Surface NMR using quantum sensors in diamond
NMR is a noninvasive, molecular-level spectroscopic technique widely used for chemical characterization. However, it lacks the sensitivity to probe the small number of spins at surfaces and interfaces. Here, we use nitrogen vacancy (NV) centers in diamond as quantum sensors to optically detect NMR s...
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| Published in: | Proceedings of the National Academy of Sciences - PNAS Vol. 119; no. 5 |
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| Main Authors: | , , , , , , , |
| Format: | Journal Article |
| Language: | English |
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01-02-2022
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| Abstract | NMR is a noninvasive, molecular-level spectroscopic technique widely used for chemical characterization. However, it lacks the sensitivity to probe the small number of spins at surfaces and interfaces. Here, we use nitrogen vacancy (NV) centers in diamond as quantum sensors to optically detect NMR signals from chemically modified thin films. To demonstrate the method's capabilities, aluminum oxide layers, common supports in catalysis and materials science, are prepared by atomic layer deposition and are subsequently functionalized by phosphonate chemistry to form self-assembled monolayers. The surface NV-NMR technique detects spatially resolved NMR signals from the monolayer, indicates chemical binding, and quantifies molecular coverage. In addition, it can monitor in real time the formation kinetics at the solid-liquid interface. With our approach, we show that NV quantum sensors are a surface-sensitive NMR tool with femtomole sensitivity for in situ analysis in catalysis, materials, and biological research. |
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| AbstractList | NMR is a noninvasive, molecular-level spectroscopic technique widely used for chemical characterization. However, it lacks the sensitivity to probe the small number of spins at surfaces and interfaces. Here, we use nitrogen vacancy (NV) centers in diamond as quantum sensors to optically detect NMR signals from chemically modified thin films. To demonstrate the method's capabilities, aluminum oxide layers, common supports in catalysis and materials science, are prepared by atomic layer deposition and are subsequently functionalized by phosphonate chemistry to form self-assembled monolayers. The surface NV-NMR technique detects spatially resolved NMR signals from the monolayer, indicates chemical binding, and quantifies molecular coverage. In addition, it can monitor in real time the formation kinetics at the solid-liquid interface. With our approach, we show that NV quantum sensors are a surface-sensitive NMR tool with femtomole sensitivity for in situ analysis in catalysis, materials, and biological research. Many of the functions and applications of materials in catalysis, energy conversion, drug delivery, bioanalysis, and electronics are based on their interfacial properties and structures. The characterization of their molecular properties under ambient or chemically reactive conditions is a fundamental scientific challenge. Here, we develop a surface-sensitive magnetic resonance technique that combines the nanoscale-sensing capabilities of defects in diamond with a high precision and versatile protocol for diamond surface modification. We demonstrate the functionality of this method for probing the molecular properties and kinetics at surfaces and interfaces under ambient conditions. NMR is a noninvasive, molecular-level spectroscopic technique widely used for chemical characterization. However, it lacks the sensitivity to probe the small number of spins at surfaces and interfaces. Here, we use nitrogen vacancy (NV) centers in diamond as quantum sensors to optically detect NMR signals from chemically modified thin films. To demonstrate the method’s capabilities, aluminum oxide layers, common supports in catalysis and materials science, are prepared by atomic layer deposition and are subsequently functionalized by phosphonate chemistry to form self-assembled monolayers. The surface NV-NMR technique detects spatially resolved NMR signals from the monolayer, indicates chemical binding, and quantifies molecular coverage. In addition, it can monitor in real time the formation kinetics at the solid–liquid interface. With our approach, we show that NV quantum sensors are a surface-sensitive NMR tool with femtomole sensitivity for in situ analysis in catalysis, materials, and biological research. |
| Author | Heindl, Markus W Bartl, Johannes D Bucher, Dominik B Liu, Kristina S Henning, Alex Sharp, Ian D Rizzato, Roberto Allert, Robin D |
| Author_xml | – sequence: 1 givenname: Kristina S orcidid: 0000-0001-8532-4503 surname: Liu fullname: Liu, Kristina S organization: Department of Chemistry, Technical University of Munich, Munich 85748, Germany – sequence: 2 givenname: Alex orcidid: 0000-0003-0419-4992 surname: Henning fullname: Henning, Alex organization: Physics Department, Technical University of Munich, Garching 85748, Germany – sequence: 3 givenname: Markus W orcidid: 0000-0001-7968-617X surname: Heindl fullname: Heindl, Markus W organization: Physics Department, Technical University of Munich, Garching 85748, Germany – sequence: 4 givenname: Robin D surname: Allert fullname: Allert, Robin D organization: Department of Chemistry, Technical University of Munich, Munich 85748, Germany – sequence: 5 givenname: Johannes D orcidid: 0000-0003-3767-8782 surname: Bartl fullname: Bartl, Johannes D organization: Physics Department, Technical University of Munich, Garching 85748, Germany – sequence: 6 givenname: Ian D orcidid: 0000-0001-5238-7487 surname: Sharp fullname: Sharp, Ian D organization: Physics Department, Technical University of Munich, Garching 85748, Germany – sequence: 7 givenname: Roberto surname: Rizzato fullname: Rizzato, Roberto organization: Department of Chemistry, Technical University of Munich, Munich 85748, Germany – sequence: 8 givenname: Dominik B surname: Bucher fullname: Bucher, Dominik B email: dominik.bucher@tum.de organization: Department of Chemistry, Technical University of Munich, Munich 85748, Germany; dominik.bucher@tum.de |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/35082146$$D View this record in MEDLINE/PubMed |
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| Keywords | quantum sensing surface analysis spectroscopy self-assembled monolayer NV center in diamond |
| Language | English |
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| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 Edited by D. D. Awschalom, Pritzker School of Molecular Engineering, The University of Chicago, Chicago, IL; received June 24, 2021; accepted December 10, 2021 Author contributions: D.B.B. designed research; K.S.L. and R.R. performed research; A.H., M.W.H., R.D.A., J.D.B., and I.D.S. contributed new reagents/analytic tools; K.S.L., A.H., R.R., and D.B.B. analyzed data; and K.S.L., R.R., and D.B.B. wrote the paper. |
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| Snippet | NMR is a noninvasive, molecular-level spectroscopic technique widely used for chemical characterization. However, it lacks the sensitivity to probe the small... Many of the functions and applications of materials in catalysis, energy conversion, drug delivery, bioanalysis, and electronics are based on their interfacial... |
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| SubjectTerms | Aluminum Aluminum oxide Atomic layer epitaxy Biological research Catalysis Diamonds Interfaces Liquid-solid interfaces Materials science Monolayers NMR Nuclear magnetic resonance Phosphonates Physical Sciences Quantum sensors Self-assembled monolayers Self-assembly Sensitivity analysis Sensors Thin films |
| Title | Surface NMR using quantum sensors in diamond |
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