Electrochemical Characterization of a Polymer Inclusion Membrane Made of Cellulose Triacetate and Aliquat 336 and Its Application to Sulfonamides Separation

An electrochemical characterization of a polymer inclusion membrane (PIM) fabricated with the ionic liquid (IL) Aliquat 336 (26%) and the polymer cellulose triacetate (CTA) (76%) is presented. Considering the use of PIMs in separation systems to remove pollutants from water, the characterization was...

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Published in:	Separations Vol. 5; no. 1; p. 5
Main Authors:	Benavente, Juana, Romero, Virginia, Vázquez, María, Anticó, Enriqueta, Fontàs, Clàudia
Format:	Journal Article
Language:	English
Published:	Basel MDPI AG 01-03-2018 MDPI (Multidisciplinary Digital Publishing Institute)
Subjects:	Aliquat Aliquat 336 Antibiotics Anàlisi electroquímica Cellulose Cellulose triacetate Chemical compounds Contact angle Electrical resistivity Electrochemical analysis Electrochemical impedance spectroscopy Electrolytes Espectroscòpia d'impedància Handbooks Impedance spectroscopy Ionic liquids membrane potential Membranes Membranes (Technology) Membranes (Tecnologia) Organic chemistry Pollutants polymer inclusion membrane Polymers Polímers Powder injection molding Separation Sodium chloride Sulfonamides Transport New York United States > US Spain
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Abstract	An electrochemical characterization of a polymer inclusion membrane (PIM) fabricated with the ionic liquid (IL) Aliquat 336 (26%) and the polymer cellulose triacetate (CTA) (76%) is presented. Considering the use of PIMs in separation systems to remove pollutants from water, the characterization was performed with NaCl solutions by measuring membrane potential, electrochemical impedance spectroscopy, and salt diffusion and results were compared with those obtained from dry membranes. Results showed a significant reduction in the membrane diffusive permeability and electrical conductivity as well as the transport number of cation Na+ across the PIM when compared with solution values, which could be mainly related to the dense character of the membrane. Membrane application in the separation of different sulfonamides (sulfathiazole, sulfapyridine, sulfamethazine, and sulfamethoxazole) from water, with 1 M NaCl solution as striping phase, was also considered. These results indicated that the different chemical characteristics of the compounds, as well as the compact structure of the PIM, limited the transport of the organic molecules though it.
AbstractList	An electrochemical characterization of a polymer inclusion membrane (PIM) fabricated with the ionic liquid (IL) Aliquat 336 (26%) and the polymer cellulose triacetate (CTA) (76%) is presented. Considering the use of PIMs in separation systems to remove pollutants from water, the characterization was performed with NaCl solutions by measuring membrane potential, electrochemical impedance spectroscopy, and salt diffusion and results were compared with those obtained from dry membranes. Results showed a significant reduction in the membrane diffusive permeability and electrical conductivity as well as the transport number of cation Na+ across the PIM when compared with solution values, which could be mainly related to the dense character of the membrane. Membrane application in the separation of different sulfonamides (sulfathiazole, sulfapyridine, sulfamethazine, and sulfamethoxazole) from water, with 1 M NaCl solution as striping phase, was also considered. These results indicated that the different chemical characteristics of the compounds, as well as the compact structure of the PIM, limited the transport of the organic molecules though it. An electrochemical characterization of a polymer inclusion membrane (PIM) fabricated with the ionic liquid (IL) Aliquat 336 (26%) and the polymer cellulose triacetate (CTA) (76%) is presented. Considering the use of PIMs in separation systems to remove pollutants from water, the characterization was performed with NaCl solutions by measuring membrane potential, electrochemical impedance spectroscopy, and salt diffusion and results were compared with those obtained from dry membranes. Results showed a significant reduction in the membrane diffusive permeability and electrical conductivity as well as the transport number of cation Na+ across the PIM when compared with solution values, which could be mainly related to the dense character of the membrane. Membrane application in the separation of different sulfonamides (sulfathiazole, sulfapyridine, sulfamethazine, and sulfamethoxazole) from water, with 1 M NaCl solution as striping phase, was also considered. These results indicated that the different chemical characteristics of the compounds, as well as the compact structure of the PIM, limited the transport of the organic molecules though it The financial support of the research project CTM2016-78798-C2-2-P (AEI/FEDER/UE) is acknowledged.
Author	Vázquez, María Anticó, Enriqueta Fontàs, Clàudia Benavente, Juana Romero, Virginia
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Snippet	An electrochemical characterization of a polymer inclusion membrane (PIM) fabricated with the ionic liquid (IL) Aliquat 336 (26%) and the polymer cellulose... An electrochemical characterization of a polymer inclusion membrane (PIM) fabricated with the ionic liquid (IL) Aliquat 336 (26%) and the polymer cellulose...
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SubjectTerms	Aliquat Aliquat 336 Antibiotics Anàlisi electroquímica Cellulose Cellulose triacetate Chemical compounds Contact angle Electrical resistivity Electrochemical analysis Electrochemical impedance spectroscopy Electrolytes Espectroscòpia d'impedància Handbooks Impedance spectroscopy Ionic liquids membrane potential Membranes Membranes (Technology) Membranes (Tecnologia) Organic chemistry Pollutants polymer inclusion membrane Polymers Polímers Powder injection molding Separation Sodium chloride Sulfonamides Transport
Title	Electrochemical Characterization of a Polymer Inclusion Membrane Made of Cellulose Triacetate and Aliquat 336 and Its Application to Sulfonamides Separation
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