Evaluation of the potential of volatile organic compound (di-methyl benzene) removal using adsorption on natural minerals compared to commercial oxides

• Published in: Journal of hazardous materials Vol. 262; pp. 365 - 376
• Main Authors: Zaitan, Hicham, Korrir, Abdelhamid, Chafik, Tarik, Bianchi, Daniel
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier B.V 15-11-2013; Elsevier
• Subjects: Adsorption; Applied sciences; Catalysis; Chemical engineering; Chemical Sciences; Clay; Environment and Society; Environmental Sciences; Exact sciences and technology; Heat of adsorption; Isotherm of adsorption; Microscopy, Electron, Scanning; Minerals - chemistry; Oxides - chemistry; Pollution; Reactors; Thermogravimetry; VOC; Xylenes - chemistry; Xylenes - isolation & purification; Clay; VOC; Adsorption; Isotherm of adsorption; Heat of adsorption; Chemical method; Saturation; Adsorption isotherm; Fixed bed reactor; Volatile organic compound; Desorption; Modeling; Dynamic conditions; Pollutant; Fourier-transformed infrared spectrometry; Organic compounds; Breakthrough curve
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2013.08.071

•The adsorption of dMB on natural minerals and commercial oxides was evaluated.•The adsorption capacities were discussed considering the adsorbents cost and the bed size.•The adsorption capacity of bentonite is higher than other adsorbents.•Langmuir model provide best correlation of the experimental data.•The isotherms data allow determination of isosteric heat of adsorption.
This study is dedicated to the investigation of the potential of volatile organic compounds (VOC) adsorption over low cost natural minerals (bentonite and diatomite). The performances of these solids, in terms of adsorption/desorption properties, were compared to commercial adsorbents, such as silica, alumina and titanium dioxide. The solids were first characterized by different physico-chemical methods and di-methyl benzene (dMB) was selected as model VOC pollutant for the investigation of adsorptive characteristics. The experiments were carried out with a fixed bed reactor under dynamic conditions using Fourier Transform InfraRed spectrometer to measure the evolution of dMB concentrations in the gaseous stream at the outlet of the reactor. The measured breakthrough curves yields to adsorbed amounts at saturation that has been used to obtain adsorption isotherms. The latters were used for determination of the heat involved in the adsorption process and estimation of its values using the isosteric method. Furthermore, the performances of the studied materials were compared considering the adsorption efficiency/cost ratio