Cellulose Based Photonic Materials Displaying Direction Modulated Photoluminescence
Photonic materials featuring simultaneous iridescence and light emission are an attractive alternative for designing novel optical devices. The luminescence study of a new optical material that integrates light emission and iridescence through liquid crystal self-assembly of cellulose nanocrystal-te...
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Published in: | Frontiers in bioengineering and biotechnology Vol. 9; p. 617328 |
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Abstract | Photonic materials featuring simultaneous iridescence and light emission are an attractive alternative for designing novel optical devices. The luminescence study of a new optical material that integrates light emission and iridescence through liquid crystal self-assembly of cellulose nanocrystal-template silica approach is herein presented. These materials containing Rhodamine 6G were obtained as freestanding composite films with a chiral nematic organization. The scanning electron microscopy confirms that the cellulose nanocrystal film structure comprises multi-domain Bragg reflectors and the optical properties of these films can be tuned through changes in the relative content of silica/cellulose nanocrystals. Moreover, the incorporation of the light-emitting compound allows a complementary control of the optical properties. Overall, such findings demonstrated that the photonic structure plays the role of direction-dependent inner-filter, causing selective suppression of the light emitted with angle-dependent detection. |
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AbstractList | Photonic materials featuring simultaneous iridescence and light emission are an attractive alternative for designing novel optical devices. The luminescence study of a new optical material that integrates light emission and iridescence through liquid crystal self-assembly of cellulose nanocrystal-template silica approach is herein presented. These materials containing Rhodamine 6G were obtained as freestanding composite films with a chiral nematic organization. The scanning electron microscopy confirms that the cellulose nanocrystal film structure comprises multi-domain Bragg reflectors and the optical properties of these films can be tuned through changes in the relative content of silica/cellulose nanocrystals. Moreover, the incorporation of the light-emitting compound allows a complementary control of the optical properties. Overall, such findings demonstrated that the photonic structure plays the role of direction-dependent inner-filter, causing selective suppression of the light emitted with angle-dependent detection. |
Author | Maturi, Fernando E Carlos, Luís D Ferreira, Rute A S Santos, Molíria V Ribeiro, Sidney J L Barud, Hernane S Pecoraro, Édison Lima, Laís R |
AuthorAffiliation | 2 Department of Physics, CICECO – Aveiro Institute of Materials, University of Aveiro , Aveiro , Portugal 3 Biopolymers and Biomaterials Laboratory, University of Araraquara , Araraquara , Brazil 1 Institute of Chemistry, São Paulo State University (UNESP) , Araraquara , Brazil |
AuthorAffiliation_xml | – name: 3 Biopolymers and Biomaterials Laboratory, University of Araraquara , Araraquara , Brazil – name: 2 Department of Physics, CICECO – Aveiro Institute of Materials, University of Aveiro , Aveiro , Portugal – name: 1 Institute of Chemistry, São Paulo State University (UNESP) , Araraquara , Brazil |
Author_xml | – sequence: 1 givenname: Molíria V surname: Santos fullname: Santos, Molíria V organization: Department of Physics, CICECO - Aveiro Institute of Materials, University of Aveiro, Aveiro, Portugal – sequence: 2 givenname: Fernando E surname: Maturi fullname: Maturi, Fernando E organization: Department of Physics, CICECO - Aveiro Institute of Materials, University of Aveiro, Aveiro, Portugal – sequence: 3 givenname: Édison surname: Pecoraro fullname: Pecoraro, Édison organization: Institute of Chemistry, São Paulo State University (UNESP), Araraquara, Brazil – sequence: 4 givenname: Hernane S surname: Barud fullname: Barud, Hernane S organization: Biopolymers and Biomaterials Laboratory, University of Araraquara, Araraquara, Brazil – sequence: 5 givenname: Laís R surname: Lima fullname: Lima, Laís R organization: Institute of Chemistry, São Paulo State University (UNESP), Araraquara, Brazil – sequence: 6 givenname: Rute A S surname: Ferreira fullname: Ferreira, Rute A S organization: Department of Physics, CICECO - Aveiro Institute of Materials, University of Aveiro, Aveiro, Portugal – sequence: 7 givenname: Luís D surname: Carlos fullname: Carlos, Luís D organization: Department of Physics, CICECO - Aveiro Institute of Materials, University of Aveiro, Aveiro, Portugal – sequence: 8 givenname: Sidney J L surname: Ribeiro fullname: Ribeiro, Sidney J L organization: Institute of Chemistry, São Paulo State University (UNESP), Araraquara, Brazil |
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Cites_doi | 10.2478/s11532-013-0289-1 10.1002/adma.201905876 10.1002/anie.201302687 10.1002/adma.201907569 10.1039/c4tc01482k 10.1039/c5tc04163e 10.1063/1.358518 10.1016/j.clay.2006.02.011 10.1016/j.jlumin.2007.03.022 10.1155/2011/721631 10.1364/ol.23.001707 10.1039/b809212e 10.1038/378467a0 10.1021/jp810835j 10.1039/c3cs60204d 10.1039/c0sm00142b 10.1063/1.4978387 10.1021/bm049300p 10.1039/c4dt00662c 10.1002/adfm.201302521 10.1016/j.carbpol.2008.11.014 10.1021/ma012098n 10.1016/j.carbpol.2020.116664 10.1016/j.jnoncrysol.2006.10.014 10.1021/ar400243m 10.1088/2040-8986/aa9e7d 10.1007/s10570-012-9733-1 10.1515/nanoph-2020-0039 10.1016/j.cej.2018.02.007 10.1002/bip.360271210 10.1021/bm801193d 10.1007/s10971-007-1669-9 10.1016/j.optmat.2014.12.009 10.1021/jp050440i 10.1021/ma00122a053 10.1002/adfm.201301737 10.1103/PhysRevE.85.041702 10.1021/cr900339w 10.1002/adma.201606083 10.1002/adem.201400085 10.1002/anie.201201113 10.1016/j.jnoncrysol.2005.04.027 10.1016/j.apmt.2020.100912 10.1016/j.snb.2012.09.100 10.1021/am501995e 10.1002/anie.201001273 10.1002/adom.201600514 10.1039/c4tc02913e 10.1016/s0141-8130(05)80008-x 10.1021/am508273x 10.1002/anie.201911468 10.1021/bm034519%2B 10.1038/nature09540 10.1038/am.2013.69 10.1107/s0365110x51000751 |
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Copyright | Copyright © 2021 Santos, Maturi, Pecoraro, Barud, Lima, Ferreira, Carlos and Ribeiro. Copyright © 2021 Santos, Maturi, Pecoraro, Barud, Lima, Ferreira, Carlos and Ribeiro. 2021 Santos, Maturi, Pecoraro, Barud, Lima, Ferreira, Carlos and Ribeiro |
Copyright_xml | – notice: Copyright © 2021 Santos, Maturi, Pecoraro, Barud, Lima, Ferreira, Carlos and Ribeiro. – notice: Copyright © 2021 Santos, Maturi, Pecoraro, Barud, Lima, Ferreira, Carlos and Ribeiro. 2021 Santos, Maturi, Pecoraro, Barud, Lima, Ferreira, Carlos and Ribeiro |
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Keywords | iridescence rhodamine 6G luminescence chiral nematic liquid crystal bacterial cellulose nanocrystals modulated light emission photonic materials |
Language | English |
License | Copyright © 2021 Santos, Maturi, Pecoraro, Barud, Lima, Ferreira, Carlos and Ribeiro. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms. |
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Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 This article was submitted to Biomaterials, a section of the journal Frontiers in Bioengineering and Biotechnology Edited by: Muhammad Wajid Ullah, Huazhong University of Science and Technology, China Reviewed by: Yan Qiao, Institute of Chemistry (CAS), China; Adil Denizli, Hacettepe University, Turkey |
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Snippet | Photonic materials featuring simultaneous iridescence and light emission are an attractive alternative for designing novel optical devices. The luminescence... |
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SubjectTerms | bacterial cellulose nanocrystals Bioengineering and Biotechnology chiral nematic liquid crystal iridescence luminescence modulated light emission photonic materials |
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Title | Cellulose Based Photonic Materials Displaying Direction Modulated Photoluminescence |
URI | https://www.ncbi.nlm.nih.gov/pubmed/33859978 https://search.proquest.com/docview/2514598739 https://pubmed.ncbi.nlm.nih.gov/PMC8042215 https://doaj.org/article/d9938221389d4538884134f313f36ac7 |
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