Cyclization of Terphenyl‐Bisfluorenols: A Mechanistic Study of the Regioselectvity
The mechanism of the bicyclization reaction of a series of terphenyl‐bisfluorenols into dispiro[fluorene‐9,6′‐indeno[1,2‐b]fluorene‐12′,9′′‐fluorene] and dispiro[fluorene‐9,6′‐indeno[2,1‐a]fluorene‐12′,9′′‐fluorene] is reported. Through a combined experimental and theoretical study, the different pa...
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| Published in: | Chemistry : a European journal Vol. 25; no. 45; pp. 10689 - 10697 |
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| Abstract | The mechanism of the bicyclization reaction of a series of terphenyl‐bisfluorenols into dispiro[fluorene‐9,6′‐indeno[1,2‐b]fluorene‐12′,9′′‐fluorene] and dispiro[fluorene‐9,6′‐indeno[2,1‐a]fluorene‐12′,9′′‐fluorene] is reported. Through a combined experimental and theoretical study, the different parameters that drive the regioselectivity of this cyclization reaction have been studied and are presented.
How to upgrade your bicycle: Through a combined experimental and theoretical study, the mechanism of the bicyclization reaction for a series of terphenyl‐bisfluorenols into dispirofluorene—indenofluorene derivatives is reported. In particular, the different parameters that drive the regioselectivity of this double cyclization reaction were studied and are presented. |
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| AbstractList | The mechanism of the bicyclization reaction of a series of terphenyl‐bisfluorenols into dispiro[fluorene‐9,6′‐indeno[1,2‐b]fluorene‐12′,9′′‐fluorene] and dispiro[fluorene‐9,6′‐indeno[2,1‐a]fluorene‐12′,9′′‐fluorene] is reported. Through a combined experimental and theoretical study, the different parameters that drive the regioselectivity of this cyclization reaction have been studied and are presented.
How to upgrade your bicycle: Through a combined experimental and theoretical study, the mechanism of the bicyclization reaction for a series of terphenyl‐bisfluorenols into dispirofluorene—indenofluorene derivatives is reported. In particular, the different parameters that drive the regioselectivity of this double cyclization reaction were studied and are presented. The mechanism of the bicyclization reaction of a series of terphenyl-bisfluorenols into dispiro[fluorene-9,6'-indeno[1,2-b]fluorene-12',9''-fluorene] and dispiro[fluorene-9,6'-indeno[2,1-a]fluorene-12',9''-fluorene] is reported. Through a combined experimental and theoretical study, the different parameters that drive the regioselectivity of this cyclization reaction have been studied and are presented. The mechanism of the bicyclization reaction of a series of terphenyl‐bisfluorenols into dispiro[fluorene‐9,6′‐indeno[1,2‐ b ]fluorene‐12′,9′′‐fluorene] and dispiro[fluorene‐9,6′‐indeno[2,1‐ a ]fluorene‐12′,9′′‐fluorene] is reported. Through a combined experimental and theoretical study, the different parameters that drive the regioselectivity of this cyclization reaction have been studied and are presented. |
| Author | Rault‐Berthelot, Joëlle Poriel, Cyril Barrière, Frédéric Thirion, Damien |
| Author_xml | – sequence: 1 givenname: Cyril orcidid: 0000-0002-6036-1778 surname: Poriel fullname: Poriel, Cyril email: cyril.poriel@univ-rennes1.fr organization: Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques Rennes), UMR 6226 – sequence: 2 givenname: Frédéric orcidid: 0000-0001-5515-4080 surname: Barrière fullname: Barrière, Frédéric email: frederic.barriere@univ-rennes1.fr organization: Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques Rennes), UMR 6226 – sequence: 3 givenname: Joëlle surname: Rault‐Berthelot fullname: Rault‐Berthelot, Joëlle organization: Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques Rennes), UMR 6226 – sequence: 4 givenname: Damien surname: Thirion fullname: Thirion, Damien organization: Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques Rennes), UMR 6226 |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/31087579$$D View this record in MEDLINE/PubMed |
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| Keywords | reaction mechanisms fluorenol fluorenes cyclization spiro compounds |
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| Snippet | The mechanism of the bicyclization reaction of a series of terphenyl‐bisfluorenols into dispiro[fluorene‐9,6′‐indeno[1,2‐b]fluorene‐12′,9′′‐fluorene] and... The mechanism of the bicyclization reaction of a series of terphenyl-bisfluorenols into dispiro[fluorene-9,6'-indeno[1,2-b]fluorene-12',9''-fluorene] and... The mechanism of the bicyclization reaction of a series of terphenyl‐bisfluorenols into dispiro[fluorene‐9,6′‐indeno[1,2‐ b ]fluorene‐12′,9′′‐fluorene] and... |
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| StartPage | 10689 |
| SubjectTerms | Chemistry cyclization Fluorene fluorenes fluorenol reaction mechanisms Regioselectivity spiro compounds |
| Title | Cyclization of Terphenyl‐Bisfluorenols: A Mechanistic Study of the Regioselectvity |
| URI | https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fchem.201901457 https://www.ncbi.nlm.nih.gov/pubmed/31087579 https://www.proquest.com/docview/2269896266 https://search.proquest.com/docview/2231998127 |
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