Carbon nanotube–quantum dot nanocomposites as new fluorescence nanoparticles for the determination of trace levels of PAHs in water
Amplification of fluorescence is a nanoscale phenomenon which is particularly pronounced in close proximity to metal nanostructures. We have demonstrated for first time that fluorescence amplification can also be produced by single-walled carbon nanotube–quantum dot nanocomposites (SWCNT–QDs). Concr...
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Published in: | Analytica chimica acta Vol. 652; no. 1; pp. 278 - 284 |
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12-10-2009
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Abstract | Amplification of fluorescence is a nanoscale phenomenon which is particularly pronounced in close proximity to metal nanostructures. We have demonstrated for first time that fluorescence amplification can also be produced by single-walled carbon nanotube–quantum dot nanocomposites (SWCNT–QDs). Concretely we exploit the adsorption capabilities of SWCNTs to facilitate the interaction of analytes with the nanoparticle. The fluorescence amplification mechanism is discussed in the paper. The analytical potential of these nanocomposites has been demonstrated for the detection of trace levels of polycyclic aromatic compounds (PAHs) in river water samples. Compared with QDs nanoparticles, the fluorescence enhancement achieved with the SWCNT–QDs nanocomposites was 3.6–5.5 times higher. |
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AbstractList | Amplification of fluorescence is a nanoscale phenomenon which is particularly pronounced in close proximity to metal nanostructures. We have demonstrated for first time that fluorescence amplification can also be produced by single-walled carbon nanotube-quantum dot nanocomposites (SWCNT-QDs). Concretely we exploit the adsorption capabilities of SWCNTs to facilitate the interaction of analytes with the nanoparticle. The fluorescence amplification mechanism is discussed in the paper. The analytical potential of these nanocomposites has been demonstrated for the detection of trace levels of polycyclic aromatic compounds (PAHs) in river water samples. Compared with QDs nanoparticles, the fluorescence enhancement achieved with the SWCNT-QDs nanocomposites was 3.6-5.5 times higher. |
Author | Simonet, Bartolomé M. Carrillo-Carrión, Carolina Valcárcel, Miguel |
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BackLink | https://www.ncbi.nlm.nih.gov/pubmed/19786193$$D View this record in MEDLINE/PubMed |
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Cites_doi | 10.1021/nl0259683 10.1021/jp065176n 10.1007/s12274-008-8011-x 10.1021/nl071225b 10.1039/b404204b 10.1021/nl015651n 10.1021/nl025799m 10.1002/adma.200306100 10.1016/j.matlet.2006.03.057 10.1021/ja0550733 10.1021/nl048498g |
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Keywords | Carbon nanotubes Nanocomposites Quantum dots River water samples Fluorescence amplification polycyclic aromatic hydrocarbons (PAHs) |
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SubjectTerms | Amplification Carbon Carbon nanotubes Fluorescence Fluorescence amplification polycyclic aromatic hydrocarbons (PAHs) Freshwater Mathematical analysis Nanocomposites Nanomaterials Nanoparticles Nanostructure Quantum dots River water samples |
Title | Carbon nanotube–quantum dot nanocomposites as new fluorescence nanoparticles for the determination of trace levels of PAHs in water |
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