High strength poly(vinyl alcohol)/poly(acrylic acid) cross-linked nanofibrous hybrid composites incorporating nanohybrid POSS

A novel system for enhancing the mechanical properties of PVA/PAA cross-linked nanofibrous hybrid composites incorporating POSS was developed in this study. An electrospinning and followed by simple heat-treatment strategy was used to prepare nanofibrous PVA/PAA composite hydrogels. The mechanical p...

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Published in:Composites science and technology Vol. 110; pp. 111 - 117
Main Authors: Lee, Eun-Sook, Lei, Danyun, Devarayan, Kesavan, Kim, Byoung-Suhk
Format: Journal Article
Language:English
Published: Elsevier Ltd 06-04-2015
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Abstract A novel system for enhancing the mechanical properties of PVA/PAA cross-linked nanofibrous hybrid composites incorporating POSS was developed in this study. An electrospinning and followed by simple heat-treatment strategy was used to prepare nanofibrous PVA/PAA composite hydrogels. The mechanical properties have been dramatically improved by a heat-treatment as well as an incorporated nanohybrid POSS. The PVA/PAA composite nanofibers exhibited 2.3 times higher tensile strength and 4.4 times higher Young’s modulus after heat-treatment, suggesting that the elasticity of these nanofibers was reinforced by the formation of chemically cross-linked networks. Moreover, compared to the heat-treated PVA/PAA nanofibers without POSS, the PVA/PAA/POSS hybrid nanofibers (POSS content ∼0.6wt.%) showed 3.3 times improvement in Young’s modulus and 2.0 times increase in tensile strength after heat-treatment at 160°C for 30min. This suggests that the elasticity of these nanofibers were dramatically reinforced by the incorporated POSS nanoparticles as well as chemically cross-linked networks via an ester bond formation between OH groups of PVA and COOH groups in PAA.
AbstractList A novel system for enhancing the mechanical properties of PVA/PAA cross-linked nanofibrous hybrid composites incorporating POSS was developed in this study. An electrospinning and followed by simple heat-treatment strategy was used to prepare nanofibrous PVA/PAA composite hydrogels. The mechanical properties have been dramatically improved by a heat-treatment as well as an incorporated nanohybrid POSS. The PVA/PAA composite nanofibers exhibited 2.3 times higher tensile strength and 4.4 times higher Young's modulus after heat-treatment, suggesting that the elasticity of these nanofibers was reinforced by the formation of chemically cross-linked networks. Moreover, compared to the heat-treated PVA/PAA nanofibers without POSS, the PVA/PAA/POSS hybrid nanofibers (POSS content ~0.6 wt.%) showed 3.3 times improvement in Young's modulus and 2.0 times increase in tensile strength after heat-treatment at 160 [degrees]C for 30 min. This suggests that the elasticity of these nanofibers were dramatically reinforced by the incorporated POSS nanoparticles as well as chemically cross-linked networks via an ester bond formation between -OH groups of PVA and -COOH groups in PAA.
A novel system for enhancing the mechanical properties of PVA/PAA cross-linked nanofibrous hybrid composites incorporating POSS was developed in this study. An electrospinning and followed by simple heat-treatment strategy was used to prepare nanofibrous PVA/PAA composite hydrogels. The mechanical properties have been dramatically improved by a heat-treatment as well as an incorporated nanohybrid POSS. The PVA/PAA composite nanofibers exhibited 2.3 times higher tensile strength and 4.4 times higher Young’s modulus after heat-treatment, suggesting that the elasticity of these nanofibers was reinforced by the formation of chemically cross-linked networks. Moreover, compared to the heat-treated PVA/PAA nanofibers without POSS, the PVA/PAA/POSS hybrid nanofibers (POSS content ∼0.6wt.%) showed 3.3 times improvement in Young’s modulus and 2.0 times increase in tensile strength after heat-treatment at 160°C for 30min. This suggests that the elasticity of these nanofibers were dramatically reinforced by the incorporated POSS nanoparticles as well as chemically cross-linked networks via an ester bond formation between OH groups of PVA and COOH groups in PAA.
Author Lei, Danyun
Lee, Eun-Sook
Devarayan, Kesavan
Kim, Byoung-Suhk
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Keywords A. Structural composites
B. Mechanical properties
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Snippet A novel system for enhancing the mechanical properties of PVA/PAA cross-linked nanofibrous hybrid composites incorporating POSS was developed in this study. An...
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StartPage 111
SubjectTerms A. Fibers
A. Structural composites
B. Mechanical properties
Crosslinking
E. Electro-spinning
Heat treatment
Hybrid composites
Nanofibers
Nanostructure
Networks
Polyvinyl alcohols
Tensile strength
Title High strength poly(vinyl alcohol)/poly(acrylic acid) cross-linked nanofibrous hybrid composites incorporating nanohybrid POSS
URI https://dx.doi.org/10.1016/j.compscitech.2015.02.001
https://search.proquest.com/docview/1692361192
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