Identification of a point source of chlordane contamination from a timber treatment facility

Technical Chlordane is a multi-component chlorinated hydrocarbon pesticide formulation containing in excess of 140 different compounds. Chlordane has been used extensively as a timber preservative in both the LOSP pressure treatment method or as an antibiotic component of the adhesives in plywood ma...

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Published in:Bulletin of environmental contamination and toxicology Vol. 55; no. 2; pp. 289 - 295
Main Authors: SIMPSON, C. D, SMITH, T. J, BURGGRAAF, S, WILKINS, A. L, LANGDON, A. G, WILCOCK, R. J
Format: Journal Article
Language:English
Published: New York, NY Springer-Verlag 01-08-1995
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Abstract Technical Chlordane is a multi-component chlorinated hydrocarbon pesticide formulation containing in excess of 140 different compounds. Chlordane has been used extensively as a timber preservative in both the LOSP pressure treatment method or as an antibiotic component of the adhesives in plywood manufacture. The widespread use of chlordane, combined with its broad spectrum toxicity, propensity to bioaccumulate, and persistance in the environment make chlordane a significant environmental pollutant. Manukau Harbor is a large (344 km super(2)) shallow inlet adjacent to Auckland city, New Zealand. Earlier studies showed levels of chlordane in Manukau Harbor comparable with heavily industrialised countries such as Japan and the USA. The initial study showed that the levels of contamination increased approaching the Mangere Inlet - Onehunga region of the harbor. A survey of industry in this area indicated that a timber treatment facility was the most likely source. Chlordane can be released into the timber yard by spillage, and by drip from recently treated timber. Since chlordane is virtually insoluble in water, this poses little threat if contained. However, the surface material in the yard is susceptible to erosion by wind and rain, and can easily be carried off the site as dust or sediment in runoff.
AbstractList Samples taken of mud, gravel, soil, sediment, and sand from the environs of an abandoned timber treatment facility near Mangere Inlet of Manukau Harbor, New Zealand, were analyzed for chlordane content. All samples contained chlordane, but the samples from within the timber yard had chlordane content at least two orders of magnitude greater than those taken from the nearby marsh and outlet. The timber yard sample also had a different profile of chlordane components than the other samples. The role of photodegradation, or volatility of some of the components in the different component profiles is briefly discussed. Sampling was done in 1988, 1989, and 1990. Results from the most contaminated sampling site showed a downward trend in concentration with time. PAHs were also detected in samples from areas that drained the timber yard. Samples from a marsh adjacent to a bowling green also contained DDT.
Technical Chlordane is a multi-component chlorinated hydrocarbon pesticide formulation containing in excess of 140 different compounds. Chlordane has been used extensively as a timber preservative in both the LOSP pressure treatment method or as an antibiotic component of the adhesives in plywood manufacture. The widespread use of chlordane, combined with its broad spectrum toxicity, propensity to bioaccumulate, and persistance in the environment make chlordane a significant environmental pollutant. Manukau Harbor is a large (344 km super(2)) shallow inlet adjacent to Auckland city, New Zealand. Earlier studies showed levels of chlordane in Manukau Harbor comparable with heavily industrialised countries such as Japan and the USA. The initial study showed that the levels of contamination increased approaching the Mangere Inlet - Onehunga region of the harbor. A survey of industry in this area indicated that a timber treatment facility was the most likely source. Chlordane can be released into the timber yard by spillage, and by drip from recently treated timber. Since chlordane is virtually insoluble in water, this poses little threat if contained. However, the surface material in the yard is susceptible to erosion by wind and rain, and can easily be carried off the site as dust or sediment in runoff.
Levels of chlordane, a multicomponent chlorinated hydrocarbon pesticide formulation containing more than 140 different compounds, widely used as a timber preservative, were investigated in Manukau harbour near Auckland, New Zealand. A timber treatment facility near the Mangere inlet area of the harbour was identified as the most likely source of the high levels in the harbour. The study showed that inadvertent chlordane release from timber treatment units could produce large point sources of contamination. Risks of chlordane residues from around 400 sites in New Zealand contaminating the surrounding environment were significant. Control measures were recommended.
Author SMITH, T. J
WILKINS, A. L
LANGDON, A. G
BURGGRAAF, S
WILCOCK, R. J
SIMPSON, C. D
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Keywords New Zealand
Ports and harbors
Content
Pesticides
Pollution source
Wood industry
Soil pollution
Chlordane
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Snippet Levels of chlordane, a multicomponent chlorinated hydrocarbon pesticide formulation containing more than 140 different compounds, widely used as a timber...
Samples taken of mud, gravel, soil, sediment, and sand from the environs of an abandoned timber treatment facility near Mangere Inlet of Manukau Harbor, New...
Technical Chlordane is a multi-component chlorinated hydrocarbon pesticide formulation containing in excess of 140 different compounds. Chlordane has been used...
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StartPage 289
SubjectTerms Applied sciences
Chlordan - analysis
Chlordan - metabolism
Exact sciences and technology
Gas Chromatography-Mass Spectrometry
Industry
Insecticides - analysis
Insecticides - metabolism
New Zealand
Pest Control
Pesticide Residues - analysis
Pesticide Residues - metabolism
Pollution
Pollution sources. Measurement results
Soil and sediments pollution
Soil Pollutants - analysis
Title Identification of a point source of chlordane contamination from a timber treatment facility
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