Cellulose Based Photonic Materials Displaying Direction Modulated Photoluminescence

Photonic materials featuring simultaneous iridescence and light emission are an attractive alternative for designing novel optical devices. The luminescence study of a new optical material that integrates light emission and iridescence through liquid crystal self-assembly of cellulose nanocrystal-te...

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Published in:Frontiers in bioengineering and biotechnology Vol. 9; p. 617328
Main Authors: Santos, Molíria V, Maturi, Fernando E, Pecoraro, Édison, Barud, Hernane S, Lima, Laís R, Ferreira, Rute A S, Carlos, Luís D, Ribeiro, Sidney J L
Format: Journal Article
Language:English
Published: Switzerland Frontiers Media S.A 30-03-2021
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Abstract Photonic materials featuring simultaneous iridescence and light emission are an attractive alternative for designing novel optical devices. The luminescence study of a new optical material that integrates light emission and iridescence through liquid crystal self-assembly of cellulose nanocrystal-template silica approach is herein presented. These materials containing Rhodamine 6G were obtained as freestanding composite films with a chiral nematic organization. The scanning electron microscopy confirms that the cellulose nanocrystal film structure comprises multi-domain Bragg reflectors and the optical properties of these films can be tuned through changes in the relative content of silica/cellulose nanocrystals. Moreover, the incorporation of the light-emitting compound allows a complementary control of the optical properties. Overall, such findings demonstrated that the photonic structure plays the role of direction-dependent inner-filter, causing selective suppression of the light emitted with angle-dependent detection.
AbstractList Photonic materials featuring simultaneous iridescence and light emission are an attractive alternative for designing novel optical devices. The luminescence study of a new optical material that integrates light emission and iridescence through liquid crystal self-assembly of cellulose nanocrystal-template silica approach is herein presented. These materials containing Rhodamine 6G were obtained as freestanding composite films with a chiral nematic organization. The scanning electron microscopy confirms that the cellulose nanocrystal film structure comprises multi-domain Bragg reflectors and the optical properties of these films can be tuned through changes in the relative content of silica/cellulose nanocrystals. Moreover, the incorporation of the light-emitting compound allows a complementary control of the optical properties. Overall, such findings demonstrated that the photonic structure plays the role of direction-dependent inner-filter, causing selective suppression of the light emitted with angle-dependent detection.
Author Maturi, Fernando E
Carlos, Luís D
Ferreira, Rute A S
Santos, Molíria V
Ribeiro, Sidney J L
Barud, Hernane S
Pecoraro, Édison
Lima, Laís R
AuthorAffiliation 2 Department of Physics, CICECO – Aveiro Institute of Materials, University of Aveiro , Aveiro , Portugal
3 Biopolymers and Biomaterials Laboratory, University of Araraquara , Araraquara , Brazil
1 Institute of Chemistry, São Paulo State University (UNESP) , Araraquara , Brazil
AuthorAffiliation_xml – name: 3 Biopolymers and Biomaterials Laboratory, University of Araraquara , Araraquara , Brazil
– name: 2 Department of Physics, CICECO – Aveiro Institute of Materials, University of Aveiro , Aveiro , Portugal
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Copyright Copyright © 2021 Santos, Maturi, Pecoraro, Barud, Lima, Ferreira, Carlos and Ribeiro.
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Keywords iridescence
rhodamine 6G
luminescence
chiral nematic liquid crystal
bacterial cellulose nanocrystals
modulated light emission
photonic materials
Language English
License Copyright © 2021 Santos, Maturi, Pecoraro, Barud, Lima, Ferreira, Carlos and Ribeiro.
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This article was submitted to Biomaterials, a section of the journal Frontiers in Bioengineering and Biotechnology
Edited by: Muhammad Wajid Ullah, Huazhong University of Science and Technology, China
Reviewed by: Yan Qiao, Institute of Chemistry (CAS), China; Adil Denizli, Hacettepe University, Turkey
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Snippet Photonic materials featuring simultaneous iridescence and light emission are an attractive alternative for designing novel optical devices. The luminescence...
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SubjectTerms bacterial cellulose nanocrystals
Bioengineering and Biotechnology
chiral nematic liquid crystal
iridescence
luminescence
modulated light emission
photonic materials
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Title Cellulose Based Photonic Materials Displaying Direction Modulated Photoluminescence
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