Solar photocatalytic degradation of azo dye: comparison of photocatalytic efficiency of ZnO and TiO2

• Published in: Solar energy materials and solar cells Vol. 77; no. 1; pp. 65 - 82
• Main Authors: SAKTHIVEL, S, NEPPOLIAN, B, SHANKAR, M. V, ARABINDOO, B, PALANICHAMY, M, MURUGESAN, V
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier 30-04-2003
• Subjects: Chemistry; Exact sciences and technology; General and physical chemistry; Photochemistry; Physical chemistry of induced reactions (with radiations, particles and ultrasonics); Photocatalysis; Degradation; Acid brown 14; Azo dye; Water pollution control; Solar energy; Zinc oxide; ZnO; Waste water purification; Titanium oxide; Comparative study; Organic compounds; Photochemical degradation; TiO2
• ISSN: 0927-0248; 1879-3398
• DOI: 10.1016/s0927-0248(02)00255-6

The photocatalytic activity of commercial ZnO powder has been investigated and compared with that of Degussa P25 TiO2. Laboratory experiments with acid brown 14 as the model pollutant have been carried out to evaluate the performance of both ZnO and TiO2 catalysts. Solar light was used as the energy source for the photocatalytic experiments. These catalysts were examined for surface area, particle size and crystallinity. The effect of initial dye concentration, catalyst loading, irradiation time, pH, adsorption of acid brown 14 on ZnO and TiO2, intensity of light and comparison of photocatalytic activity with different commercial catalysts were studied. The progress of photocatalytic degradation of the acid brown 14 has been observed by monitoring the change in substrate concentration of the model compound employing HPLC and measuring the absorbance in UV-Visible spectrophotometer for decolourisation. The photodegradation rate was determined for each experiment and the highest values were observed for ZnO suggesting that it absorbs large fraction of the solar spectrum and absorption of more light quanta than TiO2. The complete mineralisation was confirmed by total organic carbon (TOC) analysis, COD measurement and estimation of the formation of inorganic ions such as NH4+, NO3-, Cl- and SO42-. 40 refs.