Photo- and electroluminescent properties of bithiophene disubstituted 1,3,4-thiadiazoles and their application as active components in organic light emitting diodes

[Display omitted] •Solution processable organic light emitting diodes (OLEDs).•Bithiophene disubstituted 1,3,4-thiadiazoles as a new class of bluish-green emitters.•Effective guest–host electroluminescent systems for application in OLEDs. Photo- and electroluminescence of five bithiophene disubstitu...

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Published in:Optical materials Vol. 37; pp. 193 - 199
Main Authors: Grykien, Remigiusz, Luszczynska, Beata, Glowacki, Ireneusz, Kurach, Ewa, Rybakiewicz, Renata, Kotwica, Kamil, Zagorska, Malgorzata, Pron, Adam, Tassini, Paolo, Maglione, Maria Grazia, Mauro, Anna De Girolamo Del, Fasolino, Tommaso, Rega, Romina, Pandolfi, Giuseppe, Minarini, Carla, Aprano, Salvatore
Format: Journal Article
Language:English
Published: Oxford Elsevier B.V 01-11-2014
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Abstract [Display omitted] •Solution processable organic light emitting diodes (OLEDs).•Bithiophene disubstituted 1,3,4-thiadiazoles as a new class of bluish-green emitters.•Effective guest–host electroluminescent systems for application in OLEDs. Photo- and electroluminescence of five bithiophene disubstituted 1,3,4-thiadiazoles, constituting a new class of solution processable materials for organic opto-electronics, were studied. It was found that the introduction of alkyl solubilizing substituents bathochromically shifted the photo- and electroluminescence bands. The most pronounced effect was observed for the substitution at the Cα position which changed the emitting light color from bluish to green. All five derivatives were tested in host/guest type organic light emitting diodes (OLEDs) with either poly(N-vinylcarbazole) (PVK) or poly(N-vinylcarbazole)+2-tert-butylphenyl-5-biphenyl-1,3,4-oxadiazole (PVK+PBD) matrices. The latter matrix turned out especially well suited for these guest molecules yielding devices of varying color coordinates. The best luminance (750cd/m2) was measured for 2,5-bis(5′-octyl-2,2′-bithiophene-5-yl)-1,3,4-thiadiazole with the luminous efficiency exceeding 0.4cd/A.
AbstractList [Display omitted] •Solution processable organic light emitting diodes (OLEDs).•Bithiophene disubstituted 1,3,4-thiadiazoles as a new class of bluish-green emitters.•Effective guest–host electroluminescent systems for application in OLEDs. Photo- and electroluminescence of five bithiophene disubstituted 1,3,4-thiadiazoles, constituting a new class of solution processable materials for organic opto-electronics, were studied. It was found that the introduction of alkyl solubilizing substituents bathochromically shifted the photo- and electroluminescence bands. The most pronounced effect was observed for the substitution at the Cα position which changed the emitting light color from bluish to green. All five derivatives were tested in host/guest type organic light emitting diodes (OLEDs) with either poly(N-vinylcarbazole) (PVK) or poly(N-vinylcarbazole)+2-tert-butylphenyl-5-biphenyl-1,3,4-oxadiazole (PVK+PBD) matrices. The latter matrix turned out especially well suited for these guest molecules yielding devices of varying color coordinates. The best luminance (750cd/m2) was measured for 2,5-bis(5′-octyl-2,2′-bithiophene-5-yl)-1,3,4-thiadiazole with the luminous efficiency exceeding 0.4cd/A.
Photo- and electroluminescence of five bithiophene disubstituted 1,3,4-thiadiazoles, constituting a new class of solution processable materials for organic opto-electronics, were studied. It was found that the introduction of alkyl solubilizing substituents bathochromically shifted the photo- and electroluminescence bands. The most pronounced effect was observed for the substitution at the C sub( alpha ) position which changed the emitting light color from bluish to green. All five derivatives were tested in host/guest type organic light emitting diodes (OLEDs) with either poly(N-vinylcarbazole) (PVK) or poly(N-vinylcarbazole) + 2-tert-butylphenyl-5-biphenyl-1,3,4-oxadiazole (PVK + PBD) matrices. The latter matrix turned out especially well suited for these guest molecules yielding devices of varying color coordinates. The best luminance (750 cd/m super(2)) was measured for 2,5-bis(5'-octyl-2,2'-bithiophene-5-yl)-1,3,4-thiadia zole with the luminous efficiency exceeding 0.4 cd/A.
Author Kurach, Ewa
Mauro, Anna De Girolamo Del
Luszczynska, Beata
Maglione, Maria Grazia
Aprano, Salvatore
Glowacki, Ireneusz
Tassini, Paolo
Pandolfi, Giuseppe
Minarini, Carla
Grykien, Remigiusz
Rybakiewicz, Renata
Pron, Adam
Zagorska, Malgorzata
Kotwica, Kamil
Fasolino, Tommaso
Rega, Romina
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  givenname: Ireneusz
  surname: Glowacki
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  organization: Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00664 Warsaw, Poland
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  surname: Pron
  fullname: Pron, Adam
  organization: Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00664 Warsaw, Poland
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  givenname: Paolo
  surname: Tassini
  fullname: Tassini, Paolo
  organization: ENEA C.R. Portici, P.le E. Fermi no. 1, Località Granatello, 80055 Portici, NA, Italy
– sequence: 10
  givenname: Maria Grazia
  surname: Maglione
  fullname: Maglione, Maria Grazia
  organization: ENEA C.R. Portici, P.le E. Fermi no. 1, Località Granatello, 80055 Portici, NA, Italy
– sequence: 11
  givenname: Anna De Girolamo Del
  surname: Mauro
  fullname: Mauro, Anna De Girolamo Del
  organization: ENEA C.R. Portici, P.le E. Fermi no. 1, Località Granatello, 80055 Portici, NA, Italy
– sequence: 12
  givenname: Tommaso
  surname: Fasolino
  fullname: Fasolino, Tommaso
  organization: ENEA C.R. Portici, P.le E. Fermi no. 1, Località Granatello, 80055 Portici, NA, Italy
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  givenname: Romina
  surname: Rega
  fullname: Rega, Romina
  organization: ENEA C.R. Portici, P.le E. Fermi no. 1, Località Granatello, 80055 Portici, NA, Italy
– sequence: 14
  givenname: Giuseppe
  surname: Pandolfi
  fullname: Pandolfi, Giuseppe
  organization: ENEA C.R. Portici, P.le E. Fermi no. 1, Località Granatello, 80055 Portici, NA, Italy
– sequence: 15
  givenname: Carla
  surname: Minarini
  fullname: Minarini, Carla
  organization: ENEA C.R. Portici, P.le E. Fermi no. 1, Località Granatello, 80055 Portici, NA, Italy
– sequence: 16
  givenname: Salvatore
  surname: Aprano
  fullname: Aprano, Salvatore
  organization: SESMAT S.r.l., S.S.7 Appia no.36, 82018 San Giorgio del Sannio, BN, Italy
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Keywords Organic light emitting diodes
Bithiophene disubstituted 1,3,4-thiadiazoles
Host/guest electroluminescent system
Biphenyl
Oxadiazole derivatives
Benzenic compound
Electroluminescence
Organic light-emitting devices
Organic compounds
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Snippet [Display omitted] •Solution processable organic light emitting diodes (OLEDs).•Bithiophene disubstituted 1,3,4-thiadiazoles as a new class of bluish-green...
Photo- and electroluminescence of five bithiophene disubstituted 1,3,4-thiadiazoles, constituting a new class of solution processable materials for organic...
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SubjectTerms Applied sciences
Bands
Bithiophene disubstituted 1,3,4-thiadiazoles
Color
Derivatives
Electroluminescence
Electronics
Exact sciences and technology
Host/guest electroluminescent system
Luminance
Optoelectronic devices
Optoelectronics
Organic light emitting diodes
Polyvinyl carbazole
Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices
Title Photo- and electroluminescent properties of bithiophene disubstituted 1,3,4-thiadiazoles and their application as active components in organic light emitting diodes
URI https://dx.doi.org/10.1016/j.optmat.2014.05.023
https://search.proquest.com/docview/1651436728
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