Alkaline dechlorination of poly(vinyl chloride) in organic solvents under mild conditions
A mild alkaline hydrolysis of poly(vinyl chloride) (PVC) in an organic solvent was conducted with a satisfactory degree of dechlorination (DD). Under atmospheric pressure, a DD of 98–99% was accomplished in the hydrolysis with NaOH in dimethylsulfoxide at 80 °C for 1–3 h. The resulting hydrolysis pr...
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Published in: | Polymer degradation and stability Vol. 86; no. 3; pp. 541 - 547 |
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Abstract | A mild alkaline hydrolysis of poly(vinyl chloride) (PVC) in an organic solvent was conducted with a satisfactory degree of dechlorination (DD). Under atmospheric pressure, a DD of 98–99% was accomplished in the hydrolysis with NaOH in dimethylsulfoxide at 80
°C for 1–3
h. The resulting hydrolysis product is poly(vinyl alcohol) with a very small chlorine content. Sodium chloride was the only by-product and no other harmful products such as dioxins were formed. Possible solvent recycling mainly depends on controlled use of water. |
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AbstractList | A mild alkaline hydrolysis of poly(vinyl chloride) (PVC) in an organic solvent was conducted with a satisfactory degree of dechlorination (DD). Under atmospheric pressure, a DD of 98–99% was accomplished in the hydrolysis with NaOH in dimethylsulfoxide at 80
°C for 1–3
h. The resulting hydrolysis product is poly(vinyl alcohol) with a very small chlorine content. Sodium chloride was the only by-product and no other harmful products such as dioxins were formed. Possible solvent recycling mainly depends on controlled use of water. |
Author | Tanimura, Toshifumi Yamaye, Makoto Ichiki, Tomoyuki Fujino, Hiroshi Kito, Taketoshi Ogata, Masahiko Yamanobe, Takeshi Yoshinaga, Tetsutaro Chen, Jie |
Author_xml | – sequence: 1 givenname: Tetsutaro surname: Yoshinaga fullname: Yoshinaga, Tetsutaro email: yosinaga@che.kyutech.ac.jp organization: Department of Applied Chemistry, Faculty of Engineering, Kyushu Institute of Technology, 1-1, Sensuicho, Tobata-ku, Kitakyushu 804-8550, Japan – sequence: 2 givenname: Makoto surname: Yamaye fullname: Yamaye, Makoto organization: Faculty of Engineering, Kyushu Kyoritsu University, Jiyugaoka, Yahatanishi-ku, Kitakyushu 807-8585, Japan – sequence: 3 givenname: Taketoshi surname: Kito fullname: Kito, Taketoshi organization: Department of Applied Chemistry, Faculty of Engineering, Kyushu Institute of Technology, 1-1, Sensuicho, Tobata-ku, Kitakyushu 804-8550, Japan – sequence: 4 givenname: Tomoyuki surname: Ichiki fullname: Ichiki, Tomoyuki organization: Department of Applied Chemistry, Faculty of Engineering, Kyushu Institute of Technology, 1-1, Sensuicho, Tobata-ku, Kitakyushu 804-8550, Japan – sequence: 5 givenname: Masahiko surname: Ogata fullname: Ogata, Masahiko organization: Department of Applied Chemistry, Faculty of Engineering, Kyushu Institute of Technology, 1-1, Sensuicho, Tobata-ku, Kitakyushu 804-8550, Japan – sequence: 6 givenname: Jie surname: Chen fullname: Chen, Jie organization: Department of Applied Chemistry, Faculty of Engineering, Kyushu Institute of Technology, 1-1, Sensuicho, Tobata-ku, Kitakyushu 804-8550, Japan – sequence: 7 givenname: Hiroshi surname: Fujino fullname: Fujino, Hiroshi organization: Kitakyushu City Institute of Environmental Sciences, Shinike, Tobata-ku, Kitakyushu 804-0082, Japan – sequence: 8 givenname: Toshifumi surname: Tanimura fullname: Tanimura, Toshifumi organization: Yamaguchi Prefectural Research Institute of Public Health, Asada, Yamaguchi 753-0871, Japan – sequence: 9 givenname: Takeshi surname: Yamanobe fullname: Yamanobe, Takeshi organization: Department of Chemistry, Gunma University, Tenjincho, Kiryu, Gunma 376-8515, Japan |
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Cites_doi | 10.1021/ie9709392 10.1016/0014-3057(91)90040-U 10.1002/prac.199733901127 10.1016/S0141-3910(97)00221-8 10.1016/0956-053X(92)90037-J 10.1002/(SICI)1097-4628(19980328)67:13<2171::AID-APP7>3.0.CO;2-B 10.1016/S0079-6700(02)00039-4 10.1016/0141-3910(95)00064-S 10.1021/es9506364 10.1016/S0141-3910(97)00272-3 10.1016/0045-6535(89)90340-8 10.1016/0045-6535(89)90346-9 10.1002/pola.10906 10.1021/ie980445k 10.2473/shigentosozai.116.737 |
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Keywords | Mild conditions Alkaline hydrolysis of PVC Chemical recycling Dechlorination in organic solvents Solvent effect Waste treatment Temperature effect Chemical degradation Experimental study Hydrolysis Organic solvent Dechlorination Basic medium Kinetics Recycling Polyvinyl chloride Plastic waste |
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SubjectTerms | Alkaline hydrolysis of PVC Applied sciences Chemical recycling Dechlorination in organic solvents Exact sciences and technology Mild conditions Polymer industry, paints, wood Technology of polymers Waste treatment |
Title | Alkaline dechlorination of poly(vinyl chloride) in organic solvents under mild conditions |
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