Properties of amorphous alloys of Al–REM–Ni and Al–REM–Ni–Fe systems with nanocrystalline structure
We have investigated the influence of annealing on the physicochemical properties of amorphous alloys based on aluminum. It has been established that, after annealing at the temperature of the first stage of crystallization, an X-ray amorphous structure with an insignificant volume fraction of a dis...
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| Published in: | Materials science (New York, N.Y.) Vol. 48; no. 4; pp. 555 - 559 |
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| Abstract | We have investigated the influence of annealing on the physicochemical properties of amorphous alloys based on aluminum. It has been established that, after annealing at the temperature of the first stage of crystallization, an X-ray amorphous structure with an insignificant volume fraction of a disordered nanocrystalline phase forms. In this case, the polarization resistance of the surface of the alloys in a 0.5 М aqueous solution of NaOH increases substantially, and the free potential shifts in the direction to anode potentials. In structural transformations under these conditions, the microhardness of the alloys increases to a maximum degree. |
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| AbstractList | We have investigated the influence of annealing on the physicochemical properties of amorphous alloys based on aluminum. It has been established that, after annealing at the temperature of the first stage of crystallization, an X-ray amorphous structure with an insignificant volume fraction of a disordered nanocrystalline phase forms. In this case, the polarization resistance of the surface of the alloys in a 0.5 M aqueous solution of NaOH increases substantially, and the free potential shifts in the direction to anode potentials. In structural transformations under these conditions, the microhardness of the alloys increases to a maximum degree. Keywords: amorphous metallic alloys, nanocrystallization, microhardness, electric resistance, corrosion. We have investigated the influence of annealing on the physicochemical properties of amorphous alloys based on aluminum. It has been established that, after annealing at the temperature of the first stage of crystallization, an X-ray amorphous structure with an insignificant volume fraction of a disordered nanocrystalline phase forms. In this case, the polarization resistance of the surface of the alloys in a 0.5 М aqueous solution of NaOH increases substantially, and the free potential shifts in the direction to anode potentials. In structural transformations under these conditions, the microhardness of the alloys increases to a maximum degree. We have investigated the influence of annealing on the physicochemical properties of amorphous alloys based on aluminum. It has been established that, after annealing at the temperature of the first stage of crystallization, an X-ray amorphous structure with an insignificant volume fraction of a disordered nanocrystalline phase forms. In this case, the polarization resistance of the surface of the alloys in a 0.5 Ðoe aqueous solution of NaOH increases substantially, and the free potential shifts in the direction to anode potentials. In structural transformations under these conditions, the microhardness of the alloys increases to a maximum degree. We have investigated the influence of annealing on the physicochemical properties of amorphous alloys based on aluminum. It has been established that, after annealing at the temperature of the first stage of crystallization, an X-ray amorphous structure with an insignificant volume fraction of a disordered nanocrystalline phase forms. In this case, the polarization resistance of the surface of the alloys in a 0.5 M aqueous solution of NaOH increases substantially, and the free potential shifts in the direction to anode potentials. In structural transformations under these conditions, the microhardness of the alloys increases to a maximum degree. |
| Audience | Academic |
| Author | Pereverzeva, T. H. Kovbuz, M. O. Boichyshyn, L. M. Hertsyk, O. M. Kotur, B. Ya |
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| Cites_doi | 10.1016/j.intermet.2004.04.004 10.1007/BF00723766 10.1023/A:1018436931465 10.1016/j.jnoncrysol.2008.01.020 10.1016/S1359-6454(02)00511-6 |
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| References | Mika, Karolus, Haneczok (CR9) 2008; 354 CR11 Tsai, Inoue, Masumoto (CR1) 1988; 7 Munoz-Morris, Surinach, Gich (CR10) 2003; 51 Larikov (CR2) 1995; 11 Mudry, Bednarska, Kotur, Hertsyk (CR3) 2004; 25 CR5 Hertsyk, Kovbuz, Bednars’ka, Pereverzeva (CR8) 2010; 51 Abrosimova, Aronin, Zver’kova (CR12) 1998; 40 Basu, Ranganathan (CR4) 2004; 12 Monticelli, Zucchi, Brunoro, Trabanelli (CR6) 1997; 27 Mudryi, Korolyshyn, Kotur, Bednars’ka, Hertsyk, Kovbuz (CR7) 2005; 41 9537_CR5 GE Abrosimova (9537_CR12) 1998; 40 M Munoz-Morris (9537_CR10) 2003; 51 J Basu (9537_CR4) 2004; 12 9537_CR11 T Mika (9537_CR9) 2008; 354 S Mudry (9537_CR3) 2004; 25 SI Mudryi (9537_CR7) 2005; 41 C Monticelli (9537_CR6) 1997; 27 LN Larikov (9537_CR2) 1995; 11 AP Tsai (9537_CR1) 1988; 7 O Hertsyk (9537_CR8) 2010; 51 |
| References_xml | – volume: 12 start-page: 1045 issue: 10–11 year: 2004 end-page: 1050 ident: CR4 article-title: Crystallization in Al-ETM-LTM-La metallic glasses publication-title: Intermetallics doi: 10.1016/j.intermet.2004.04.004 contributor: fullname: Ranganathan – volume: 41 start-page: 126 issue: 3 year: 2005 end-page: 128 ident: CR7 article-title: Evaluation of the volume fraction of the crystalline phase in amorphous alloys publication-title: Fiz.-Khim. Mekh. Mater. contributor: fullname: Kovbuz – volume: 7 start-page: 805 year: 1988 end-page: 807 ident: CR1 article-title: Ductile Al-Ni-Zr amorphous alloys with high mechanical strength publication-title: J. Mater. Sci. Lett. doi: 10.1007/BF00723766 contributor: fullname: Masumoto – volume: 25 start-page: 373 issue: 4 year: 2004 end-page: 378 ident: CR3 article-title: Temperatures changes of structure in Al Ni Y amorphous alloy publication-title: Arch. Mater. Sci. contributor: fullname: Hertsyk – volume: 11 start-page: 69 issue: 1 year: 1995 end-page: 72 ident: CR2 article-title: Diffusion processes in nanocrystalline materials publication-title: Metallofiz. Noveish. Tekhnol. contributor: fullname: Larikov – ident: CR5 – volume: 27 start-page: 325 year: 1997 end-page: 334 ident: CR6 article-title: Corrosion and corrosion inhibition of alumina particulate/aluminum alloys metal matrix composites in neutral chloride solutions publication-title: J. Appl. Electrochem. doi: 10.1023/A:1018436931465 contributor: fullname: Trabanelli – volume: 354 start-page: 3099 issue: 27 year: 2008 end-page: 3106 ident: CR9 article-title: Influence of Gd and Fe on crystallization of Al Y Ni amorphous alloy publication-title: J. Non-Cryst. Sol. doi: 10.1016/j.jnoncrysol.2008.01.020 contributor: fullname: Haneczok – volume: 40 start-page: 10 issue: 1 year: 1998 end-page: 16 ident: CR12 article-title: Formation, structure, and microhardness of Ni–Mo–B nanocrystalline alloys publication-title: Fiz. Tverd. Tela contributor: fullname: Zver’kova – volume: 51 start-page: 1067 year: 2003 end-page: 1077 ident: CR10 article-title: Crystallization of a Al–4Ni–6Ce glass and its influence on mechanical properties publication-title: Acta Mater. doi: 10.1016/S1359-6454(02)00511-6 contributor: fullname: Gich – volume: 51 start-page: 329 year: 2010 end-page: 334 ident: CR8 article-title: Influence of рН of the environment on the corrosion resistance of the Al Gd Ni amorphous metallic alloy publication-title: Visn. L’viv. Univ. Ser. Khimiya. contributor: fullname: Pereverzeva – ident: CR11 – volume: 12 start-page: 1045 issue: 10–11 year: 2004 ident: 9537_CR4 publication-title: Intermetallics doi: 10.1016/j.intermet.2004.04.004 contributor: fullname: J Basu – volume: 27 start-page: 325 year: 1997 ident: 9537_CR6 publication-title: J. Appl. Electrochem. doi: 10.1023/A:1018436931465 contributor: fullname: C Monticelli – volume: 7 start-page: 805 year: 1988 ident: 9537_CR1 publication-title: J. Mater. Sci. Lett. doi: 10.1007/BF00723766 contributor: fullname: AP Tsai – volume: 51 start-page: 1067 year: 2003 ident: 9537_CR10 publication-title: Acta Mater. doi: 10.1016/S1359-6454(02)00511-6 contributor: fullname: M Munoz-Morris – volume: 40 start-page: 10 issue: 1 year: 1998 ident: 9537_CR12 publication-title: Fiz. Tverd. Tela contributor: fullname: GE Abrosimova – ident: 9537_CR5 – volume: 41 start-page: 126 issue: 3 year: 2005 ident: 9537_CR7 publication-title: Fiz.-Khim. Mekh. Mater. contributor: fullname: SI Mudryi – volume: 11 start-page: 69 issue: 1 year: 1995 ident: 9537_CR2 publication-title: Metallofiz. Noveish. Tekhnol. contributor: fullname: LN Larikov – volume: 25 start-page: 373 issue: 4 year: 2004 ident: 9537_CR3 publication-title: Arch. Mater. Sci. contributor: fullname: S Mudry – volume: 354 start-page: 3099 issue: 27 year: 2008 ident: 9537_CR9 publication-title: J. Non-Cryst. Sol. doi: 10.1016/j.jnoncrysol.2008.01.020 contributor: fullname: T Mika – volume: 51 start-page: 329 year: 2010 ident: 9537_CR8 publication-title: Visn. L’viv. Univ. Ser. Khimiya. contributor: fullname: O Hertsyk – ident: 9537_CR11 |
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| SubjectTerms | Annealing Characterization and Evaluation of Materials Chemistry and Materials Science Corrosion and anti-corrosives Hardness Materials Science Metallic glasses Solid Mechanics Specialty metals industry Structural Materials |
| Title | Properties of amorphous alloys of Al–REM–Ni and Al–REM–Ni–Fe systems with nanocrystalline structure |
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