Carbon nanotube–quantum dot nanocomposites as new fluorescence nanoparticles for the determination of trace levels of PAHs in water

Amplification of fluorescence is a nanoscale phenomenon which is particularly pronounced in close proximity to metal nanostructures. We have demonstrated for first time that fluorescence amplification can also be produced by single-walled carbon nanotube–quantum dot nanocomposites (SWCNT–QDs). Concr...

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Published in:Analytica chimica acta Vol. 652; no. 1; pp. 278 - 284
Main Authors: Carrillo-Carrión, Carolina, Simonet, Bartolomé M., Valcárcel, Miguel
Format: Journal Article
Language:English
Published: Netherlands Elsevier B.V 12-10-2009
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Abstract Amplification of fluorescence is a nanoscale phenomenon which is particularly pronounced in close proximity to metal nanostructures. We have demonstrated for first time that fluorescence amplification can also be produced by single-walled carbon nanotube–quantum dot nanocomposites (SWCNT–QDs). Concretely we exploit the adsorption capabilities of SWCNTs to facilitate the interaction of analytes with the nanoparticle. The fluorescence amplification mechanism is discussed in the paper. The analytical potential of these nanocomposites has been demonstrated for the detection of trace levels of polycyclic aromatic compounds (PAHs) in river water samples. Compared with QDs nanoparticles, the fluorescence enhancement achieved with the SWCNT–QDs nanocomposites was 3.6–5.5 times higher.
AbstractList Amplification of fluorescence is a nanoscale phenomenon which is particularly pronounced in close proximity to metal nanostructures. We have demonstrated for first time that fluorescence amplification can also be produced by single-walled carbon nanotube-quantum dot nanocomposites (SWCNT-QDs). Concretely we exploit the adsorption capabilities of SWCNTs to facilitate the interaction of analytes with the nanoparticle. The fluorescence amplification mechanism is discussed in the paper. The analytical potential of these nanocomposites has been demonstrated for the detection of trace levels of polycyclic aromatic compounds (PAHs) in river water samples. Compared with QDs nanoparticles, the fluorescence enhancement achieved with the SWCNT-QDs nanocomposites was 3.6-5.5 times higher.
Author Simonet, Bartolomé M.
Carrillo-Carrión, Carolina
Valcárcel, Miguel
Author_xml – sequence: 1
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  surname: Valcárcel
  fullname: Valcárcel, Miguel
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BackLink https://www.ncbi.nlm.nih.gov/pubmed/19786193$$D View this record in MEDLINE/PubMed
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Issue 1
Keywords Carbon nanotubes
Nanocomposites
Quantum dots
River water samples
Fluorescence amplification polycyclic aromatic hydrocarbons (PAHs)
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SubjectTerms Amplification
Carbon
Carbon nanotubes
Fluorescence
Fluorescence amplification polycyclic aromatic hydrocarbons (PAHs)
Freshwater
Mathematical analysis
Nanocomposites
Nanomaterials
Nanoparticles
Nanostructure
Quantum dots
River water samples
Title Carbon nanotube–quantum dot nanocomposites as new fluorescence nanoparticles for the determination of trace levels of PAHs in water
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