Effect of the catalyst MCM-41 on the kinetic of the thermal decomposition of poly(ethylene terephthalate)

The aim of this work is to determine the activation energy for the thermal decomposition of poly(ethylene terephthalate)—PET, in the presence of a MCM-41 mesoporous catalyst. This material was synthesized by the hydrothermal method, using cetyltrimethylammonium as template. The PET sample has been s...

Full description

Saved in:

Bibliographic Details
Published in:	Journal of thermal analysis and calorimetry Vol. 99; no. 2; pp. 465 - 469
Main Authors:	Araújo, Sulene A., Araujo, Antonio S., Fernandes, Nedja S., Fernandes, Valter J., Ionashiro, Massao
Format:	Journal Article
Language:	English
Published:	Dordrecht Springer Netherlands 01-02-2010 Springer
Subjects:	Activation energy Analysis Analytical Chemistry Applied sciences Calorimetry Catalysts Chemical reactions and properties Chemistry Chemistry and Materials Science Degradation Ethylene Exact sciences and technology Inorganic Chemistry Measurement Science and Instrumentation Organic polymers Physical Chemistry Physicochemistry of polymers Polyethylene terephthalates Polymer Sciences Polymers Reaction kinetics Thermal decomposition Thermal degradation Thermogravimetry Toy industry MCM-41 Flynn–Wall kinetic model Thermogravimetry Poly(ethylene terephthalate) Ethylene terephthalate polymer Scanning electron microscopy Pyrolysis X ray diffraction Porous material Mesoporosity Molecular sieve Surface structure Heterogeneous catalysis Kinetic model Flynn―Wall kinetic model Morphology Surface properties Thermal analysis Kinetics Surface area Catalyst Thermal degradation
Online Access:	Get full text
Tags:	Add Tag No Tags, Be the first to tag this record!

Abstract	The aim of this work is to determine the activation energy for the thermal decomposition of poly(ethylene terephthalate)—PET, in the presence of a MCM-41 mesoporous catalyst. This material was synthesized by the hydrothermal method, using cetyltrimethylammonium as template. The PET sample has been submitted to thermal degradation alone and in presence of MCM-41 catalyst at a concentration of 25% in mass (MCM-41/PET). The degradation process was evaluated by thermogravimetry, at temperature range from 350 to 500 °C, under nitrogen atmosphere, with heating rates of 5, 10 and 25 °C min −1 . From TG, the activation energy, determined using the Flynn–Wall kinetic method, decreased from 231 kJ mol −1 , for the pure polymer (PET), to 195 kJ mol −1 , in the presence of the material (MCM-41/PET), showing the catalyst efficiency for the polymer decomposition process.
AbstractList	The aim of this work is to determine the activation energy for the thermal decomposition of poly(ethylene terephthalate)—PET, in the presence of a MCM-41 mesoporous catalyst. This material was synthesized by the hydrothermal method, using cetyltrimethylammonium as template. The PET sample has been submitted to thermal degradation alone and in presence of MCM-41 catalyst at a concentration of 25% in mass (MCM-41/PET). The degradation process was evaluated by thermogravimetry, at temperature range from 350 to 500 °C, under nitrogen atmosphere, with heating rates of 5, 10 and 25 °C min −1 . From TG, the activation energy, determined using the Flynn–Wall kinetic method, decreased from 231 kJ mol −1 , for the pure polymer (PET), to 195 kJ mol −1 , in the presence of the material (MCM-41/PET), showing the catalyst efficiency for the polymer decomposition process. The aim of this work is to determine the activation energy for the thermal decomposition of poly(ethylene terephthalate)--PET, in the presence of a MCM-41 mesoporous catalyst. This material was synthesized by the hydrothermal method, using cetyltrimethylammonium as template. The PET sample has been submitted to thermal degradation alone and in presence of MCM-41 catalyst at a concentration of 25% in mass (MCM-41/PET). The degradation process was evaluated by thermogravimetry, at temperature range from 350 to 500 ?C, under nitrogen atmosphere, with heating rates of 5, 10 and 25 ?C min-1. From TG, the activation energy, determined using the Flynn--Wall kinetic method, decreased from 231 kJ mol-1, for the pure polymer (PET), to 195 kJ mol-1, in the presence of the material (MCM-41/PET), showing the catalyst efficiency for the polymer decomposition process. The aim of this work is to determine the activation energy for the thermal decomposition of poly (ethylene terephthalate)--PET, in the presence of a MCM-41 mesoporous catalyst. This material was synthesized by the hydrothermal method, using cetyltrimethylammonium as template. The PET sample has been submitted to thermal degradation alone and in presence of MCM-41 catalyst at a concentration of 25% in mass (MCM-41/PET). The degradation process was evaluated by thermogravimetry, at temperature range from 350 to 500[degrees]C, under nitrogen atmosphere, with heating rates of 5, 10 and 25[degrees]C [min.sup.-1]. From TG, the activation energy, determined using the Flynn-Wall kinetic method, decreased from 231 kJ [mol.sup.-1], for the pure polymer (PET), to 195 kJ [mol.sup.-1], in the presence of the material (MCM-41/PET), showing the catalyst efficiency for the polymer decomposition process. The aim of this work is to determine the activation energy for the thermal decomposition of poly (ethylene terephthalate)--PET, in the presence of a MCM-41 mesoporous catalyst. This material was synthesized by the hydrothermal method, using cetyltrimethylammonium as template. The PET sample has been submitted to thermal degradation alone and in presence of MCM-41 catalyst at a concentration of 25% in mass (MCM-41/PET). The degradation process was evaluated by thermogravimetry, at temperature range from 350 to 500[degrees]C, under nitrogen atmosphere, with heating rates of 5, 10 and 25[degrees]C [min.sup.-1]. From TG, the activation energy, determined using the Flynn-Wall kinetic method, decreased from 231 kJ [mol.sup.-1], for the pure polymer (PET), to 195 kJ [mol.sup.-1], in the presence of the material (MCM-41/PET), showing the catalyst efficiency for the polymer decomposition process. Keywords Poly(ethylene terephthalate) * MCM-41 * Flynn-Wall kinetic model * Thermogravimetry
Audience	Academic
Author	Fernandes, Nedja S. Fernandes, Valter J. Araujo, Antonio S. Ionashiro, Massao Araújo, Sulene A.
Author_xml	– sequence: 1 givenname: Sulene A. surname: Araújo fullname: Araújo, Sulene A. email: sulene@hotmail.com organization: Department of Chemistry, State University of Southwest of Bahia (UESB) – sequence: 2 givenname: Antonio S. surname: Araujo fullname: Araujo, Antonio S. email: asa-ufrn@usa.net organization: Department of Chemistry, Federal University of Rio Grande do Norte – sequence: 3 givenname: Nedja S. surname: Fernandes fullname: Fernandes, Nedja S. organization: Department of Chemistry, Federal University of Rio Grande do Norte – sequence: 4 givenname: Valter J. surname: Fernandes fullname: Fernandes, Valter J. organization: Department of Chemistry, Federal University of Rio Grande do Norte – sequence: 5 givenname: Massao surname: Ionashiro fullname: Ionashiro, Massao organization: Institute of Chemistry, UNESP
BackLink	http://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22414356$$DView record in Pascal Francis
BookMark	eNp9kU1r3DAQhk1JIWmaH5CbL6XNwam-LEvHsKRtIKGQtGehlUe7amXJlbSQ_ffV1kkglyIGDTPPOwzzvmuOQgzQNOcYXWKEhs8ZIznQDiHZISZRJ980J7gXoiOS8KOa05pz3KPj5ixnt0YEIy57IU8ad20tmNJG25YttEYX7fe5tHeru47hNoZ_5d8uQHHmmaqRJu3bEUyc5phdcRWszTn6_Sco272HUDFIMG_LVntd4OJ989Zqn-Hs6T9tfn65_rH61t1-_3qzurrtDOOodGLgUlvKNRvNes1H3XMkjRmH0TBBBilHO1hJALQATg0WmhlrgIqhtwiYpafNx2XunOKfHeSiJpcNeK8DxF1WklPBKCKykpcLudEelAs2lqRNfSNMztQTW1frV7QeSgrCSRVcvBJUpsBj2ehdzurm4f41ixfWpJhzAqvm5Cad9gojdXBNLa6p6po6uKYOC314Wl1no71NOhiXX4SEMMxozytHFi7XVthAUr_iLoV61f8M_wt3NajN
CitedBy_id	crossref_primary_10_1007_s10973_011_1295_1 crossref_primary_10_1080_1023666X_2017_1313808 crossref_primary_10_1002_app_39246 crossref_primary_10_1007_s10973_011_1353_8 crossref_primary_10_1016_j_micromeso_2013_01_022 crossref_primary_10_1007_s10965_013_0310_6 crossref_primary_10_1007_s10973_017_6185_8 crossref_primary_10_1007_s10973_014_3757_8 crossref_primary_10_1007_s10973_017_6237_0 crossref_primary_10_1080_10916466_2016_1278388 crossref_primary_10_1007_s42247_019_00057_1 crossref_primary_10_1590_1516_1439_217113 crossref_primary_10_3390_sym15010038
Cites_doi	10.1016/j.matlet.2006.01.066 10.1016/0040-6031(95)02804-8 10.1023/A:1011564916290 10.1007/s10973-006-7535-0 10.1016/0040-6031(94)02131-7 10.1007/s10973-008-9362-y 10.1007/s10973-005-0070-6 10.1021/jp0021648 10.1016/j.cattod.2005.07.065 10.1016/S0165-2370(00)00193-5 10.1007/s10973-006-7781-1 10.1023/A:1011511504478 10.1016/S0920-5861(02)00074-3 10.1007/s10973-007-8690-7 10.1023/A:1010142003725 10.1021/j150547a024 10.1002/pol.1967.110050211
ContentType	Journal Article
Copyright	Akadémiai Kiadó, Budapest, Hungary 2009 2015 INIST-CNRS COPYRIGHT 2010 Springer
Copyright_xml	– notice: Akadémiai Kiadó, Budapest, Hungary 2009 – notice: 2015 INIST-CNRS – notice: COPYRIGHT 2010 Springer
DBID	IQODW AAYXX CITATION ISR 7SR 7U5 8BQ 8FD JG9 L7M
DOI	10.1007/s10973-009-0490-9
DatabaseName	Pascal-Francis CrossRef Gale In Context: Science Engineered Materials Abstracts Solid State and Superconductivity Abstracts METADEX Technology Research Database Materials Research Database Advanced Technologies Database with Aerospace
DatabaseTitle	CrossRef Materials Research Database Engineered Materials Abstracts Solid State and Superconductivity Abstracts Technology Research Database Advanced Technologies Database with Aerospace METADEX
DatabaseTitleList	Materials Research Database
DeliveryMethod	fulltext_linktorsrc
Discipline	Chemistry Applied Sciences
EISSN	1588-2926 1572-8943
EndPage	469
ExternalDocumentID	A358998262 10_1007_s10973_009_0490_9 22414356
GroupedDBID	-4Y -58 -5G -BR -EM -Y2 -~C .86 .VR 06C 06D 0R~ 0VY 1N0 2.D 203 29L 2J2 2JN 2JY 2KG 2KM 2LR 2P1 2VQ 2~H 30V 4.4 406 408 409 40D 40E 53G 5GY 5QI 5VS 67Z 6NX 8TC 8UJ 95- 95. 95~ 96X AAAVM AABHQ AABYN AAFGU AAGCJ AAHNG AAIAL AAIKT AANZL AARHV AARTL AATNV AATVU AAUCO AAUYE AAWCG AAYFA AAYIU AAYQN AAYTO ABBBX ABBXA ABDBF ABDZT ABECU ABFGW ABFTV ABHLI ABHQN ABJOX ABKAS ABKCH ABKTR ABMNI ABMQK ABNWP ABPTK ABQBU ABSXP ABTEG ABTHY ABTKH ABTMW ABULA ABWNU ABXPI ACBMV ACBRV ACBXY ACBYP ACGFS ACHSB ACHXU ACIGE ACIPQ ACIWK ACKNC ACMDZ ACMLO ACOKC ACOMO ACSNA ACTTH ACVWB ACWMK ADHIR ADINQ ADKNI ADKPE ADMDM ADOXG ADPHR ADRFC ADTPH ADURQ ADYFF ADZKW AEBTG AEEQQ AEFIE AEGAL AEGNC AEJHL AEJRE AEKMD AENEX AEOHA AEPYU AESKC AETLH AEVLU AEXYK AFEXP AFGCZ AFLOW AFNRJ AFQWF AFWTZ AFZKB AGAYW AGDGC AGGDS AGJBK AGMZJ AGQMX AGWIL AGWZB AGYKE AHAVH AHBYD AHKAY AHSBF AHYZX AI. AIAKS AIIXL AILAN AIMYW AITGF AJBLW AJDOV AJGSW AJRNO AJZVZ AKQUC ALMA_UNASSIGNED_HOLDINGS ALWAN AMKLP AMXSW AMYLF AOCGG ARMRJ AXYYD AYJHY AZFZN B-. B0M BA0 BDATZ BGNMA CAG COF CS3 CSCUP DDRTE DL5 DNIVK DPUIP DU5 EAD EAP EBLON EBS EIOEI EJD EMK EPL ESBYG ESX F5P FEDTE FERAY FFXSO FIGPU FINBP FNLPD FRRFC FSGXE FWDCC G-Y G-Z GGCAI GGRSB GJIRD GNWQR GQ6 GQ7 GQ8 GXS HF~ HG5 HG6 HMJXF HQYDN HRMNR HVGLF HZ~ I-F IAO IHE IJ- IKXTQ ISR ITC ITM IWAJR IXC IXE IZIGR IZQ I~X I~Z J-C J0Z JBSCW JCJTX JZLTJ KDC KOV LAK LLZTM M4Y MA- MET MKB N2Q N9A NB0 NDZJH NPVJJ NQJWS NU0 O9- O93 O9G O9I O9J OAM OVD P19 P9N PF0 PT4 PT5 QOK QOR QOS R89 R9I RKA RNI RNS ROL RPX RSV RZC RZE RZK S16 S1Z S26 S27 S28 S3B SAP SCG SCLPG SCM SDH SHX SISQX SJYHP SNE SNPRN SNX SOHCF SOJ SPISZ SQXTU SRMVM SSLCW STPWE SZN T13 T16 TEORI TSG TSK TSV TUC TUS U2A UG4 UNUBA UOJIU UTJUX UZXMN VC2 VFIZW VH1 W23 W48 W4F WJK WK8 YLTOR Z45 Z5O Z7R Z7S Z7U Z7V Z7W Z7X Z7Y Z7Z Z81 Z83 Z85 Z86 Z87 Z88 Z8M Z8N Z8O Z8P Z8Q Z8R Z8T Z8W Z91 Z92 ZE2 ZMTXR ~02 ~8M H13 IQODW AACDK AAEOY AAJBT AASML AAYXX AAYZH ABAKF ACAOD ACDTI ACZOJ AEFQL AEMSY AFBBN AGJZZ AGQEE AGRTI AIGIU CITATION 7SR 7U5 8BQ 8FD JG9 L7M
ID	FETCH-LOGICAL-c460t-8769af36a4dcbb6da5609ccd7dc482799df7f92eea8e63c18a4cfce3875f0e4f3
IEDL.DBID	AEJHL
ISSN	1388-6150
IngestDate	Fri Oct 25 08:58:08 EDT 2024 Tue Nov 12 23:14:16 EST 2024 Thu Aug 01 20:24:47 EDT 2024 Thu Nov 21 21:35:55 EST 2024 Sun Oct 22 16:06:34 EDT 2023 Sat Dec 16 12:02:41 EST 2023
IsPeerReviewed	true
IsScholarly	true
Issue	2
Keywords	MCM-41 Flynn–Wall kinetic model Thermogravimetry Poly(ethylene terephthalate) Ethylene terephthalate polymer Scanning electron microscopy Pyrolysis X ray diffraction Porous material Mesoporosity Molecular sieve Surface structure Heterogeneous catalysis Kinetic model Flynn―Wall kinetic model Morphology Surface properties Thermal analysis Kinetics Surface area Catalyst Thermal degradation
Language	English
License	CC BY 4.0
LinkModel	DirectLink
MergedId	FETCHMERGED-LOGICAL-c460t-8769af36a4dcbb6da5609ccd7dc482799df7f92eea8e63c18a4cfce3875f0e4f3
Notes	ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23
PQID	963843029
PQPubID	23500
PageCount	5
ParticipantIDs	proquest_miscellaneous_963843029 gale_infotracacademiconefile_A358998262 gale_incontextgauss_ISR_A358998262 crossref_primary_10_1007_s10973_009_0490_9 pascalfrancis_primary_22414356 springer_journals_10_1007_s10973_009_0490_9
PublicationCentury	2000
PublicationDate	2010-02-01
PublicationDateYYYYMMDD	2010-02-01
PublicationDate_xml	– month: 02 year: 2010 text: 2010-02-01 day: 01
PublicationDecade	2010
PublicationPlace	Dordrecht
PublicationPlace_xml	– name: Dordrecht
PublicationSubtitle	An International Forum for Thermal Studies
PublicationTitle	Journal of thermal analysis and calorimetry
PublicationTitleAbbrev	J Therm Anal Calorim
PublicationYear	2010
Publisher	Springer Netherlands Springer
Publisher_xml	– name: Springer Netherlands – name: Springer
References	Souza, Araujo, Pedrosa, Marinkovic, Jardim, Morgado (CR6) 2006; 60 Sinfronio, Souza, Santos, Fernandes, Novak, Ehen (CR7) 2006; 85 Fernandes, Fernandes, Araujo (CR10) 2002; 75 Fernandes, Araujo, Fernandes, Matos, Ionashiro (CR8) 2001; 64 Polli, Pontes, Araujo, Barros, Fernandes (CR4) 2009; 95 Pacheco, Graciliano, Silva, Souza, Araujo (CR9) 2005; 107 Polli, Pontes, Araujo (CR3) 2005; 79 CR16 Flynn, Dickens (CR17) 1978; 176 Bolbukh, Kuzema, Tertykh, Laguta (CR2) 2008; 94 Herrera, Wilhelm, Matuschek, Kettrup (CR1) 2001; 58–59 Antochshuk, Araujo, Jaroniec (CR14) 2000; 104 Flynn (CR18) 1996; 283 Mianowski, Siudyga (CR5) 2008; 92 Fernandes, Araújo (CR12) 1995; 255 Fernandes, Araujo, Medeiros, Matos, Mercuri, Silva, Melo (CR11) 1999; 56 Araujo, Ionashiro, Fernandes, Araujo (CR13) 2001; 64 Flynn (CR15) 1957; 61 VJ Fernandes (490_CR12) 1995; 255 V Antochshuk (490_CR14) 2000; 104 VJ Fernandes (490_CR8) 2001; 64 490_CR16 A Mianowski (490_CR5) 2008; 92 JH Flynn (490_CR17) 1978; 176 GJT Fernandes (490_CR10) 2002; 75 JGA Pacheco (490_CR9) 2005; 107 VJ Fernandes (490_CR11) 1999; 56 H Polli (490_CR3) 2005; 79 JH Flynn (490_CR18) 1996; 283 M Herrera (490_CR1) 2001; 58–59 Y Bolbukh (490_CR2) 2008; 94 SA Araujo (490_CR13) 2001; 64 H Polli (490_CR4) 2009; 95 JH Flynn (490_CR15) 1957; 61 FSM Sinfronio (490_CR7) 2006; 85 MJB Souza (490_CR6) 2006; 60
References_xml	– volume: 60 start-page: 2682 year: 2006 end-page: 2685 ident: CR6 article-title: Textural features of highly ordered Al-MCM-41 molecular sieve studied by X-ray diffraction, nitrogen adsorption and transmission electron microscopy publication-title: Mater Lett doi: 10.1016/j.matlet.2006.01.066 contributor: fullname: Morgado – volume: 283 start-page: 35 year: 1996 end-page: 42 ident: CR18 article-title: Early papers by Takeo Ozawa and their continuing relevance publication-title: Thermochim Acta doi: 10.1016/0040-6031(95)02804-8 contributor: fullname: Flynn – volume: 64 start-page: 801 year: 2001 end-page: 805 ident: CR13 article-title: Thermogravimetric investigations during the synthesis of silica-based MCM-41 publication-title: J Therm Anal Calorim doi: 10.1023/A:1011564916290 contributor: fullname: Araujo – volume: 85 start-page: 391 year: 2006 end-page: 399 ident: CR7 article-title: Influence of H-ZSM-5, Al-MCM-41 and acid hybrid ZSM-5/MCM-41 on polyethylene decomposition publication-title: J Therm Anal Calorim doi: 10.1007/s10973-006-7535-0 contributor: fullname: Ehen – volume: 255 start-page: 273 year: 1995 end-page: 280 ident: CR12 article-title: Kinetic-study of H-Y zeolite regeneration by thermogravimetry publication-title: Thermochim Acta doi: 10.1016/0040-6031(94)02131-7 contributor: fullname: Araújo – volume: 94 start-page: 727 year: 2008 end-page: 736 ident: CR2 article-title: Thermal degradation of polyethylene containing antioxidant and hydrophilic/hydrophobic silica publication-title: J Therm Anal Calorim doi: 10.1007/s10973-008-9362-y contributor: fullname: Laguta – ident: CR16 – volume: 79 start-page: 383 year: 2005 end-page: 387 ident: CR3 article-title: Application of model-free kinetics to the study of thermal degradation of polycarbonate publication-title: J Therm Anal Calorim doi: 10.1007/s10973-005-0070-6 contributor: fullname: Araujo – volume: 104 start-page: 9713 year: 2000 end-page: 9719 ident: CR14 article-title: Functionalized MCM-41 and CeMCM-41 materials synthesized via interfacial reactions publication-title: J Phys Chem B doi: 10.1021/jp0021648 contributor: fullname: Jaroniec – volume: 107 start-page: 507 year: 2005 end-page: 512 ident: CR9 article-title: Thermo gravimetric kinetics of polypropylene degradation on ZSM-12 and ZSM-5 catalysts publication-title: Catal Today doi: 10.1016/j.cattod.2005.07.065 contributor: fullname: Araujo – volume: 58–59 start-page: 173 year: 2001 end-page: 188 ident: CR1 article-title: Thermoanalytical and pyrolysis studies of nitrogen containing polymer publication-title: J Anal Appl Pyrol doi: 10.1016/S0165-2370(00)00193-5 contributor: fullname: Kettrup – volume: 95 start-page: 131 year: 2009 end-page: 134 ident: CR4 article-title: Degradation behavior and kinetic study of ABS polymer publication-title: J Therm Anal Calorim doi: 10.1007/s10973-006-7781-1 contributor: fullname: Fernandes – volume: 64 start-page: 585 year: 2001 end-page: 589 ident: CR8 article-title: Kinetic parameters of polymer degradation by SAPO-37 publication-title: J Therm Anal Calorim doi: 10.1023/A:1011511504478 contributor: fullname: Ionashiro – volume: 75 start-page: 233 year: 2002 end-page: 238 ident: CR10 article-title: Catalytic degradation of polyethylene over SAPO-37 molecular sieve publication-title: Catal Today doi: 10.1016/S0920-5861(02)00074-3 contributor: fullname: Araujo – volume: 176 start-page: 14 year: 1978 ident: CR17 article-title: Application of new kinetic techniques to lifetime prediction of polymers from weight-loss data publication-title: Abstr Pap ACS contributor: fullname: Dickens – volume: 92 start-page: 543 year: 2008 end-page: 552 ident: CR5 article-title: Influence of sample preparation on thermal decomposition of wasted polyolefins-oil mixtures publication-title: J Therm Anal Calorim doi: 10.1007/s10973-007-8690-7 contributor: fullname: Siudyga – volume: 56 start-page: 1279 year: 1999 end-page: 1282 ident: CR11 article-title: Kinetic parameters of polyethylene degradation by the natural zeolite chabazite publication-title: J Therm Anal Calorim doi: 10.1023/A:1010142003725 contributor: fullname: Melo – volume: 61 start-page: 110 year: 1957 ident: CR15 article-title: A function to aid in the fitting of kinetic data to a rate equation publication-title: J Phys Chem contributor: fullname: Flynn – volume: 64 start-page: 801 year: 2001 ident: 490_CR13 publication-title: J Therm Anal Calorim doi: 10.1023/A:1011564916290 contributor: fullname: SA Araujo – volume: 92 start-page: 543 year: 2008 ident: 490_CR5 publication-title: J Therm Anal Calorim doi: 10.1007/s10973-007-8690-7 contributor: fullname: A Mianowski – volume: 94 start-page: 727 year: 2008 ident: 490_CR2 publication-title: J Therm Anal Calorim doi: 10.1007/s10973-008-9362-y contributor: fullname: Y Bolbukh – volume: 95 start-page: 131 year: 2009 ident: 490_CR4 publication-title: J Therm Anal Calorim doi: 10.1007/s10973-006-7781-1 contributor: fullname: H Polli – volume: 255 start-page: 273 year: 1995 ident: 490_CR12 publication-title: Thermochim Acta doi: 10.1016/0040-6031(94)02131-7 contributor: fullname: VJ Fernandes – volume: 58–59 start-page: 173 year: 2001 ident: 490_CR1 publication-title: J Anal Appl Pyrol doi: 10.1016/S0165-2370(00)00193-5 contributor: fullname: M Herrera – volume: 79 start-page: 383 year: 2005 ident: 490_CR3 publication-title: J Therm Anal Calorim doi: 10.1007/s10973-005-0070-6 contributor: fullname: H Polli – volume: 104 start-page: 9713 year: 2000 ident: 490_CR14 publication-title: J Phys Chem B doi: 10.1021/jp0021648 contributor: fullname: V Antochshuk – volume: 64 start-page: 585 year: 2001 ident: 490_CR8 publication-title: J Therm Anal Calorim doi: 10.1023/A:1011511504478 contributor: fullname: VJ Fernandes – volume: 56 start-page: 1279 year: 1999 ident: 490_CR11 publication-title: J Therm Anal Calorim doi: 10.1023/A:1010142003725 contributor: fullname: VJ Fernandes – volume: 60 start-page: 2682 year: 2006 ident: 490_CR6 publication-title: Mater Lett doi: 10.1016/j.matlet.2006.01.066 contributor: fullname: MJB Souza – volume: 176 start-page: 14 year: 1978 ident: 490_CR17 publication-title: Abstr Pap ACS contributor: fullname: JH Flynn – volume: 283 start-page: 35 year: 1996 ident: 490_CR18 publication-title: Thermochim Acta doi: 10.1016/0040-6031(95)02804-8 contributor: fullname: JH Flynn – volume: 75 start-page: 233 year: 2002 ident: 490_CR10 publication-title: Catal Today doi: 10.1016/S0920-5861(02)00074-3 contributor: fullname: GJT Fernandes – volume: 107 start-page: 507 year: 2005 ident: 490_CR9 publication-title: Catal Today doi: 10.1016/j.cattod.2005.07.065 contributor: fullname: JGA Pacheco – volume: 61 start-page: 110 year: 1957 ident: 490_CR15 publication-title: J Phys Chem doi: 10.1021/j150547a024 contributor: fullname: JH Flynn – ident: 490_CR16 doi: 10.1002/pol.1967.110050211 – volume: 85 start-page: 391 year: 2006 ident: 490_CR7 publication-title: J Therm Anal Calorim doi: 10.1007/s10973-006-7535-0 contributor: fullname: FSM Sinfronio
SSID	ssib021069589 ssj0009901 ssib021656697 ssib053395279
Score	2.0082834
Snippet	The aim of this work is to determine the activation energy for the thermal decomposition of poly(ethylene terephthalate)—PET, in the presence of a MCM-41... The aim of this work is to determine the activation energy for the thermal decomposition of poly (ethylene terephthalate)--PET, in the presence of a MCM-41... The aim of this work is to determine the activation energy for the thermal decomposition of poly(ethylene terephthalate)--PET, in the presence of a MCM-41...
SourceID	proquest gale crossref pascalfrancis springer
SourceType	Aggregation Database Index Database Publisher
StartPage	465
SubjectTerms	Activation energy Analysis Analytical Chemistry Applied sciences Calorimetry Catalysts Chemical reactions and properties Chemistry Chemistry and Materials Science Degradation Ethylene Exact sciences and technology Inorganic Chemistry Measurement Science and Instrumentation Organic polymers Physical Chemistry Physicochemistry of polymers Polyethylene terephthalates Polymer Sciences Polymers Reaction kinetics Thermal decomposition Thermal degradation Thermogravimetry Toy industry
Title	Effect of the catalyst MCM-41 on the kinetic of the thermal decomposition of poly(ethylene terephthalate)
URI	https://link.springer.com/article/10.1007/s10973-009-0490-9 https://search.proquest.com/docview/963843029
Volume	99
hasFullText	1
inHoldings	1
isFullTextHit
isPrint
link	http://sdu.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1Lb9QwELZoewAJ8UYsjypCSLxk5NqOEx-XZVdbRCtEQeJmOX5Q1JKsNtlD_z0zm7jLIjjAKVIySpyZyfgbz-QzIc8Yd95JXVGbV4FKzRytCi-p8F4zmyttI67pzk-K46_luynS5PDLpYv67E2qSK4D9S__uulC0H4tXzOqd8geTD05-PbeePp-_iF5EeQwSucbDnWO_DJqUysDfKNzjrWpRM2rWZ-Wgc8gPXqqff7poVuz1xDDry9sC_qM_UYYW0j1t-Lqes6a3fyft71FbgwINRv3LnWbXAn1HXJ1kjaGu0u-94zHWRMzQI_ZegHoou2yo8kRlQdZU69PnwF8hTskKcSZP-C2PmAT-9AphhcXzfnFiwDuAtMfiIVlWJx2p_YcMPDLe-TLbPp5MqfDjg3UScU6DK1gXKGs9K6qlAdjM-2cL8AfStC59rGImodgy6CEOyitdNEFAUlTZEFGcZ_s1k0dHpAslEEqbJFmFWSIoqgsVxVHuj3sG7DliLxKljCLnpjDbCiYUXsGtGdQe0aPyFO0lUHCixo7ar7ZVduaw5NPZixyTDm54iPyfBCKTbe0zg4_KMB4kCNrS3J_y-aXA0A8BPhTjUiWnMCAcbAGY-vQrFqD8U4KxmFIr5PlzRA22r-_wMN_kn5ErvVNDth185jsdstVeEJ2Wr_aHz4WOM4Oj99-_AkiLwpu
link.rule.ids	315,782,786,27933,27934,41073,42142,48344,48347,48357,49649,49652,49662,52153
linkProvider	Springer Nature
linkToHtml	http://sdu.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1Lb9QwELbo9lAkxBuxPEqEkHhUllzbceLjattqK7o90CK1J8uxHYooyWqTPfTfM5PELIvgANdklDgzk_E3nvFnQt4w7ryTuqA2LQKVmjlaZF5S4b1mNlXalrimOzvLTi_yg0OkyRFxL0zX7R5Lkl2k_mWzm84E7RfzNaN6i2wj2Tkfke3JxeXlQXQjSGKUTtck6hwJZtS6WAYAR6cci1ORm1ezPi8Dp0F-9Fj8_NNLN6avIYjfWdgGFFr2J2FsQNXfqqvdpHV0778-9z65O2DUZNI71QNyK1QPyc40Hg33iHztOY-TukwAPybdEtBN0ybz6ZzK_aSuusvfAMDCE6IUIs3v8FgfsI196BXDm4v6-uZdAIeBCRDEwjIsrtorew0o-P1j8vno8Hw6o8OZDdRJxVoMrmBeoaz0riiUB3Mz7ZzPwCNyULr2ZVZqHoLNgxJuP7fSlS4ISJtKFmQpnpBRVVfhKUlCHqTCJmlWQI4ossJyVXAk3MPOAZuPyYdoCrPoqTnMmoQZtWdAewa1Z_SYvEZjGaS8qLCn5otdNY05PvtkJiLFpJMrPiZvB6GybpfW2WGLAowHWbI2JHc3jP5zAIiIAIGqMUmiFxgwDlZhbBXqVWMw4knBOAxpL1reDIGj-fsHPPsn6VdkZ3Y-PzEnx6cfn5PbfcsD9uC8IKN2uQovyVbjV7vDn_MDHSgNDg
linkToPdf	http://sdu.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1Lb9QwEB7RrQRIiDdieZQIIfFSVDdxnPiEVtsuXUErRIvEzXL8oIiSRJvsof-emU3MsggOiGsyShzPF_sbz_gzwDOWGGu4LGOdlS7mkpm4zC2PU2sl05mQ2tOa7uFJfvy52D8gmZw3YS_Mqto9pCT7PQ2k0lR1u431u79sfJN5GvcL-5LFcgu2aVWMj2B7Mj99OwuQwoBGyGwtqJ6Q2IxYJ86Q7MgsoURV0OmVrI_REECklR4SoX966cZUNgzo1xrdYuf6_lSMDdr6W6Z1NYHNbvz3p9-E6wN3jSY92G7BJVfdhivTcGTcHfjaayFHtY-QV0arpaGLtouOpkcx34vqanX5GxJbfEKwIgb6HR9rHZW3DzVkdLOpzy9eOAQSToxo5hauOevO9Dmy45d34dPs4HR6GA9nOcSGC9bRoItuT4Xm1pSlsAgDJo2xOSKlQAdI63MvE-d04URq9grNjTcuxXDKM8d9eg9GVV25-xC5wnFBxdOsxNgxzUudiDIhIT6qKNDFGF4Ft6iml-xQa3Fm6j2Fvaeo95Qcw1NynCIpjIpqbb7oZduq-clHNUkzCkYTkYzh-WDk626hjR62LmB7SD1rw3JnAwA_G0BMCZmpGEMUEKHQOZSd0ZWrl62ikZCnLMEmvQ4oUMOA0v79Ax78k_UTuPxhf6bez4_fPYSrfSUEleY8glG3WLrHsNXa5c7wE_0Ax2cVpQ
openUrl	ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Effect+of+the+catalyst+MCM-41+on+the+kinetic+of+the+thermal+decomposition+of+poly%28ethylene+terephthalate%29&rft.jtitle=Journal+of+thermal+analysis+and+calorimetry&rft.au=Ara%C3%BAjo%2C+Sulene+A.&rft.au=Araujo%2C+Antonio+S.&rft.au=Fernandes%2C+Nedja+S.&rft.au=Fernandes%2C+Valter+J.&rft.date=2010-02-01&rft.pub=Springer+Netherlands&rft.issn=1388-6150&rft.eissn=1588-2926&rft.volume=99&rft.issue=2&rft.spage=465&rft.epage=469&rft_id=info:doi/10.1007%2Fs10973-009-0490-9&rft.externalDocID=10_1007_s10973_009_0490_9
thumbnail_l	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1388-6150&client=summon
thumbnail_m	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1388-6150&client=summon
thumbnail_s	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1388-6150&client=summon