Stabilisation of oil-in-water emulsions with non-chemical modified gelatinised starch

In this research, stabilisation of oil-in-water emulsions with non-chemically modified gelatinised starch is presented. Thus far only octenyl succinic anhydride (OSA) modified gelatinised starch has been known to adsorb at emulsion droplet interfaces, acting as emulsifiers. Screening a range of comm...

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Published in:Food hydrocolloids Vol. 81; pp. 409 - 418
Main Authors: Kasprzak, Miroslaw M., Macnaughtan, William, Harding, Stephen, Wilde, Peter, Wolf, Bettina
Format: Journal Article
Language:English
Published: United States Elsevier Ltd 01-08-2018
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Abstract In this research, stabilisation of oil-in-water emulsions with non-chemically modified gelatinised starch is presented. Thus far only octenyl succinic anhydride (OSA) modified gelatinised starch has been known to adsorb at emulsion droplet interfaces, acting as emulsifiers. Screening a range of commercially available food starches revealed that a non-waxy rice starch, a waxy rice starch and the waxy maize starch PRIMA600 showed oil-in-water emulsifying ability following gelatinisation. The microstructure of emulsions formulated with 20% oil and 1% starch was stable for at least 3 months. Thermal, crystallinity and molecular property analyses as well as amylose and protein content revealed no obvious link to this property. Nevertheless, this research has provided the food industry with exciting results for the formulation of clean label emulsions. Moreover, it presents a concept for oral release food emulsions with destabilisation via salivary amylase digestion of the stabilising starch emulsifier. [Display omitted] •Non-chemically modified gelatinised starches screened for emulsifier functionality.•High shear overhead processing of oil-in-water emulsions.•A waxy & non-waxy rice & waxy maize starch adsorbed at oil droplets, others did not.•Not related to thermal, crystallinity & molecular properties, amylose, protein.•Functionality as clean label emulsifier clearly demonstrated.
AbstractList In this research, stabilisation of oil-in-water emulsions with non-chemically modified gelatinised starch is presented. Thus far only octenyl succinic anhydride (OSA) modified gelatinised starch has been known to adsorb at emulsion droplet interfaces, acting as emulsifiers. Screening a range of commercially available food starches revealed that a non-waxy rice starch, a waxy rice starch and the waxy maize starch PRIMA600 showed oil-in-water emulsifying ability following gelatinisation. The microstructure of emulsions formulated with 20% oil and 1% starch was stable for at least 3 months. Thermal, crystallinity and molecular property analyses as well as amylose and protein content revealed no obvious link to this property. Nevertheless, this research has provided the food industry with exciting results for the formulation of clean label emulsions. Moreover, it presents a concept for oral release food emulsions with destabilisation via salivary amylase digestion of the stabilising starch emulsifier. [Display omitted] •Non-chemically modified gelatinised starches screened for emulsifier functionality.•High shear overhead processing of oil-in-water emulsions.•A waxy & non-waxy rice & waxy maize starch adsorbed at oil droplets, others did not.•Not related to thermal, crystallinity & molecular properties, amylose, protein.•Functionality as clean label emulsifier clearly demonstrated.
In this research, stabilisation of oil-in-water emulsions with non-chemically modified gelatinised starch is presented. Thus far only octenyl succinic anhydride (OSA) modified gelatinised starch has been known to adsorb at emulsion droplet interfaces, acting as emulsifiers. Screening a range of commercially available food starches revealed that a non-waxy rice starch, a waxy rice starch and the waxy maize starch PRIMA600 showed oil-in-water emulsifying ability following gelatinisation. The microstructure of emulsions formulated with 20% oil and 1% starch was stable for at least 3 months. Thermal, crystallinity and molecular property analyses as well as amylose and protein content revealed no obvious link to this property. Nevertheless, this research has provided the food industry with exciting results for the formulation of clean label emulsions. Moreover, it presents a concept for oral release food emulsions with destabilisation via salivary amylase digestion of the stabilising starch emulsifier.
In this research, stabilisation of oil-in-water emulsions with non-chemically modified gelatinised starch is presented. Thus far only octenyl succinic anhydride (OSA) modified gelatinised starch has been known to adsorb at emulsion droplet interfaces, acting as emulsifiers. Screening a range of commercially available food starches revealed that a non-waxy rice starch, a waxy rice starch and the waxy maize starch PRIMA600 showed oil-in-water emulsifying ability following gelatinisation. The microstructure of emulsions formulated with 20% oil and 1% starch was stable for at least 3 months. Thermal, crystallinity and molecular property analyses as well as amylose and protein content revealed no obvious link to this property. Nevertheless, this research has provided the food industry with exciting results for the formulation of clean label emulsions. Moreover, it presents a concept for oral release food emulsions with destabilisation via salivary amylase digestion of the stabilising starch emulsifier. Image 1 • Non-chemically modified gelatinised starches screened for emulsifier functionality. • High shear overhead processing of oil-in-water emulsions. • A waxy & non-waxy rice & waxy maize starch adsorbed at oil droplets, others did not. • Not related to thermal, crystallinity & molecular properties, amylose, protein. • Functionality as clean label emulsifier clearly demonstrated.
Author Wolf, Bettina
Kasprzak, Miroslaw M.
Wilde, Peter
Macnaughtan, William
Harding, Stephen
AuthorAffiliation a School of Biosciences, University of Nottingham, Sutton Bonington, Loughborough, LE12 5RD, UK
b Quadram Institute Bioscience, Norwich Research Park, Colney, Norwich, NR4 7UA, UK
AuthorAffiliation_xml – name: a School of Biosciences, University of Nottingham, Sutton Bonington, Loughborough, LE12 5RD, UK
– name: b Quadram Institute Bioscience, Norwich Research Park, Colney, Norwich, NR4 7UA, UK
Author_xml – sequence: 1
  givenname: Miroslaw M.
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  organization: School of Biosciences, University of Nottingham, Sutton Bonington, Loughborough, LE12 5RD, UK
– sequence: 2
  givenname: William
  surname: Macnaughtan
  fullname: Macnaughtan, William
  organization: School of Biosciences, University of Nottingham, Sutton Bonington, Loughborough, LE12 5RD, UK
– sequence: 3
  givenname: Stephen
  surname: Harding
  fullname: Harding, Stephen
  organization: School of Biosciences, University of Nottingham, Sutton Bonington, Loughborough, LE12 5RD, UK
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  surname: Wolf
  fullname: Wolf, Bettina
  email: Bettina.Wolf@nottingham.ac.uk
  organization: School of Biosciences, University of Nottingham, Sutton Bonington, Loughborough, LE12 5RD, UK
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Keywords OSA starch
Emulsion
Stability
Sedimentation coefficient
Non-chemically modified gelatinised starch
Language English
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This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
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Snippet In this research, stabilisation of oil-in-water emulsions with non-chemically modified gelatinised starch is presented. Thus far only octenyl succinic...
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SubjectTerms Emulsion
Non-chemically modified gelatinised starch
OSA starch
Sedimentation coefficient
Stability
Title Stabilisation of oil-in-water emulsions with non-chemical modified gelatinised starch
URI https://dx.doi.org/10.1016/j.foodhyd.2018.03.002
https://www.ncbi.nlm.nih.gov/pubmed/30078926
https://search.proquest.com/docview/2084338797
https://pubmed.ncbi.nlm.nih.gov/PMC5899762
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