Novel structures by microlayer coextrusion-talc-filled PP, PC/SAN, and HDPE/LLDPE

Numerous examples in the literature illustrate how the coextrusion of film with three or more polymeric layers is economically used to achieve a desirable mix of end‐use characteristics. More recently, layer‐multiplying devices permit two polymers of widely dissimilar solid‐state properties to be co...

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Published in:	Polymer engineering and science Vol. 37; no. 2; pp. 355 - 362
Main Authors:	Mueller, Chad D., Nazarenko, Sergei, Ebeling, Thomas, Schuman, Thomas L., Hiltner, Anne, Baer, Eric
Format:	Journal Article
Language:	English
Published:	Hoboken Wiley Subscription Services, Inc., A Wiley Company 01-02-1997 Wiley Subscription Services Society of Plastics Engineers, Inc Blackwell Publishing Ltd
Subjects:	Acrylonitrile Analysis Applied sciences Exact sciences and technology Extrusion Extrusion moulding Machinery and processing Moulding Plastics Polycarbonates Polyethylene Polymer industry, paints, wood Polypropylene Styrene Technology of polymers Acrylonitrile copolymer Low density ethylene polymer Multilayer Coextrusion molding Propylene polymer High density ethylene polymer Interdiffusion Polycarbonate Operating conditions Styrene copolymer
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Abstract	Numerous examples in the literature illustrate how the coextrusion of film with three or more polymeric layers is economically used to achieve a desirable mix of end‐use characteristics. More recently, layer‐multiplying devices permit two polymers of widely dissimilar solid‐state properties to be combined into unique microlayer and nanolayer structures with hundreds or thousands of alternating layers. If the layers are thin enough, the key properties of the constituents can combine synergistically. The microlayer structure is also an effective research tool. Because the microlayer and nanolayer structures contain large specific interfacial areas, they are ideal for fundamental studies of phenomena such as interdiffusion and adhesion. Three examples of microlayered materials with up to 1024 layers illustrate the versatility of this coextrusion process: talc‐filled PP, PC/SAN, and HDPE/LLDPE.
AbstractList	Numerous examples in the literature illustrate how the coextrusion of film with three or more polymeric layers is economically used to achieve a desirable mix of end‐use characteristics. More recently, layer‐multiplying devices permit two polymers of widely dissimilar solid‐state properties to be combined into unique microlayer and nanolayer structures with hundreds or thousands of alternating layers. If the layers are thin enough, the key properties of the constituents can combine synergistically. The microlayer structure is also an effective research tool. Because the microlayer and nanolayer structures contain large specific interfacial areas, they are ideal for fundamental studies of phenomena such as interdiffusion and adhesion. Three examples of microlayered materials with up to 1024 layers illustrate the versatility of this coextrusion process: talc‐filled PP, PC/SAN, and HDPE/LLDPE. Numerous examples in the literature illustrate how the coextrusion of film with three or more polymeric layers is economically used to achieve a desirable mix of end-use characteristics. More recently, layer-multiplying devices permit two polymers of widely dissimilar solid-state properties to be combined into unique micro-layer and nanolayer structures with hundreds or thousands of alternating layers. If the layers are thin enough, the key properties of the constituents can combine synergistically. The microlayer structure is also an effective research tool. Because the microlayer and nanolayer structures contain large specific interfacial areas, they are ideal for fundamental studies of phenomena such as interdiffusion and adhesion. Three examples of microlayered materials with up to 1024 layers illustrate the versatility of this coextrusion process: talc-filled PP, PC/SAN, and HDPE/LLDPE.
Audience	Academic
Author	Nazarenko, Sergei Mueller, Chad D. Ebeling, Thomas Baer, Eric Schuman, Thomas L. Hiltner, Anne
Author_xml	– sequence: 1 givenname: Chad D. surname: Mueller fullname: Mueller, Chad D. organization: Department of Macromolecular Science and Center for Applied Polymer Research (CAPRI), Case Western Reserve University, Cleveland, Ohio 44106-7202 – sequence: 2 givenname: Sergei surname: Nazarenko fullname: Nazarenko, Sergei organization: Department of Macromolecular Science and Center for Applied Polymer Research (CAPRI), Case Western Reserve University, Cleveland, Ohio 44106-7202 – sequence: 3 givenname: Thomas surname: Ebeling fullname: Ebeling, Thomas organization: Department of Macromolecular Science and Center for Applied Polymer Research (CAPRI), Case Western Reserve University, Cleveland, Ohio 44106-7202 – sequence: 4 givenname: Thomas L. surname: Schuman fullname: Schuman, Thomas L. organization: Department of Macromolecular Science and Center for Applied Polymer Research (CAPRI), Case Western Reserve University, Cleveland, Ohio 44106-7202 – sequence: 5 givenname: Anne surname: Hiltner fullname: Hiltner, Anne organization: Department of Macromolecular Science and Center for Applied Polymer Research (CAPRI), Case Western Reserve University, Cleveland, Ohio 44106-7202 – sequence: 6 givenname: Eric surname: Baer fullname: Baer, Eric organization: Department of Macromolecular Science and Center for Applied Polymer Research (CAPRI), Case Western Reserve University, Cleveland, Ohio 44106-7202
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Keywords	Acrylonitrile copolymer Low density ethylene polymer Multilayer Coextrusion molding Propylene polymer High density ethylene polymer Interdiffusion Polycarbonate Operating conditions Styrene copolymer
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Snippet	Numerous examples in the literature illustrate how the coextrusion of film with three or more polymeric layers is economically used to achieve a desirable mix...
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SubjectTerms	Acrylonitrile Analysis Applied sciences Exact sciences and technology Extrusion Extrusion moulding Machinery and processing Moulding Plastics Polycarbonates Polyethylene Polymer industry, paints, wood Polypropylene Styrene Technology of polymers
Title	Novel structures by microlayer coextrusion-talc-filled PP, PC/SAN, and HDPE/LLDPE
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