Identification of a point source of chlordane contamination from a timber treatment facility
Technical Chlordane is a multi-component chlorinated hydrocarbon pesticide formulation containing in excess of 140 different compounds. Chlordane has been used extensively as a timber preservative in both the LOSP pressure treatment method or as an antibiotic component of the adhesives in plywood ma...
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Published in: | Bulletin of environmental contamination and toxicology Vol. 55; no. 2; pp. 289 - 295 |
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Main Authors: | , , , , , |
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Language: | English |
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New York, NY
Springer-Verlag
01-08-1995
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Abstract | Technical Chlordane is a multi-component chlorinated hydrocarbon pesticide formulation containing in excess of 140 different compounds. Chlordane has been used extensively as a timber preservative in both the LOSP pressure treatment method or as an antibiotic component of the adhesives in plywood manufacture. The widespread use of chlordane, combined with its broad spectrum toxicity, propensity to bioaccumulate, and persistance in the environment make chlordane a significant environmental pollutant. Manukau Harbor is a large (344 km super(2)) shallow inlet adjacent to Auckland city, New Zealand. Earlier studies showed levels of chlordane in Manukau Harbor comparable with heavily industrialised countries such as Japan and the USA. The initial study showed that the levels of contamination increased approaching the Mangere Inlet - Onehunga region of the harbor. A survey of industry in this area indicated that a timber treatment facility was the most likely source. Chlordane can be released into the timber yard by spillage, and by drip from recently treated timber. Since chlordane is virtually insoluble in water, this poses little threat if contained. However, the surface material in the yard is susceptible to erosion by wind and rain, and can easily be carried off the site as dust or sediment in runoff. |
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AbstractList | Samples taken of mud, gravel, soil, sediment, and sand from the environs of an abandoned timber treatment facility near Mangere Inlet of Manukau Harbor, New Zealand, were analyzed for chlordane content. All samples contained chlordane, but the samples from within the timber yard had chlordane content at least two orders of magnitude greater than those taken from the nearby marsh and outlet. The timber yard sample also had a different profile of chlordane components than the other samples. The role of photodegradation, or volatility of some of the components in the different component profiles is briefly discussed. Sampling was done in 1988, 1989, and 1990. Results from the most contaminated sampling site showed a downward trend in concentration with time. PAHs were also detected in samples from areas that drained the timber yard. Samples from a marsh adjacent to a bowling green also contained DDT. Technical Chlordane is a multi-component chlorinated hydrocarbon pesticide formulation containing in excess of 140 different compounds. Chlordane has been used extensively as a timber preservative in both the LOSP pressure treatment method or as an antibiotic component of the adhesives in plywood manufacture. The widespread use of chlordane, combined with its broad spectrum toxicity, propensity to bioaccumulate, and persistance in the environment make chlordane a significant environmental pollutant. Manukau Harbor is a large (344 km super(2)) shallow inlet adjacent to Auckland city, New Zealand. Earlier studies showed levels of chlordane in Manukau Harbor comparable with heavily industrialised countries such as Japan and the USA. The initial study showed that the levels of contamination increased approaching the Mangere Inlet - Onehunga region of the harbor. A survey of industry in this area indicated that a timber treatment facility was the most likely source. Chlordane can be released into the timber yard by spillage, and by drip from recently treated timber. Since chlordane is virtually insoluble in water, this poses little threat if contained. However, the surface material in the yard is susceptible to erosion by wind and rain, and can easily be carried off the site as dust or sediment in runoff. Levels of chlordane, a multicomponent chlorinated hydrocarbon pesticide formulation containing more than 140 different compounds, widely used as a timber preservative, were investigated in Manukau harbour near Auckland, New Zealand. A timber treatment facility near the Mangere inlet area of the harbour was identified as the most likely source of the high levels in the harbour. The study showed that inadvertent chlordane release from timber treatment units could produce large point sources of contamination. Risks of chlordane residues from around 400 sites in New Zealand contaminating the surrounding environment were significant. Control measures were recommended. |
Author | SMITH, T. J WILKINS, A. L LANGDON, A. G BURGGRAAF, S WILCOCK, R. J SIMPSON, C. D |
Author_xml | – sequence: 1 givenname: C. D surname: SIMPSON fullname: SIMPSON, C. D organization: Univ. British Columbia, chemistry dep., Vancouver BC V6T 1Z1, Canada – sequence: 2 givenname: T. J surname: SMITH fullname: SMITH, T. J organization: Univ. British Columbia, chemistry dep., Vancouver BC V6T 1Z1, Canada – sequence: 3 givenname: S surname: BURGGRAAF fullname: BURGGRAAF, S organization: Univ. British Columbia, chemistry dep., Vancouver BC V6T 1Z1, Canada – sequence: 4 givenname: A. L surname: WILKINS fullname: WILKINS, A. L organization: Univ. British Columbia, chemistry dep., Vancouver BC V6T 1Z1, Canada – sequence: 5 givenname: A. G surname: LANGDON fullname: LANGDON, A. G organization: Univ. British Columbia, chemistry dep., Vancouver BC V6T 1Z1, Canada – sequence: 6 givenname: R. J surname: WILCOCK fullname: WILCOCK, R. J organization: Univ. British Columbia, chemistry dep., Vancouver BC V6T 1Z1, Canada |
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Keywords | New Zealand Ports and harbors Content Pesticides Pollution source Wood industry Soil pollution Chlordane |
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Snippet | Levels of chlordane, a multicomponent chlorinated hydrocarbon pesticide formulation containing more than 140 different compounds, widely used as a timber... Samples taken of mud, gravel, soil, sediment, and sand from the environs of an abandoned timber treatment facility near Mangere Inlet of Manukau Harbor, New... Technical Chlordane is a multi-component chlorinated hydrocarbon pesticide formulation containing in excess of 140 different compounds. Chlordane has been used... |
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SubjectTerms | Applied sciences Chlordan - analysis Chlordan - metabolism Exact sciences and technology Gas Chromatography-Mass Spectrometry Industry Insecticides - analysis Insecticides - metabolism New Zealand Pest Control Pesticide Residues - analysis Pesticide Residues - metabolism Pollution Pollution sources. Measurement results Soil and sediments pollution Soil Pollutants - analysis |
Title | Identification of a point source of chlordane contamination from a timber treatment facility |
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