High strength poly(vinyl alcohol)/poly(acrylic acid) cross-linked nanofibrous hybrid composites incorporating nanohybrid POSS
A novel system for enhancing the mechanical properties of PVA/PAA cross-linked nanofibrous hybrid composites incorporating POSS was developed in this study. An electrospinning and followed by simple heat-treatment strategy was used to prepare nanofibrous PVA/PAA composite hydrogels. The mechanical p...
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Published in: | Composites science and technology Vol. 110; pp. 111 - 117 |
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06-04-2015
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Abstract | A novel system for enhancing the mechanical properties of PVA/PAA cross-linked nanofibrous hybrid composites incorporating POSS was developed in this study. An electrospinning and followed by simple heat-treatment strategy was used to prepare nanofibrous PVA/PAA composite hydrogels. The mechanical properties have been dramatically improved by a heat-treatment as well as an incorporated nanohybrid POSS. The PVA/PAA composite nanofibers exhibited 2.3 times higher tensile strength and 4.4 times higher Young’s modulus after heat-treatment, suggesting that the elasticity of these nanofibers was reinforced by the formation of chemically cross-linked networks. Moreover, compared to the heat-treated PVA/PAA nanofibers without POSS, the PVA/PAA/POSS hybrid nanofibers (POSS content ∼0.6wt.%) showed 3.3 times improvement in Young’s modulus and 2.0 times increase in tensile strength after heat-treatment at 160°C for 30min. This suggests that the elasticity of these nanofibers were dramatically reinforced by the incorporated POSS nanoparticles as well as chemically cross-linked networks via an ester bond formation between OH groups of PVA and COOH groups in PAA. |
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AbstractList | A novel system for enhancing the mechanical properties of PVA/PAA cross-linked nanofibrous hybrid composites incorporating POSS was developed in this study. An electrospinning and followed by simple heat-treatment strategy was used to prepare nanofibrous PVA/PAA composite hydrogels. The mechanical properties have been dramatically improved by a heat-treatment as well as an incorporated nanohybrid POSS. The PVA/PAA composite nanofibers exhibited 2.3 times higher tensile strength and 4.4 times higher Young's modulus after heat-treatment, suggesting that the elasticity of these nanofibers was reinforced by the formation of chemically cross-linked networks. Moreover, compared to the heat-treated PVA/PAA nanofibers without POSS, the PVA/PAA/POSS hybrid nanofibers (POSS content ~0.6 wt.%) showed 3.3 times improvement in Young's modulus and 2.0 times increase in tensile strength after heat-treatment at 160 [degrees]C for 30 min. This suggests that the elasticity of these nanofibers were dramatically reinforced by the incorporated POSS nanoparticles as well as chemically cross-linked networks via an ester bond formation between -OH groups of PVA and -COOH groups in PAA. A novel system for enhancing the mechanical properties of PVA/PAA cross-linked nanofibrous hybrid composites incorporating POSS was developed in this study. An electrospinning and followed by simple heat-treatment strategy was used to prepare nanofibrous PVA/PAA composite hydrogels. The mechanical properties have been dramatically improved by a heat-treatment as well as an incorporated nanohybrid POSS. The PVA/PAA composite nanofibers exhibited 2.3 times higher tensile strength and 4.4 times higher Young’s modulus after heat-treatment, suggesting that the elasticity of these nanofibers was reinforced by the formation of chemically cross-linked networks. Moreover, compared to the heat-treated PVA/PAA nanofibers without POSS, the PVA/PAA/POSS hybrid nanofibers (POSS content ∼0.6wt.%) showed 3.3 times improvement in Young’s modulus and 2.0 times increase in tensile strength after heat-treatment at 160°C for 30min. This suggests that the elasticity of these nanofibers were dramatically reinforced by the incorporated POSS nanoparticles as well as chemically cross-linked networks via an ester bond formation between OH groups of PVA and COOH groups in PAA. |
Author | Lei, Danyun Lee, Eun-Sook Devarayan, Kesavan Kim, Byoung-Suhk |
Author_xml | – sequence: 1 givenname: Eun-Sook surname: Lee fullname: Lee, Eun-Sook organization: Department of Organic Materials & Fiber Engineering, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju-si, Jeollabuk-do 561-756, Republic of Korea – sequence: 2 givenname: Danyun surname: Lei fullname: Lei, Danyun organization: Department of BIN Fusion Technology, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju-si, Jeollabuk-do 561-756, Republic of Korea – sequence: 3 givenname: Kesavan surname: Devarayan fullname: Devarayan, Kesavan organization: Department of BIN Fusion Technology, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju-si, Jeollabuk-do 561-756, Republic of Korea – sequence: 4 givenname: Byoung-Suhk surname: Kim fullname: Kim, Byoung-Suhk email: kbsuhk@jbnu.ac.kr organization: Department of Organic Materials & Fiber Engineering, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju-si, Jeollabuk-do 561-756, Republic of Korea |
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Snippet | A novel system for enhancing the mechanical properties of PVA/PAA cross-linked nanofibrous hybrid composites incorporating POSS was developed in this study. An... |
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SubjectTerms | A. Fibers A. Structural composites B. Mechanical properties Crosslinking E. Electro-spinning Heat treatment Hybrid composites Nanofibers Nanostructure Networks Polyvinyl alcohols Tensile strength |
Title | High strength poly(vinyl alcohol)/poly(acrylic acid) cross-linked nanofibrous hybrid composites incorporating nanohybrid POSS |
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