Polymer-Assisted Synthesis, Structure and Magnetic Properties of Bimetallic FeCo- and FeNi/N-Doped Carbon Nanocomposites
Bimetallic FeCo and FeNi nanoparticles attract much attention due to their promising magnetic properties and a wide range of practical applications as recording and storage media, catalytic systems in fuel cells, supercapacitors, lithium batteries, etc. In this paper, we propose an original approach...
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Published in: | Magnetochemistry Vol. 9; no. 10; p. 213 |
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Abstract | Bimetallic FeCo and FeNi nanoparticles attract much attention due to their promising magnetic properties and a wide range of practical applications as recording and storage media, catalytic systems in fuel cells, supercapacitors, lithium batteries, etc. In this paper, we propose an original approach to the preparation of FeCo- and FeNi/N-doped carbon nanocomposites by means of a coupled process of frontal polymerization and thermolysis of molecular co-crystallized acrylamide complexes. The phase composition, structure, and microstructure of the resulting nanocomposites are studied using XRD, IR spectroscopy, elemental and thermal analysis, and electron microscopy data. The main magnetic characteristics of the synthesized nanocomposites, including the field dependences and the ZFC-FC curves peculiarities, are studied. It is shown that the obtained FeCo/N-C nanocomposites exhibit exchange bias behavior at low temperatures. In turn, FeNi/N-C nanocomposites are ferromagnetically ordered. |
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AbstractList | Bimetallic FeCo and FeNi nanoparticles attract much attention due to their promising magnetic properties and a wide range of practical applications as recording and storage media, catalytic systems in fuel cells, supercapacitors, lithium batteries, etc. In this paper, we propose an original approach to the preparation of FeCo- and FeNi/N-doped carbon nanocomposites by means of a coupled process of frontal polymerization and thermolysis of molecular co-crystallized acrylamide complexes. The phase composition, structure, and microstructure of the resulting nanocomposites are studied using XRD, IR spectroscopy, elemental and thermal analysis, and electron microscopy data. The main magnetic characteristics of the synthesized nanocomposites, including the field dependences and the ZFC-FC curves peculiarities, are studied. It is shown that the obtained FeCo/N-C nanocomposites exhibit exchange bias behavior at low temperatures. In turn, FeNi/N-C nanocomposites are ferromagnetically ordered. |
Audience | Academic |
Author | Kugabaeva, Gulsara D. Degtyarenko, Pavel N. Golubeva, Nina D. Golovkova, Ekaterina A. Uflyand, Igor E. Baimuratova, Rose K. Karpenkov, Dmitry Yu Bondarenko, Lyubov S. Dzhardimalieva, Gulzhian I. Kydralieva, Kamila A. |
Author_xml | – sequence: 1 givenname: Gulsara D. surname: Kugabaeva fullname: Kugabaeva, Gulsara D. – sequence: 2 givenname: Kamila A. surname: Kydralieva fullname: Kydralieva, Kamila A. – sequence: 3 givenname: Lyubov S. orcidid: 0000-0002-3107-0648 surname: Bondarenko fullname: Bondarenko, Lyubov S. – sequence: 4 givenname: Rose K. surname: Baimuratova fullname: Baimuratova, Rose K. – sequence: 5 givenname: Dmitry Yu surname: Karpenkov fullname: Karpenkov, Dmitry Yu – sequence: 6 givenname: Ekaterina A. surname: Golovkova fullname: Golovkova, Ekaterina A. – sequence: 7 givenname: Pavel N. orcidid: 0000-0003-2733-6703 surname: Degtyarenko fullname: Degtyarenko, Pavel N. – sequence: 8 givenname: Nina D. surname: Golubeva fullname: Golubeva, Nina D. – sequence: 9 givenname: Igor E. orcidid: 0000-0002-7164-8168 surname: Uflyand fullname: Uflyand, Igor E. – sequence: 10 givenname: Gulzhian I. orcidid: 0000-0002-4727-8910 surname: Dzhardimalieva fullname: Dzhardimalieva, Gulzhian I. |
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SubjectTerms | Acrylamide Alloys bimetallic nanoparticles Bimetals Carbon Chemical properties Chemical synthesis Composite materials Coordination compounds Crystallization Ferromagnetism Fuel cells Gas turbine engines Hydrocarbons Infrared spectroscopy Lithium batteries Low temperature Magnetic properties Methods Nanocomposites Nanomaterials Nanoparticles Nitrates Nitrogen Oxidation Phase composition Polymerization Polymers Temperature Thermal analysis thermolysis |
Title | Polymer-Assisted Synthesis, Structure and Magnetic Properties of Bimetallic FeCo- and FeNi/N-Doped Carbon Nanocomposites |
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