Star polymers by cross-linking of linear poly(benzyl-L-glutamate) macromonomers via free-radical and RAFT polymerization. A simple route toward peptide-stabilized nanoparticles

Poly(benzyl-L-glutamate) (PBLG) macromonomers were synthesized by N-carboxyanhydride (NCA) polymerization initiated with 4-vinyl benzylamine. MALDI-ToF analysis confirmed the presence of styrenic end-groups in the PBLG. Free-radical and RAFT polymerization of the macromonomer in the presence of divi...

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Bibliographic Details
Published in:	Journal of polymer science. Part A, Polymer chemistry Vol. 48; no. 20; pp. 4602 - 4610
Main Authors:	Audouin, Fabrice, Knoop, Ruther J.I, Huang, Jin, Heise, Andreas
Format:	Journal Article
Language:	English
Published:	Hoboken Wiley Subscription Services, Inc., A Wiley Company 15-10-2010 Wiley
Subjects:	Aminoacid polymers Applied sciences bioconjugates controlled radical polymerization Exact sciences and technology free-radical polymerization macromonomer Molecular weight Nanoparticles PBLG Physicochemistry of polymers Polydispersity Polymer chemistry Polymerization RAFT Rafts Reproduction Stars Synthetic biopolymers Ring opening polymerization Optically active polymer PBLG macromonomer controlled radical polymerization Experimental study Aminoacid polymer Gamma benzyl glutamate polymer Macromer Monodispersed polymer Chemical modification Chain transfer nanoparticles bioconjugates free-radical polymerization Preparation Water solubility pH Debenzylation Glutamic acid polymer Star polymer RAFT Radical copolymerization
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