Thermal conductivity of heavy, even-carbon number n-alkanes (C22 to C32)
The thermal conductivity of even carbon number n-alkanes from n-dodecane to n-dotriacontane (C22H46 to C32H66) was measured in both the liquid and solid phases, in the temperature range from 297.15 to 353.15 K at 0.1 MPa. To assure the purity and map the solid phase of the different samples during t...
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| Published in: | Fluid phase equilibria Vol. 477; pp. 78 - 86 |
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Elsevier B.V
15-12-2018
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| Abstract | The thermal conductivity of even carbon number n-alkanes from n-dodecane to n-dotriacontane (C22H46 to C32H66) was measured in both the liquid and solid phases, in the temperature range from 297.15 to 353.15 K at 0.1 MPa. To assure the purity and map the solid phase of the different samples during the thermal conductivity measurements of the solid samples, the melting point, solid-solid transition temperature and their respective enthalpies were also evaluated. The thermal conductivity measurements for the liquid and solid samples were obtained within uncertainty levels better than 3% and 5%, respectively. To the best of our knowledge, this is the first report on the thermal conductivity of liquid n-hexacontane, n-octacontane, n-triacontane and n-dotriacontane, and, for solid samples, from n-docosane to n-dotriacontane. |
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| AbstractList | The thermal conductivity of even carbon number n-alkanes from n-dodecane to n-dotriacontane (C22H46 to C32H66) was measured in both the liquid and solid phases, in the temperature range from 297.15 to 353.15 K at 0.1 MPa. To assure the purity and map the solid phase of the different samples during the thermal conductivity measurements of the solid samples, the melting point, solid-solid transition temperature and their respective enthalpies were also evaluated. The thermal conductivity measurements for the liquid and solid samples were obtained within uncertainty levels better than 3% and 5%, respectively. To the best of our knowledge, this is the first report on the thermal conductivity of liquid n-hexacontane, n-octacontane, n-triacontane and n-dotriacontane, and, for solid samples, from n-docosane to n-dotriacontane. |
| Author | Orlande, Hélcio Rangel Barreto Azevedo, Luis Fernando Alzuguir de Andrade Silva, Lívia Daridon, Jean-Luc Pauly, Jérôme Fleming, Felipe Pereira Herzog, Iasmin Lima, Guilherme dos Santos Vieira |
| Author_xml | – sequence: 1 givenname: Felipe Pereira surname: Fleming fullname: Fleming, Felipe Pereira organization: CENPES - Centro de Pesquisas da Petrobras, Cidade Universitária, CEP: 21941-915, Rio de janeiro, RJ, Brazil – sequence: 2 givenname: Lívia surname: de Andrade Silva fullname: de Andrade Silva, Lívia organization: CENPES - Centro de Pesquisas da Petrobras, Cidade Universitária, CEP: 21941-915, Rio de janeiro, RJ, Brazil – sequence: 3 givenname: Guilherme dos Santos Vieira surname: Lima fullname: Lima, Guilherme dos Santos Vieira organization: CENPES - Centro de Pesquisas da Petrobras, Cidade Universitária, CEP: 21941-915, Rio de janeiro, RJ, Brazil – sequence: 4 givenname: Iasmin surname: Herzog fullname: Herzog, Iasmin organization: Programa de Engenharia Mecânica/COPPE, Universidade Federal do Rio de Janeiro, RJ, Brazil – sequence: 5 givenname: Hélcio Rangel Barreto surname: Orlande fullname: Orlande, Hélcio Rangel Barreto organization: Programa de Engenharia Mecânica/COPPE, Universidade Federal do Rio de Janeiro, RJ, Brazil – sequence: 6 givenname: Jean-Luc surname: Daridon fullname: Daridon, Jean-Luc organization: Laboratoire des Fluides Complexes et leurs Réservoirs, UPPA, Pau, France – sequence: 7 givenname: Jérôme surname: Pauly fullname: Pauly, Jérôme organization: Laboratoire des Fluides Complexes et leurs Réservoirs, UPPA, Pau, France – sequence: 8 givenname: Luis Fernando Alzuguir surname: Azevedo fullname: Azevedo, Luis Fernando Alzuguir email: lfaa@puc-rio.br organization: Departamento de Engenharia Mecânica, PUC-RIO, Rio de Janeiro, RJ, Brazil |
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| Keywords | Thermal conductivity n-Alkanes Thermophysical properties Melting point Entalpy of fusion |
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| SubjectTerms | Applied geology Chemical Physics Earth Sciences Engineering Sciences Entalpy of fusion Geophysics Mechanics Melting point n-Alkanes Physics Sciences of the Universe Thermal conductivity Thermophysical properties |
| Title | Thermal conductivity of heavy, even-carbon number n-alkanes (C22 to C32) |
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