Synthesis of oligo(ethylene glycol) methacrylate polymer brushes

Here we report a study into controlling the polymerization of mono-hydroxy and mono-methoxy terminated oligo(ethylene glycol) methacrylates (HOEGMA and MeOEGMA, respectively) from functionalised, planar surfaces via atom transfer radical polymerization (ATRP). The effects of initiator structure, ini...

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Bibliographic Details
Published in:	European polymer journal Vol. 41; no. 8; pp. 1757 - 1765
Main Authors:	Brown, Andrew A., Khan, Neelam S., Steinbock, Lorenz, Huck, Wilhelm T.S.
Format:	Journal Article
Language:	English
Published:	Oxford Elsevier Ltd 01-08-2005 Elsevier
Subjects:	Applied sciences Atom transfer radical polymerization (ATRP) Exact sciences and technology Organic polymers Physicochemistry of polymers Poly(oligo(ethylene glycol) methacrylate) (POEGMA) Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts Protein resistance Protein resistance Atom transfer radical polymerization (ATRP) Poly(oligo(ethylene glycol) methacrylate) (POEGMA) Biological properties Surface reaction Graft copolymer Liquid solid adsorption Atom transfer polymerization Polymer brush Ethylene oxide copolymer Experimental study Protein Macromer Ethylene oxide polymer Monodispersed polymer Preparation Silicon Kinetics Methacrylate copolymer Activation energy
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