Influence of Acids on Extraction Efficiency of Zirconium and Rare Earth Metals in Eudialyte Concentrate Leaching

• Published in: Journal of mining science Vol. 55; no. 6; pp. 984 - 994
• Main Authors: Chanturia, V. A., Minenko, V. G., Koporulina, E. V., Ryazantseva, M. V., Samusev, A. L.
• Format: Journal Article
• Language: English
• Published: Moscow Pleiades Publishing 01-11-2019; Springer; Springer Nature B.V
• Subjects: Acids; Aluminum; Analytical methods; Cations; Earth; Earth and Environmental Science; Earth Sciences; Gels; Geophysics/Geodesy; Geotechnical Engineering & Applied Earth Sciences; Gypsum; Heavy metals; Iron; Leaching; Magnesium; Manganese; Metals; Mineral Dressing; Mineral Resources; Morphology; Rare earth elements; Rare earth metals; Silica; Silica gel; Silicon dioxide; Sulfates; Sulfur; Sulfuric acid; Sulphuric acid; Titanium; Zirconium; eudialyte concentrate; Acid leaching; loss of valuable components; zirconium; rare earth metals; silica gel
• ISSN: 1062-7391; 1573-8736
• DOI: 10.1134/S106273911906637X

The influence of nitric, sulfuric and chlorohydric acids on the morphology, composition of elements, structural and chemical transformation of mineral surface and leaching of eudialyte concentrate is studied using a set of the modern analytical techniques. Specific features are revealed in the nature and degree of eudialyte decomposition under the influence of different acids. These features affect the intensity of removal of basic cations of Al, Na, Ca, Mg, K, Ti, Mn, Fe, Sr and Zr from the mineral surface. The behavior and regular patterns in the formation of silica gel and secondary phases during dissolution of eudialyte concentrates are examined. Sulfuric acid, which ensures the highest extraction of Zr and rare earth metals in pregnant solution, contributes to maximum formation of silica gel and considerable quantity of gypsum and insoluble sulfates, which results in high loss of Zr and rare earth metals. The use of nitric and chlorohydric acids reduces the loss of Zr and rare earth metals by 2-5 times.