Isolation and Characterization of the Homoleptic Nickel(I) and Nickel(II) Bis‐benzene Sandwich Cations

A stable salt of the metalloradical [Ni(C6H6)2]+ hitherto unknown in the condensed phase was synthesized from [Ni(CO)4]+[WCA]− and benzene ([WCA]−=[F{Al(ORF)3}2]−; RF=C(CF3)3). Single crystal XRD reveals a remarkable asymmetrically η3,η6‐slipped sandwich structure. The magnetic properties of the [Ni...

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Bibliographic Details
Published in:	Angewandte Chemie International Edition Vol. 61; no. 50; pp. e202211555 - n/a
Main Authors:	Schmitt, Manuel, Mayländer, Maximilian, Heizmann, Tim, Richert, Sabine, Bülow, Christine, Hirsch, Konstantin, Zamudio‐Bayer, Vicente, Lau, J. Tobias, Krossing, Ingo
Format:	Journal Article
Language:	English
Published:	Germany Wiley Subscription Services, Inc 12-12-2022 John Wiley and Sons Inc
Edition:	International ed. in English
Subjects:	Arene Ligands Benzene Cations Communication Communications Magnetic properties Nickel Nickel carbonyl NMR Nuclear magnetic resonance Oxidation Sandwich Complexes Sandwich structures Single crystals Transition Metals Vapor phases Weakly Coordinating Anion (WCA) Weakly Coordinating Anion (WCA) Nickel Transition Metals Sandwich Complexes Arene Ligands
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