Alkaline dechlorination of poly(vinyl chloride) in organic solvents under mild conditions

A mild alkaline hydrolysis of poly(vinyl chloride) (PVC) in an organic solvent was conducted with a satisfactory degree of dechlorination (DD). Under atmospheric pressure, a DD of 98–99% was accomplished in the hydrolysis with NaOH in dimethylsulfoxide at 80 °C for 1–3 h. The resulting hydrolysis pr...

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Published in:Polymer degradation and stability Vol. 86; no. 3; pp. 541 - 547
Main Authors: Yoshinaga, Tetsutaro, Yamaye, Makoto, Kito, Taketoshi, Ichiki, Tomoyuki, Ogata, Masahiko, Chen, Jie, Fujino, Hiroshi, Tanimura, Toshifumi, Yamanobe, Takeshi
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Language:English
Published: Oxford Elsevier Ltd 01-12-2004
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Abstract A mild alkaline hydrolysis of poly(vinyl chloride) (PVC) in an organic solvent was conducted with a satisfactory degree of dechlorination (DD). Under atmospheric pressure, a DD of 98–99% was accomplished in the hydrolysis with NaOH in dimethylsulfoxide at 80 °C for 1–3 h. The resulting hydrolysis product is poly(vinyl alcohol) with a very small chlorine content. Sodium chloride was the only by-product and no other harmful products such as dioxins were formed. Possible solvent recycling mainly depends on controlled use of water.
AbstractList A mild alkaline hydrolysis of poly(vinyl chloride) (PVC) in an organic solvent was conducted with a satisfactory degree of dechlorination (DD). Under atmospheric pressure, a DD of 98–99% was accomplished in the hydrolysis with NaOH in dimethylsulfoxide at 80 °C for 1–3 h. The resulting hydrolysis product is poly(vinyl alcohol) with a very small chlorine content. Sodium chloride was the only by-product and no other harmful products such as dioxins were formed. Possible solvent recycling mainly depends on controlled use of water.
Author Tanimura, Toshifumi
Yamaye, Makoto
Ichiki, Tomoyuki
Fujino, Hiroshi
Kito, Taketoshi
Ogata, Masahiko
Yamanobe, Takeshi
Yoshinaga, Tetsutaro
Chen, Jie
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  givenname: Tetsutaro
  surname: Yoshinaga
  fullname: Yoshinaga, Tetsutaro
  email: yosinaga@che.kyutech.ac.jp
  organization: Department of Applied Chemistry, Faculty of Engineering, Kyushu Institute of Technology, 1-1, Sensuicho, Tobata-ku, Kitakyushu 804-8550, Japan
– sequence: 2
  givenname: Makoto
  surname: Yamaye
  fullname: Yamaye, Makoto
  organization: Faculty of Engineering, Kyushu Kyoritsu University, Jiyugaoka, Yahatanishi-ku, Kitakyushu 807-8585, Japan
– sequence: 3
  givenname: Taketoshi
  surname: Kito
  fullname: Kito, Taketoshi
  organization: Department of Applied Chemistry, Faculty of Engineering, Kyushu Institute of Technology, 1-1, Sensuicho, Tobata-ku, Kitakyushu 804-8550, Japan
– sequence: 4
  givenname: Tomoyuki
  surname: Ichiki
  fullname: Ichiki, Tomoyuki
  organization: Department of Applied Chemistry, Faculty of Engineering, Kyushu Institute of Technology, 1-1, Sensuicho, Tobata-ku, Kitakyushu 804-8550, Japan
– sequence: 5
  givenname: Masahiko
  surname: Ogata
  fullname: Ogata, Masahiko
  organization: Department of Applied Chemistry, Faculty of Engineering, Kyushu Institute of Technology, 1-1, Sensuicho, Tobata-ku, Kitakyushu 804-8550, Japan
– sequence: 6
  givenname: Jie
  surname: Chen
  fullname: Chen, Jie
  organization: Department of Applied Chemistry, Faculty of Engineering, Kyushu Institute of Technology, 1-1, Sensuicho, Tobata-ku, Kitakyushu 804-8550, Japan
– sequence: 7
  givenname: Hiroshi
  surname: Fujino
  fullname: Fujino, Hiroshi
  organization: Kitakyushu City Institute of Environmental Sciences, Shinike, Tobata-ku, Kitakyushu 804-0082, Japan
– sequence: 8
  givenname: Toshifumi
  surname: Tanimura
  fullname: Tanimura, Toshifumi
  organization: Yamaguchi Prefectural Research Institute of Public Health, Asada, Yamaguchi 753-0871, Japan
– sequence: 9
  givenname: Takeshi
  surname: Yamanobe
  fullname: Yamanobe, Takeshi
  organization: Department of Chemistry, Gunma University, Tenjincho, Kiryu, Gunma 376-8515, Japan
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Issue 3
Keywords Mild conditions
Alkaline hydrolysis of PVC
Chemical recycling
Dechlorination in organic solvents
Solvent effect
Waste treatment
Temperature effect
Chemical degradation
Experimental study
Hydrolysis
Organic solvent
Dechlorination
Basic medium
Kinetics
Recycling
Polyvinyl chloride
Plastic waste
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Snippet A mild alkaline hydrolysis of poly(vinyl chloride) (PVC) in an organic solvent was conducted with a satisfactory degree of dechlorination (DD). Under...
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SubjectTerms Alkaline hydrolysis of PVC
Applied sciences
Chemical recycling
Dechlorination in organic solvents
Exact sciences and technology
Mild conditions
Polymer industry, paints, wood
Technology of polymers
Waste treatment
Title Alkaline dechlorination of poly(vinyl chloride) in organic solvents under mild conditions
URI https://dx.doi.org/10.1016/j.polymdegradstab.2004.06.008
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