Adsorption of lead from aqueous solution onto coir-pith activated carbon

• Published in: Desalination and water treatment Vol. 51; no. 13-15; pp. 2529 - 2535
• Main Authors: Kumar, Pradeep, Rao, Ramamohan, Chand, Shri, Kumar, Sushil, Wasewar, K.L., Yoo, Chang Kyoo
• Format: Journal Article
• Language: English
• Published: L'Aquila Elsevier Inc 01-03-2013; Desalination Publications
• Subjects: Adsorption; Agriculture, rearing and food industries wastes; Applied sciences; Aqueous solutions; Carbon; Contact; Endothermic reactions; Exact sciences and technology; Industrial wastewaters; Isotherms; Kinetics; Lead; Lead (metal); Mathematical analysis; Pith activated carbon; Pollution; Spontaneous; Thermodynamics; Wastes; Wastewaters; Water treatment and pollution; Asia; India; Lead; Pith activated carbon; Thermodynamics; Kinetics; Adsorption; Isotherms; Organic waste; Water treatment; Coconut; Biomass; Mutagen; Sustainable development; Upgrading; Activated carbon; Agricultural waste; Liquid solid adsorption; Heavy metal; Vegetal waste; Waste management; Trace element; Industrial waste water; Waste reuse; Physicochemical purification; Waste water purification; Resource management
• ISSN: 1944-3986; 1944-3994; 1944-3986
• DOI: 10.1080/19443994.2012.749009

Adsorption of lead (Pb(II)) from aqueous solution using H2SO4-activated carbon developed from coir pith (CPAC) was studied. Batch experiments were performed to explain the effect of initial pH (pH0), contact time, adsorbent dose, and temperature on adsorption. A pH0 of 5.0, a dose of 1 g L-1 for adsorption at a concentration of Pb of 20 mg L-1 were the optimal conditions. The adsorption of lead onto CPAC was found to be a gradual process and the quasi-equilibrium condition reached in 4 h. The adsorption followed pseudo-second-order kinetics and the adsorption equilibrium followed the Temkin isotherm. Thermodynamic parameters such as ΔG0, ΔH0, and ΔS0 were evaluated by applying the Arrhenius and Van’t Hoff equations, and it was found that adsorption of Pb(II) on CPAC was spontaneous and endothermic.