Post-spinning modification of electrospun nanofiber nanocomposite from Bombyx mori silk and carbon nanotubes

Electrospinning is an effective procedure for fabricating submicron to nanoscale fibers from synthetic polymer as well as natural proteins. We successfully electrospun regenerated silk protein from cocoons of Bombyx mori to produce random as well as aligned fibers with diameter less than 100nm. The...

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Published in:Polymer (Guilford) Vol. 50; no. 8; pp. 1918 - 1924
Main Authors: Gandhi, Milind, Yang, Heejae, Shor, Lauren, Ko, Frank
Format: Journal Article
Language:English
Published: Kidlington Elsevier Ltd 09-04-2009
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Abstract Electrospinning is an effective procedure for fabricating submicron to nanoscale fibers from synthetic polymer as well as natural proteins. We successfully electrospun regenerated silk protein from cocoons of Bombyx mori to produce random as well as aligned fibers with diameter less than 100nm. The fibers were characterized using field emission environmental scanning electron microscope (ESEM), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy and wide angle X-ray diffraction (WAXD) studies. Post-spinning treatment with methanol and/or stretching and co-electrospinning with single walled carbon nanotubes (CNT) were carried out to alter the strength, toughness, crystallinity and conductivity of silk nanofibers. Addition of just 1% CNT along with post-spinning treatments resulted in 7-fold increase in the strength and 35-fold increase in the modulus of silk nanofibers. Raman spectroscopy confirmed that CNTs were incorporated in the silk fibers. FT-IR spectroscopy and WAXD studies proved that silk–CNT nanofibers had more crystallinity compared to silk nanofibers without CNT. Four-probe method demonstrated that silk–CNT nanofibers had 4 times higher electrical conductivity compared to silk nanofibers without CNT. [Display omitted]
AbstractList Electrospinning is an effective procedure for fabricating submicron to nanoscale fibers from synthetic polymer as well as natural proteins. We successfully electrospun regenerated silk protein from cocoons of Bombyx mori to produce random as well as aligned fibers with diameter less than 100 nm. The fibers were characterized using field emission environmental scanning electron microscope (ESEM), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy and wide angle X-ray diffraction (WAXD) studies. Post-spinning treatment with methanol and/or stretching and co-electrospinning with single walled carbon nanotubes (CNT) were carried out to alter the strength, toughness, crystallinity and conductivity of silk nanofibers. Addition of just 1% CNT along with post-spinning treatments resulted in 7-fold increase in the strength and 35-fold increase in the modulus of silk nanofibers. Raman spectroscopy confirmed that CNTs were incorporated in the silk fibers. FT-IR spectroscopy and WAXD studies proved that silk-CNT nanofibers had more crystallinity compared to silk nanofibers without CNT. Four-probe method demonstrated that silk-CNT nanofibers had 4 times higher electrical conductivity compared to silk nanofibers without CNT.
Electrospinning is an effective procedure for fabricating submicron to nanoscale fibers from synthetic polymer as well as natural proteins. We successfully electrospun regenerated silk protein from cocoons of Bombyx mori to produce random as well as aligned fibers with diameter less than 100nm. The fibers were characterized using field emission environmental scanning electron microscope (ESEM), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy and wide angle X-ray diffraction (WAXD) studies. Post-spinning treatment with methanol and/or stretching and co-electrospinning with single walled carbon nanotubes (CNT) were carried out to alter the strength, toughness, crystallinity and conductivity of silk nanofibers. Addition of just 1% CNT along with post-spinning treatments resulted in 7-fold increase in the strength and 35-fold increase in the modulus of silk nanofibers. Raman spectroscopy confirmed that CNTs were incorporated in the silk fibers. FT-IR spectroscopy and WAXD studies proved that silk-CNT nanofibers had more crystallinity compared to silk nanofibers without CNT. Four-probe method demonstrated that silk-CNT nanofibers had 4 times higher electrical conductivity compared to silk nanofibers without CNT.
Electrospinning is an effective procedure for fabricating submicron to nanoscale fibers from synthetic polymer as well as natural proteins. We successfully electrospun regenerated silk protein from cocoons of Bombyx mori to produce random as well as aligned fibers with diameter less than 100nm. The fibers were characterized using field emission environmental scanning electron microscope (ESEM), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy and wide angle X-ray diffraction (WAXD) studies. Post-spinning treatment with methanol and/or stretching and co-electrospinning with single walled carbon nanotubes (CNT) were carried out to alter the strength, toughness, crystallinity and conductivity of silk nanofibers. Addition of just 1% CNT along with post-spinning treatments resulted in 7-fold increase in the strength and 35-fold increase in the modulus of silk nanofibers. Raman spectroscopy confirmed that CNTs were incorporated in the silk fibers. FT-IR spectroscopy and WAXD studies proved that silk–CNT nanofibers had more crystallinity compared to silk nanofibers without CNT. Four-probe method demonstrated that silk–CNT nanofibers had 4 times higher electrical conductivity compared to silk nanofibers without CNT. [Display omitted]
Author Gandhi, Milind
Ko, Frank
Yang, Heejae
Shor, Lauren
Author_xml – sequence: 1
  givenname: Milind
  surname: Gandhi
  fullname: Gandhi, Milind
  organization: School of Biomedical Engineering, Sciences and Health System, Drexel University, Philadelphia, PA 19104, USA
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  givenname: Heejae
  surname: Yang
  fullname: Yang, Heejae
  organization: School of Biomedical Engineering, Sciences and Health System, Drexel University, Philadelphia, PA 19104, USA
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  givenname: Lauren
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  fullname: Shor, Lauren
  organization: Department of Mechanical Engineering and Mechanics, Drexel University, Philadelphia, PA 19104, USA
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  givenname: Frank
  surname: Ko
  fullname: Ko, Frank
  email: frank.ko@ubc.ca
  organization: Canada Research Chair Professor (Tier I) of Advanced Fibrous Materials and Director of Advanced Materials and Process Engineering, University of British Columbia, 2355 East Mall, Vancouver, BC V6T 1Z4, Canada
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IsPeerReviewed true
IsScholarly true
Issue 8
Keywords Post-spinning
Silk nanofibers
Tissue engineering
Drawing
Physical dressing
Insecta
Mechanical properties
Electrospinning
Carbon nanotubes
Nanofiber
Bombyx mori
Tensile property
Experimental study
Solid state
Singlewalled nanotube
Silk
Oriented polymer
Arthropoda
Bombycidae
Lepidoptera
Nanocomposite
Manufacturing
Invertebrata
Conformation
Language English
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Snippet Electrospinning is an effective procedure for fabricating submicron to nanoscale fibers from synthetic polymer as well as natural proteins. We successfully...
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StartPage 1918
SubjectTerms Applied sciences
Bombyx mori
Composites
Exact sciences and technology
Fibers and threads
Forms of application and semi-finished materials
Polymer industry, paints, wood
Post-spinning
Silk nanofibers
Technology of polymers
Tissue engineering
Title Post-spinning modification of electrospun nanofiber nanocomposite from Bombyx mori silk and carbon nanotubes
URI https://dx.doi.org/10.1016/j.polymer.2009.02.022
https://search.proquest.com/docview/20477837
https://search.proquest.com/docview/33858959
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