Thermal stability of reversible addition-fragmentation chain transfer/macromolecular architecture design by interchange of xanthates chain-transfer agents

A series of chain-transfer agents used in reversible addition-fragmentation chain transfer/macromolecular architecture design by interchange of xanthates polymerizations were subjected to thermogravimetric analysis and gas chromatography/mass spectrometry to assess their stability to heat and to det...

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Bibliographic Details
Published in:	Journal of polymer science. Part A, Polymer chemistry Vol. 44; no. 24; pp. 6980 - 6987
Main Authors:	Legge, Thomas M, Slark, Andrew T, Perrier, Sébastien
Format:	Journal Article
Language:	English
Published:	Hoboken Wiley Subscription Services, Inc., A Wiley Company 15-12-2006 Wiley
Subjects:	Applied sciences degradation Exact sciences and technology Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts reversible addition fragmentation chain transfer (RAFT) thermogravimetric analysis (TGA) Organic trithiocarbonate Polymerization modifier Organic dithiocarbamate reversible addition fragmentation chain transfer (RAFT) degradation thermogravimetric analysis (TGA) Dithioester Experimental study Thermal stability Free radical polymerization Chain transfer Organic dithiocarbonate Reaction mechanism Comparative study Thermal degradation
Online Access:	Get full text
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