Controlled fabrication of multilayered 4-(pyrrole-1-yl) benzoate supported poly(3,4-ethylenedioxythiophene) linked hybrid films of Prussian blue type nickel hexacyanoferrate

The ability of 4-(pyrrole-1-yl) benzoic acid (PyBA) to form monolayer-type carboxylate-derivatized ultra-thin organic films on solid electrode surfaces was explored here to attract coordinatively and immobilize Ni 2+ ions at the electrode/electrolyte interface. In the next step, the system was expos...

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Published in:Electrochimica acta Vol. 53; no. 3; pp. 1235 - 1243
Main Authors: Makowski, Oktawian, Kowalewska, Barbara, Szymanska, Dorota, Stroka, Jadwiga, Miecznikowski, Krzysztof, Palys, Barbara, Malik, Marcin A., Kulesza, Pawel J.
Format: Journal Article Conference Proceeding
Language:English
Published: Oxford Elsevier Ltd 20-12-2007
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Abstract The ability of 4-(pyrrole-1-yl) benzoic acid (PyBA) to form monolayer-type carboxylate-derivatized ultra-thin organic films on solid electrode surfaces was explored here to attract coordinatively and immobilize Ni 2+ ions at the electrode/electrolyte interface. In the next step, the system was exposed to Fe(CN) 6 3− or Fe(CN) 6 4− solution to form a robust nickel hexacyanoferrate (NiHCF) layer. By repeated and alternate treatments in solutions of PyBA, Ni 2+ cations, and Fe(CN) 6 3− or Fe(CN) 6 4− anions, the amount of the material could be increased systematically in a controlled fashion to form three-dimensional multilayered NiHCF-based assemblies. The layer-by-layer method was also extended to the growth of hybrid conducting polymer stabilized NiHCF films in which the initial PyBA-anchored NiHCF layer (formed on glassy carbon) was subsequently exposed (a desired number of times) through alternate immersions to the monomer (3,4-ethylenedioxythiophene), Fe(CN) 6 3− and Ni 2+ solutions. During voltammetric potential cycling (electropolymerization) in the external supporting electrolyte solution, poly(3,4-ethylenedioxythiophene) or PEDOT linked NiHCF-based multilayered films were produced. They were characterized by good stability and high dynamics of charge transport.
AbstractList The ability of 4-(pyrrole-1-yl) benzoic acid (PyBA) to form monolayer-type carboxylate-derivatized ultra-thin organic films on solid electrode surfaces was explored here to attract coordinatively and immobilize Ni 2+ ions at the electrode/electrolyte interface. In the next step, the system was exposed to Fe(CN) 6 3− or Fe(CN) 6 4− solution to form a robust nickel hexacyanoferrate (NiHCF) layer. By repeated and alternate treatments in solutions of PyBA, Ni 2+ cations, and Fe(CN) 6 3− or Fe(CN) 6 4− anions, the amount of the material could be increased systematically in a controlled fashion to form three-dimensional multilayered NiHCF-based assemblies. The layer-by-layer method was also extended to the growth of hybrid conducting polymer stabilized NiHCF films in which the initial PyBA-anchored NiHCF layer (formed on glassy carbon) was subsequently exposed (a desired number of times) through alternate immersions to the monomer (3,4-ethylenedioxythiophene), Fe(CN) 6 3− and Ni 2+ solutions. During voltammetric potential cycling (electropolymerization) in the external supporting electrolyte solution, poly(3,4-ethylenedioxythiophene) or PEDOT linked NiHCF-based multilayered films were produced. They were characterized by good stability and high dynamics of charge transport.
The ability of 4-(pyrrole-1-yl) benzoic acid (PyBA) to form monolayer-type carboxylate-derivatized ultra-thin organic films on solid electrode surfaces was explored here to attract coordinatively and immobilize Ni2+ ions at the electrode/electrolyte interface. In the next step, the system was exposed to Fe(CN)63- or Fe(CN)64- solution to form a robust nickel hexacyanoferrate (NiHCF) layer. By repeated and alternate treatments in solutions of PyBA, Ni2+ cations, and Fe(CN)63- or Fe(CN)64- anions, the amount of the material could be increased systematically in a controlled fashion to form three-dimensional multilayered NiHCF-based assemblies. The layer-by-layer method was also extended to the growth of hybrid conducting polymer stabilized NiHCF films in which the initial PyBA-anchored NiHCF layer (formed on glassy carbon) was subsequently exposed (a desired number of times) through alternate immersions to the monomer (3,4-ethylenedioxythiophene), Fe(CN)63- and Ni2+ solutions. During voltammetric potential cycling (electropolymerization) in the external supporting electrolyte solution, poly(3,4-ethylenedioxythiophene) or PEDOT linked NiHCF-based multilayered films were produced. They were characterized by good stability and high dynamics of charge transport.
Author Stroka, Jadwiga
Kowalewska, Barbara
Szymanska, Dorota
Palys, Barbara
Malik, Marcin A.
Miecznikowski, Krzysztof
Kulesza, Pawel J.
Makowski, Oktawian
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  givenname: Marcin A.
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  givenname: Pawel J.
  surname: Kulesza
  fullname: Kulesza, Pawel J.
  email: pkulesza@chem.uw.edu.pl
  organization: Department of Chemistry, University of Warsaw, Pasteura 1, PL-02-093 Warsaw, Poland
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Issue 3
Keywords Layer-by-layer growth
Nickel hexacyanoferrate
4-(Pyrrole-1-yl) benzoic acid template
Poly(3,4-ethylenedioxythiophene) inter-layers
Composite films
Self-assembled layer
Scanning electron microscopy
Nickel Hexacyanoferrates
Carbon
Composite material
Pyrrole derivatives
Surface structure
Electrodes
Conducting polymers
Thiophene derivative polymer
Mixed multilayer
Morphology
Preparation
Glassy state
Language English
License CC BY 4.0
LinkModel OpenURL
MeetingName Innovative electrochemistry enterprising science: selection of papers from the 57th annual meeting of the International Society of Electrochemistry, 27 August-1 September 2006, Edinburgh, UK
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SSID ssj0007670
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Snippet The ability of 4-(pyrrole-1-yl) benzoic acid (PyBA) to form monolayer-type carboxylate-derivatized ultra-thin organic films on solid electrode surfaces was...
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SubjectTerms 4-(Pyrrole-1-yl) benzoic acid template
Chemistry
Composite films
Electrochemistry
Electrodes: preparations and properties
Exact sciences and technology
General and physical chemistry
Layer-by-layer growth
Nickel hexacyanoferrate
Other electrodes
Poly(3,4-ethylenedioxythiophene) inter-layers
Title Controlled fabrication of multilayered 4-(pyrrole-1-yl) benzoate supported poly(3,4-ethylenedioxythiophene) linked hybrid films of Prussian blue type nickel hexacyanoferrate
URI https://dx.doi.org/10.1016/j.electacta.2007.02.083
https://search.proquest.com/docview/30940803
Volume 53
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