Growth and physicochemical properties of second-order nonlinear optical 2-amino-5-chloropyridinium trichloroacetate single crystals

• Published in: Phase transitions Vol. 88; no. 9; pp. 877 - 887
• Main Authors: Renugadevi, R., Kesavasamy, R.
• Format: Journal Article
• Language: English
• Published: Abingdon Taylor & Francis 02-09-2015; Taylor & Francis Ltd
• Subjects: Crystals; Devices; Diffraction; Fourier transforms; Methyl alcohol; NMR; nonlinear optical crystal; Nonlinearity; Nuclear magnetic resonance; organic compound; Phase transitions; Phosphates; Single crystals; Spectrum analysis; thermal analysis; Thermal properties; Thermogravimetric analysis; X-ray diffraction
• ISSN: 0141-1594; 1029-0338
• DOI: 10.1080/01411594.2015.1021347

The growth of organic nonlinear optical (NLO) crystal 2-amino-5-chloropyridinium trichloroacetate (2A5CPTCA) has been synthesized and single crystals have been grown from methanol solvent by slow evaporation technique. The grown crystals were subjected to various characterization analyses in order to find out the suitability for device fabrication. Single crystal X-ray diffraction analysis reveals that 2A5CPTCA crystallizes in monoclinic system with the space group Cc. The grown crystal was further characterized by Fourier transform infrared spectral analysis to find out the functional groups. The nuclear magnetic resonance spectroscopy is a research technique that exploits the magnetic properties of certain atomic nuclei. The optical transparency window in the visible and near-IR (200--1100 nm) regions was found to be good for NLO applications. Thermogravimetric analysis and differential thermal analysis were used to study its thermal properties. The powder second harmonic generation efficiency measurement with Nd:YAG laser (1064 nm) radiation shows that the highest value when compared with the standard potassium dihydrogen phosphate crystal.