Post-spinning modification of electrospun nanofiber nanocomposite from Bombyx mori silk and carbon nanotubes
Electrospinning is an effective procedure for fabricating submicron to nanoscale fibers from synthetic polymer as well as natural proteins. We successfully electrospun regenerated silk protein from cocoons of Bombyx mori to produce random as well as aligned fibers with diameter less than 100nm. The...
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Published in: | Polymer (Guilford) Vol. 50; no. 8; pp. 1918 - 1924 |
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Abstract | Electrospinning is an effective procedure for fabricating submicron to nanoscale fibers from synthetic polymer as well as natural proteins. We successfully electrospun regenerated silk protein from cocoons of Bombyx mori to produce random as well as aligned fibers with diameter less than 100nm. The fibers were characterized using field emission environmental scanning electron microscope (ESEM), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy and wide angle X-ray diffraction (WAXD) studies. Post-spinning treatment with methanol and/or stretching and co-electrospinning with single walled carbon nanotubes (CNT) were carried out to alter the strength, toughness, crystallinity and conductivity of silk nanofibers. Addition of just 1% CNT along with post-spinning treatments resulted in 7-fold increase in the strength and 35-fold increase in the modulus of silk nanofibers. Raman spectroscopy confirmed that CNTs were incorporated in the silk fibers. FT-IR spectroscopy and WAXD studies proved that silk–CNT nanofibers had more crystallinity compared to silk nanofibers without CNT. Four-probe method demonstrated that silk–CNT nanofibers had 4 times higher electrical conductivity compared to silk nanofibers without CNT.
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AbstractList | Electrospinning is an effective procedure for fabricating submicron to nanoscale fibers from synthetic polymer as well as natural proteins. We successfully electrospun regenerated silk protein from cocoons of Bombyx mori to produce random as well as aligned fibers with diameter less than 100 nm. The fibers were characterized using field emission environmental scanning electron microscope (ESEM), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy and wide angle X-ray diffraction (WAXD) studies. Post-spinning treatment with methanol and/or stretching and co-electrospinning with single walled carbon nanotubes (CNT) were carried out to alter the strength, toughness, crystallinity and conductivity of silk nanofibers. Addition of just 1% CNT along with post-spinning treatments resulted in 7-fold increase in the strength and 35-fold increase in the modulus of silk nanofibers. Raman spectroscopy confirmed that CNTs were incorporated in the silk fibers. FT-IR spectroscopy and WAXD studies proved that silk-CNT nanofibers had more crystallinity compared to silk nanofibers without CNT. Four-probe method demonstrated that silk-CNT nanofibers had 4 times higher electrical conductivity compared to silk nanofibers without CNT. Electrospinning is an effective procedure for fabricating submicron to nanoscale fibers from synthetic polymer as well as natural proteins. We successfully electrospun regenerated silk protein from cocoons of Bombyx mori to produce random as well as aligned fibers with diameter less than 100nm. The fibers were characterized using field emission environmental scanning electron microscope (ESEM), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy and wide angle X-ray diffraction (WAXD) studies. Post-spinning treatment with methanol and/or stretching and co-electrospinning with single walled carbon nanotubes (CNT) were carried out to alter the strength, toughness, crystallinity and conductivity of silk nanofibers. Addition of just 1% CNT along with post-spinning treatments resulted in 7-fold increase in the strength and 35-fold increase in the modulus of silk nanofibers. Raman spectroscopy confirmed that CNTs were incorporated in the silk fibers. FT-IR spectroscopy and WAXD studies proved that silk-CNT nanofibers had more crystallinity compared to silk nanofibers without CNT. Four-probe method demonstrated that silk-CNT nanofibers had 4 times higher electrical conductivity compared to silk nanofibers without CNT. Electrospinning is an effective procedure for fabricating submicron to nanoscale fibers from synthetic polymer as well as natural proteins. We successfully electrospun regenerated silk protein from cocoons of Bombyx mori to produce random as well as aligned fibers with diameter less than 100nm. The fibers were characterized using field emission environmental scanning electron microscope (ESEM), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy and wide angle X-ray diffraction (WAXD) studies. Post-spinning treatment with methanol and/or stretching and co-electrospinning with single walled carbon nanotubes (CNT) were carried out to alter the strength, toughness, crystallinity and conductivity of silk nanofibers. Addition of just 1% CNT along with post-spinning treatments resulted in 7-fold increase in the strength and 35-fold increase in the modulus of silk nanofibers. Raman spectroscopy confirmed that CNTs were incorporated in the silk fibers. FT-IR spectroscopy and WAXD studies proved that silk–CNT nanofibers had more crystallinity compared to silk nanofibers without CNT. Four-probe method demonstrated that silk–CNT nanofibers had 4 times higher electrical conductivity compared to silk nanofibers without CNT. [Display omitted] |
Author | Gandhi, Milind Ko, Frank Yang, Heejae Shor, Lauren |
Author_xml | – sequence: 1 givenname: Milind surname: Gandhi fullname: Gandhi, Milind organization: School of Biomedical Engineering, Sciences and Health System, Drexel University, Philadelphia, PA 19104, USA – sequence: 2 givenname: Heejae surname: Yang fullname: Yang, Heejae organization: School of Biomedical Engineering, Sciences and Health System, Drexel University, Philadelphia, PA 19104, USA – sequence: 3 givenname: Lauren surname: Shor fullname: Shor, Lauren organization: Department of Mechanical Engineering and Mechanics, Drexel University, Philadelphia, PA 19104, USA – sequence: 4 givenname: Frank surname: Ko fullname: Ko, Frank email: frank.ko@ubc.ca organization: Canada Research Chair Professor (Tier I) of Advanced Fibrous Materials and Director of Advanced Materials and Process Engineering, University of British Columbia, 2355 East Mall, Vancouver, BC V6T 1Z4, Canada |
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Keywords | Post-spinning Silk nanofibers Tissue engineering Drawing Physical dressing Insecta Mechanical properties Electrospinning Carbon nanotubes Nanofiber Bombyx mori Tensile property Experimental study Solid state Singlewalled nanotube Silk Oriented polymer Arthropoda Bombycidae Lepidoptera Nanocomposite Manufacturing Invertebrata Conformation |
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Snippet | Electrospinning is an effective procedure for fabricating submicron to nanoscale fibers from synthetic polymer as well as natural proteins. We successfully... |
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SubjectTerms | Applied sciences Bombyx mori Composites Exact sciences and technology Fibers and threads Forms of application and semi-finished materials Polymer industry, paints, wood Post-spinning Silk nanofibers Technology of polymers Tissue engineering |
Title | Post-spinning modification of electrospun nanofiber nanocomposite from Bombyx mori silk and carbon nanotubes |
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