Electrofluorochromism of a ruthenium complex investigated by time resolved TIRF microscopy coupled to an electrochemical cell

• Published in: Electrochemistry communications Vol. 20; pp. 83 - 87
• Main Authors: Miomandre, F., Pansu, R.B., Audibert, J.F., Guerlin, A., Mayer, C.R.
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier B.V 01-07-2012; Amsterdam Elsevier; New York, NY
• Subjects: Chemical Sciences; Chemistry; Electrochemistry; Exact sciences and technology; Fluorescence; General and physical chemistry; Lifetime; Microscopy; Miscellaneous (electroosmosis, electrophoresis, electrochromism, electrocrystallization, ...); or physical chemistry; Ruthenium; Theoretical and; TIRF; Fluorescence; Electrochemistry; Lifetime; Ruthenium; Microscopy; TIRF; Coupled method; Organic ligand; Electrochemical cell; Bipyridines; Electrochromism; Transition metal Complexes; Pyridine derivatives; Total internal reflection fluorescence microscopy; Ruthenium Complexes; Platinoid Complexes
• ISSN: 1388-2481; 1873-1902
• DOI: 10.1016/j.elecom.2012.03.030

This paper describes the use of TIRF microscopy coupled to electrochemistry to investigate the electrofluorochromic properties of a new bipyidine–phenanthroline ruthenium complex. A reversible electrochemical modulation of luminescence is observed when applying potential steps between the reduced emitting state and the oxidized non emitting one. Variations of intensity and lifetimes along the potential steps are analyzed to understand the mechanism of this switch. It is shown that a quenching mechanism occurs upon electrooxidation that accounts for the fast luminescence switch process.
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► Application of TIRF microscopy coupled to electrochemistry to the luminescence switch of an inorganic compound. ► Luminescence intensity, lifetimes, spectra and images are recorded. ► Luminescence intensity and lifetimes are modulated reversibly by the electrode potential.