorimetry (IUPAC Technical Report) publication-title: Pure Appl. Chem. doi: 10.1351/pac200678071455 contributor: fullname: Richardson – volume: 4 start-page: 23271 year: 2014 ident: ref_27 article-title: Bronstein, Magnetically recoverable catalysts based on polyphenylenepyridyl dendrons and dendrimers publication-title: RSC Adv. doi: 10.1039/c4ra00878b contributor: fullname: Kuchkina – volume: 94 start-page: 240 year: 2020 ident: ref_39 article-title: Thermodynamic properties of a first-generation siloxane dendrimer with terminal trimethylsilyl groups publication-title: Russ. J. Phys. Chem. A doi: 10.1134/S0036024420020260 contributor: fullname: Markin – volume: 116 start-page: 2103 year: 2016 ident: ref_22 article-title: Dimensional evolution of polyphenylenes: Expanding in all directions publication-title: Chem. Rev. doi: 10.1021/acs.chemrev.5b00515 contributor: fullname: Hammer – volume: 76 start-page: 767 year: 2007 ident: ref_25 article-title: Rigid aromatic dendrimers publication-title: Russ. Chem. Rev. doi: 10.1070/RC2007v076n08ABEH003671 contributor: fullname: Rajadurai – volume: 43 start-page: 139 year: 1965 ident: ref_52 article-title: On the Temperature Dependence of Cooperative Relaxation Properties in Glass-Forming Liquids publication-title: J. Chem. Phys. doi: 10.1063/1.1696442 contributor: fullname: Adam – volume: 102 start-page: 3717 year: 2002 ident: ref_6 article-title: Dendrimers as support for recoverable catalysts and reagents publication-title: Chem. Rev. doi: 10.1021/cr0103874 contributor: fullname: Kamer – ident: ref_8 doi: 10.1007/11603788 – volume: 33 start-page: 43 year: 2004 ident: ref_7 article-title: Dendrimers in drug research publication-title: Chem. Soc. Rev. doi: 10.1039/b309043b contributor: fullname: Boas – ident: ref_2 doi: 10.1002/3527600612 – volume: 52 start-page: 545 year: 2003 ident: ref_36 article-title: Thermodynamic properties of the first to fifth generations of carbosilane dendrimers with allyl terminal groups publication-title: Russ. Chem. Bull. doi: 10.1023/A:1023977916394 contributor: fullname: Lebedev – ident: ref_3 doi: 10.1017/CBO9781139048859 – volume: 38 start-page: 352 year: 2009 ident: ref_13 article-title: New methodologies in the construction of dendritic materials publication-title: Chem. Soc. Rev. doi: 10.1039/B711745K contributor: fullname: Carlmark – volume: 148 start-page: 499 year: 1989 ident: ref_50 article-title: A heat flux DSC for enthalpy and specific heat determinations to 1700 K publication-title: Thermochim. Acta doi: 10.1016/0040-6031(89)85253-0 contributor: fullname: Kaisersberger – volume: 111 start-page: 5301 year: 2011 ident: ref_26 article-title: Dendrimers as encapsulating, stabilizing, or directing agents for inorganic nanoparticles publication-title: Chem. Rev. doi: 10.1021/cr2000724 contributor: fullname: Bronstein – volume: 26 start-page: 5654 year: 2014 ident: ref_28 article-title: Hydrophobic periphery tails of polyphenylenepyridyl dendrons control nanoparticle formation and catalytic properties publication-title: Chem. Mater. doi: 10.1021/cm502336n contributor: fullname: Kuchkina
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Snippet	The molar heat capacity of the first-generation hybrid dendrimer with a "carbosilane core/phenylene shell" structure was measured for the first time in the... The molar heat capacity of the first-generation hybrid dendrimer with a “carbosilane core/phenylene shell” structure was measured for the first time in the...
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SubjectTerms	adiabatic calorimetry Catalysis Composite materials Decomposition Dendrimers DSC Enthalpy Entropy of formation glass transition Glass transition temperature Heat heat capacity hybrid dendrimers Investigations Molecular structure Resistance thermometers Specific heat Temperature thermodynamic functions Thermodynamic properties
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Title	Thermodynamic Properties of the First-Generation Hybrid Dendrimer with "Carbosilane Core/Phenylene Shell" Structure
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