Yellowing of a Red South African Kandiudult, Studied by Means of Mössbauer Spectroscopy
ABSTRACTAn Acrudoxic Kandiudult soil profile from Farmhill, KwaZulu-Natal Province, South Africa, was analyzed by Mössbauer spectroscopy as an example of a red soil with yellowish surface horizons, a common sequence for which iron oxide characteristics are only poorly documented. In the red lower pa...
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| Published in: | Soil science Vol. 181; no. 2; pp. 75 - 81 |
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| Abstract | ABSTRACTAn Acrudoxic Kandiudult soil profile from Farmhill, KwaZulu-Natal Province, South Africa, was analyzed by Mössbauer spectroscopy as an example of a red soil with yellowish surface horizons, a common sequence for which iron oxide characteristics are only poorly documented. In the red lower part of the profile (62+ cm), the Fe oxide fraction consists of hematite and well-crystallized pure goethite. In the yellowish upper part (0–62 cm), the relative hematite content is lower, goethite shows a high degree of Al-for-Fe substitution, and ferrihydrite is present. Processes found to have affected the Fe oxide fraction are hematite dissolution, partial leaching, goethite precipitation with a high degree of Al incorporation, and ferrihydrite formation in conditions with a high organic matter content; the so-called DOM (dissolved organic matter) ferrihydrites. |
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| AbstractList | An Acrudoxic Kandiudult soil profile from Farmhill, KwaZulu-Natal Province, South Africa, was analyzed by Mossbauer spectroscopy as an example of a red soil with yellowish surface horizons, a common sequence for which iron oxide characteristics are only poorly documented. In the red lower part of the profile (62+ cm), the Fe oxide fraction consists of hematite and well-crystallized pure goethite. In the yellowish upper part (0-62 cm), the relative hematite content is lower, goethite shows a high degree of Al-for-Fe substitution, and ferrihydrite is present. Processes found to have affected the Fe oxide fraction are hematite dissolution, partial leaching, goethite precipitation with a high degree of Al incorporation, and ferrihydrite formation in conditions with a high organic matter content; the so-called DOM (dissolved organic matter) ferrihydrites. ABSTRACTAn Acrudoxic Kandiudult soil profile from Farmhill, KwaZulu-Natal Province, South Africa, was analyzed by Mössbauer spectroscopy as an example of a red soil with yellowish surface horizons, a common sequence for which iron oxide characteristics are only poorly documented. In the red lower part of the profile (62+ cm), the Fe oxide fraction consists of hematite and well-crystallized pure goethite. In the yellowish upper part (0–62 cm), the relative hematite content is lower, goethite shows a high degree of Al-for-Fe substitution, and ferrihydrite is present. Processes found to have affected the Fe oxide fraction are hematite dissolution, partial leaching, goethite precipitation with a high degree of Al incorporation, and ferrihydrite formation in conditions with a high organic matter content; the so-called DOM (dissolved organic matter) ferrihydrites. |
| Author | Mees, Florias Vandenberghe, Robert E Padmanabhan, Eswaran De Grave, Eddy Van Ranst, Eric |
| AuthorAffiliation | 1Department of Geology and Soil Science (WE13), Ghent University, Gent, Belgium. 2Department of Geoscience, Faculty of Geoscience and Petroleum Engineering, Universiti Teknologi PETRONAS, Perak Darul Ridzuan, Malaysia. 3Department of Physics and Astronomy, Ghent University, Gent, Belgium. 4Department of Geology and Mineralogy, Royal Museum for Central Africa, Tervuren, Belgium |
| AuthorAffiliation_xml | – name: 1Department of Geology and Soil Science (WE13), Ghent University, Gent, Belgium. 2Department of Geoscience, Faculty of Geoscience and Petroleum Engineering, Universiti Teknologi PETRONAS, Perak Darul Ridzuan, Malaysia. 3Department of Physics and Astronomy, Ghent University, Gent, Belgium. 4Department of Geology and Mineralogy, Royal Museum for Central Africa, Tervuren, Belgium |
| Author_xml | – sequence: 1 givenname: Eric surname: Van Ranst fullname: Van Ranst, Eric organization: 1Department of Geology and Soil Science (WE13), Ghent University, Gent, Belgium. 2Department of Geoscience, Faculty of Geoscience and Petroleum Engineering, Universiti Teknologi PETRONAS, Perak Darul Ridzuan, Malaysia. 3Department of Physics and Astronomy, Ghent University, Gent, Belgium. 4Department of Geology and Mineralogy, Royal Museum for Central Africa, Tervuren, Belgium – sequence: 2 givenname: Eswaran surname: Padmanabhan fullname: Padmanabhan, Eswaran – sequence: 3 givenname: Robert surname: Vandenberghe middlename: E fullname: Vandenberghe, Robert E – sequence: 4 givenname: Eddy surname: De Grave fullname: De Grave, Eddy – sequence: 5 givenname: Florias surname: Mees fullname: Mees, Florias |
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| Cites_doi | 10.1038/232624a0 10.1180/claymin.2010.045.4.413 10.1007/BF00011851 10.1002/jpln.19921550515 |
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| Copyright | Copyright © 2016 Wolters Kluwer Health, Inc. All rights reserved. Copyright Lippincott Williams & Wilkins Feb 2016 |
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| References | (R10-4-20210217) 1982; 1982 (R15-4-20210217) 1991; 130 (R11-4-20210217) 2010; 45 Childs (R1-4-20210217) 1992; 155 (R16-4-20210217) 1971; 232 |
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| Snippet | ABSTRACTAn Acrudoxic Kandiudult soil profile from Farmhill, KwaZulu-Natal Province, South Africa, was analyzed by Mössbauer spectroscopy as an example of a red... An Acrudoxic Kandiudult soil profile from Farmhill, KwaZulu-Natal Province, South Africa, was analyzed by Mossbauer spectroscopy as an example of a red soil... |
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| SubjectTerms | Dissolved organic matter Fractionation Iron oxides Leaching Soil profiles Soil sciences Soils Spectroscopy Spectrum analysis |
| Title | Yellowing of a Red South African Kandiudult, Studied by Means of Mössbauer Spectroscopy |
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