Controlled fabrication of multilayered 4-(pyrrole-1-yl) benzoate supported poly(3,4-ethylenedioxythiophene) linked hybrid films of Prussian blue type nickel hexacyanoferrate
The ability of 4-(pyrrole-1-yl) benzoic acid (PyBA) to form monolayer-type carboxylate-derivatized ultra-thin organic films on solid electrode surfaces was explored here to attract coordinatively and immobilize Ni 2+ ions at the electrode/electrolyte interface. In the next step, the system was expos...
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Published in: | Electrochimica acta Vol. 53; no. 3; pp. 1235 - 1243 |
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Abstract | The ability of 4-(pyrrole-1-yl) benzoic acid (PyBA) to form monolayer-type carboxylate-derivatized ultra-thin organic films on solid electrode surfaces was explored here to attract coordinatively and immobilize Ni
2+ ions at the electrode/electrolyte interface. In the next step, the system was exposed to Fe(CN)
6
3− or Fe(CN)
6
4− solution to form a robust nickel hexacyanoferrate (NiHCF) layer. By repeated and alternate treatments in solutions of PyBA, Ni
2+ cations, and Fe(CN)
6
3− or Fe(CN)
6
4− anions, the amount of the material could be increased systematically in a controlled fashion to form three-dimensional multilayered NiHCF-based assemblies. The layer-by-layer method was also extended to the growth of hybrid conducting polymer stabilized NiHCF films in which the initial PyBA-anchored NiHCF layer (formed on glassy carbon) was subsequently exposed (a desired number of times) through alternate immersions to the monomer (3,4-ethylenedioxythiophene), Fe(CN)
6
3− and Ni
2+ solutions. During voltammetric potential cycling (electropolymerization) in the external supporting electrolyte solution, poly(3,4-ethylenedioxythiophene) or PEDOT linked NiHCF-based multilayered films were produced. They were characterized by good stability and high dynamics of charge transport. |
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AbstractList | The ability of 4-(pyrrole-1-yl) benzoic acid (PyBA) to form monolayer-type carboxylate-derivatized ultra-thin organic films on solid electrode surfaces was explored here to attract coordinatively and immobilize Ni
2+ ions at the electrode/electrolyte interface. In the next step, the system was exposed to Fe(CN)
6
3− or Fe(CN)
6
4− solution to form a robust nickel hexacyanoferrate (NiHCF) layer. By repeated and alternate treatments in solutions of PyBA, Ni
2+ cations, and Fe(CN)
6
3− or Fe(CN)
6
4− anions, the amount of the material could be increased systematically in a controlled fashion to form three-dimensional multilayered NiHCF-based assemblies. The layer-by-layer method was also extended to the growth of hybrid conducting polymer stabilized NiHCF films in which the initial PyBA-anchored NiHCF layer (formed on glassy carbon) was subsequently exposed (a desired number of times) through alternate immersions to the monomer (3,4-ethylenedioxythiophene), Fe(CN)
6
3− and Ni
2+ solutions. During voltammetric potential cycling (electropolymerization) in the external supporting electrolyte solution, poly(3,4-ethylenedioxythiophene) or PEDOT linked NiHCF-based multilayered films were produced. They were characterized by good stability and high dynamics of charge transport. The ability of 4-(pyrrole-1-yl) benzoic acid (PyBA) to form monolayer-type carboxylate-derivatized ultra-thin organic films on solid electrode surfaces was explored here to attract coordinatively and immobilize Ni2+ ions at the electrode/electrolyte interface. In the next step, the system was exposed to Fe(CN)63- or Fe(CN)64- solution to form a robust nickel hexacyanoferrate (NiHCF) layer. By repeated and alternate treatments in solutions of PyBA, Ni2+ cations, and Fe(CN)63- or Fe(CN)64- anions, the amount of the material could be increased systematically in a controlled fashion to form three-dimensional multilayered NiHCF-based assemblies. The layer-by-layer method was also extended to the growth of hybrid conducting polymer stabilized NiHCF films in which the initial PyBA-anchored NiHCF layer (formed on glassy carbon) was subsequently exposed (a desired number of times) through alternate immersions to the monomer (3,4-ethylenedioxythiophene), Fe(CN)63- and Ni2+ solutions. During voltammetric potential cycling (electropolymerization) in the external supporting electrolyte solution, poly(3,4-ethylenedioxythiophene) or PEDOT linked NiHCF-based multilayered films were produced. They were characterized by good stability and high dynamics of charge transport. |
Author | Stroka, Jadwiga Kowalewska, Barbara Szymanska, Dorota Palys, Barbara Malik, Marcin A. Miecznikowski, Krzysztof Kulesza, Pawel J. Makowski, Oktawian |
Author_xml | – sequence: 1 givenname: Oktawian surname: Makowski fullname: Makowski, Oktawian organization: Department of Chemistry, University of Warsaw, Pasteura 1, PL-02-093 Warsaw, Poland – sequence: 2 givenname: Barbara surname: Kowalewska fullname: Kowalewska, Barbara organization: Department of Chemistry, University of Warsaw, Pasteura 1, PL-02-093 Warsaw, Poland – sequence: 3 givenname: Dorota surname: Szymanska fullname: Szymanska, Dorota organization: Department of Chemistry, University of Warsaw, Pasteura 1, PL-02-093 Warsaw, Poland – sequence: 4 givenname: Jadwiga surname: Stroka fullname: Stroka, Jadwiga organization: Department of Chemistry, University of Warsaw, Pasteura 1, PL-02-093 Warsaw, Poland – sequence: 5 givenname: Krzysztof surname: Miecznikowski fullname: Miecznikowski, Krzysztof organization: Department of Chemistry, University of Warsaw, Pasteura 1, PL-02-093 Warsaw, Poland – sequence: 6 givenname: Barbara surname: Palys fullname: Palys, Barbara organization: Department of Chemistry, University of Warsaw, Pasteura 1, PL-02-093 Warsaw, Poland – sequence: 7 givenname: Marcin A. surname: Malik fullname: Malik, Marcin A. organization: Division of Chemistry, Department of Processing & Materials Engineering and Applied Physics, Czestochowa University of Technology, Al. Armii Krajowej 19, 42-201 Czestochowa, Poland – sequence: 8 givenname: Pawel J. surname: Kulesza fullname: Kulesza, Pawel J. email: pkulesza@chem.uw.edu.pl organization: Department of Chemistry, University of Warsaw, Pasteura 1, PL-02-093 Warsaw, Poland |
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Keywords | Layer-by-layer growth Nickel hexacyanoferrate 4-(Pyrrole-1-yl) benzoic acid template Poly(3,4-ethylenedioxythiophene) inter-layers Composite films Self-assembled layer Scanning electron microscopy Nickel Hexacyanoferrates Carbon Composite material Pyrrole derivatives Surface structure Electrodes Conducting polymers Thiophene derivative polymer Mixed multilayer Morphology Preparation Glassy state |
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SubjectTerms | 4-(Pyrrole-1-yl) benzoic acid template Chemistry Composite films Electrochemistry Electrodes: preparations and properties Exact sciences and technology General and physical chemistry Layer-by-layer growth Nickel hexacyanoferrate Other electrodes Poly(3,4-ethylenedioxythiophene) inter-layers |
Title | Controlled fabrication of multilayered 4-(pyrrole-1-yl) benzoate supported poly(3,4-ethylenedioxythiophene) linked hybrid films of Prussian blue type nickel hexacyanoferrate |
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