Photo- and electroluminescent properties of bithiophene disubstituted 1,3,4-thiadiazoles and their application as active components in organic light emitting diodes
[Display omitted] •Solution processable organic light emitting diodes (OLEDs).•Bithiophene disubstituted 1,3,4-thiadiazoles as a new class of bluish-green emitters.•Effective guest–host electroluminescent systems for application in OLEDs. Photo- and electroluminescence of five bithiophene disubstitu...
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Published in: | Optical materials Vol. 37; pp. 193 - 199 |
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Main Authors: | , , , , , , , , , , , , , , , |
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01-11-2014
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Abstract | [Display omitted]
•Solution processable organic light emitting diodes (OLEDs).•Bithiophene disubstituted 1,3,4-thiadiazoles as a new class of bluish-green emitters.•Effective guest–host electroluminescent systems for application in OLEDs.
Photo- and electroluminescence of five bithiophene disubstituted 1,3,4-thiadiazoles, constituting a new class of solution processable materials for organic opto-electronics, were studied. It was found that the introduction of alkyl solubilizing substituents bathochromically shifted the photo- and electroluminescence bands. The most pronounced effect was observed for the substitution at the Cα position which changed the emitting light color from bluish to green. All five derivatives were tested in host/guest type organic light emitting diodes (OLEDs) with either poly(N-vinylcarbazole) (PVK) or poly(N-vinylcarbazole)+2-tert-butylphenyl-5-biphenyl-1,3,4-oxadiazole (PVK+PBD) matrices. The latter matrix turned out especially well suited for these guest molecules yielding devices of varying color coordinates. The best luminance (750cd/m2) was measured for 2,5-bis(5′-octyl-2,2′-bithiophene-5-yl)-1,3,4-thiadiazole with the luminous efficiency exceeding 0.4cd/A. |
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AbstractList | [Display omitted]
•Solution processable organic light emitting diodes (OLEDs).•Bithiophene disubstituted 1,3,4-thiadiazoles as a new class of bluish-green emitters.•Effective guest–host electroluminescent systems for application in OLEDs.
Photo- and electroluminescence of five bithiophene disubstituted 1,3,4-thiadiazoles, constituting a new class of solution processable materials for organic opto-electronics, were studied. It was found that the introduction of alkyl solubilizing substituents bathochromically shifted the photo- and electroluminescence bands. The most pronounced effect was observed for the substitution at the Cα position which changed the emitting light color from bluish to green. All five derivatives were tested in host/guest type organic light emitting diodes (OLEDs) with either poly(N-vinylcarbazole) (PVK) or poly(N-vinylcarbazole)+2-tert-butylphenyl-5-biphenyl-1,3,4-oxadiazole (PVK+PBD) matrices. The latter matrix turned out especially well suited for these guest molecules yielding devices of varying color coordinates. The best luminance (750cd/m2) was measured for 2,5-bis(5′-octyl-2,2′-bithiophene-5-yl)-1,3,4-thiadiazole with the luminous efficiency exceeding 0.4cd/A. Photo- and electroluminescence of five bithiophene disubstituted 1,3,4-thiadiazoles, constituting a new class of solution processable materials for organic opto-electronics, were studied. It was found that the introduction of alkyl solubilizing substituents bathochromically shifted the photo- and electroluminescence bands. The most pronounced effect was observed for the substitution at the C sub( alpha ) position which changed the emitting light color from bluish to green. All five derivatives were tested in host/guest type organic light emitting diodes (OLEDs) with either poly(N-vinylcarbazole) (PVK) or poly(N-vinylcarbazole) + 2-tert-butylphenyl-5-biphenyl-1,3,4-oxadiazole (PVK + PBD) matrices. The latter matrix turned out especially well suited for these guest molecules yielding devices of varying color coordinates. The best luminance (750 cd/m super(2)) was measured for 2,5-bis(5'-octyl-2,2'-bithiophene-5-yl)-1,3,4-thiadia zole with the luminous efficiency exceeding 0.4 cd/A. |
Author | Kurach, Ewa Mauro, Anna De Girolamo Del Luszczynska, Beata Maglione, Maria Grazia Aprano, Salvatore Glowacki, Ireneusz Tassini, Paolo Pandolfi, Giuseppe Minarini, Carla Grykien, Remigiusz Rybakiewicz, Renata Pron, Adam Zagorska, Malgorzata Kotwica, Kamil Fasolino, Tommaso Rega, Romina |
Author_xml | – sequence: 1 givenname: Remigiusz surname: Grykien fullname: Grykien, Remigiusz organization: Department of Molecular Physics, Technical University of Lodz, Zeromskiego 116, 90924 Lodz, Poland – sequence: 2 givenname: Beata surname: Luszczynska fullname: Luszczynska, Beata email: beata.luszczynska@p.lodz.pl organization: Department of Molecular Physics, Technical University of Lodz, Zeromskiego 116, 90924 Lodz, Poland – sequence: 3 givenname: Ireneusz surname: Glowacki fullname: Glowacki, Ireneusz organization: Department of Molecular Physics, Technical University of Lodz, Zeromskiego 116, 90924 Lodz, Poland – sequence: 4 givenname: Ewa surname: Kurach fullname: Kurach, Ewa organization: Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00664 Warsaw, Poland – sequence: 5 givenname: Renata surname: Rybakiewicz fullname: Rybakiewicz, Renata organization: Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00664 Warsaw, Poland – sequence: 6 givenname: Kamil surname: Kotwica fullname: Kotwica, Kamil organization: Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00664 Warsaw, Poland – sequence: 7 givenname: Malgorzata surname: Zagorska fullname: Zagorska, Malgorzata organization: Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00664 Warsaw, Poland – sequence: 8 givenname: Adam surname: Pron fullname: Pron, Adam organization: Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00664 Warsaw, Poland – sequence: 9 givenname: Paolo surname: Tassini fullname: Tassini, Paolo organization: ENEA C.R. Portici, P.le E. Fermi no. 1, Località Granatello, 80055 Portici, NA, Italy – sequence: 10 givenname: Maria Grazia surname: Maglione fullname: Maglione, Maria Grazia organization: ENEA C.R. Portici, P.le E. Fermi no. 1, Località Granatello, 80055 Portici, NA, Italy – sequence: 11 givenname: Anna De Girolamo Del surname: Mauro fullname: Mauro, Anna De Girolamo Del organization: ENEA C.R. Portici, P.le E. Fermi no. 1, Località Granatello, 80055 Portici, NA, Italy – sequence: 12 givenname: Tommaso surname: Fasolino fullname: Fasolino, Tommaso organization: ENEA C.R. Portici, P.le E. Fermi no. 1, Località Granatello, 80055 Portici, NA, Italy – sequence: 13 givenname: Romina surname: Rega fullname: Rega, Romina organization: ENEA C.R. Portici, P.le E. Fermi no. 1, Località Granatello, 80055 Portici, NA, Italy – sequence: 14 givenname: Giuseppe surname: Pandolfi fullname: Pandolfi, Giuseppe organization: ENEA C.R. Portici, P.le E. Fermi no. 1, Località Granatello, 80055 Portici, NA, Italy – sequence: 15 givenname: Carla surname: Minarini fullname: Minarini, Carla organization: ENEA C.R. Portici, P.le E. Fermi no. 1, Località Granatello, 80055 Portici, NA, Italy – sequence: 16 givenname: Salvatore surname: Aprano fullname: Aprano, Salvatore organization: SESMAT S.r.l., S.S.7 Appia no.36, 82018 San Giorgio del Sannio, BN, Italy |
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Keywords | Organic light emitting diodes Bithiophene disubstituted 1,3,4-thiadiazoles Host/guest electroluminescent system Biphenyl Oxadiazole derivatives Benzenic compound Electroluminescence Organic light-emitting devices Organic compounds |
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•Solution processable organic light emitting diodes (OLEDs).•Bithiophene disubstituted 1,3,4-thiadiazoles as a new class of bluish-green... Photo- and electroluminescence of five bithiophene disubstituted 1,3,4-thiadiazoles, constituting a new class of solution processable materials for organic... |
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SubjectTerms | Applied sciences Bands Bithiophene disubstituted 1,3,4-thiadiazoles Color Derivatives Electroluminescence Electronics Exact sciences and technology Host/guest electroluminescent system Luminance Optoelectronic devices Optoelectronics Organic light emitting diodes Polyvinyl carbazole Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices |
Title | Photo- and electroluminescent properties of bithiophene disubstituted 1,3,4-thiadiazoles and their application as active components in organic light emitting diodes |
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