Synthesis and Characterization of Polymeric Materials from Vegetable Oils

• Published in: Macromolecular symposia. Vol. 286; no. 1; pp. 89 - 94
• Main Authors: Lopes, Roseany V.V, Loureiro, Nuno Pedro D, Zamian, José R, Fonseca, Pâmela S, Macedo, Júlio L, dos Santos, Maria L, Sales, Maria J.A
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley-VCH Verlag 01-11-2009; WILEY-VCH Verlag; WILEY‐VCH Verlag
• Subjects: Degree of polymerization; Differential scanning calorimetry; materials; Passion fruit; Polymerization; Polymers; Renewable resources; Synthesis; thermal analysis; Vegetable oils
• ISSN: 1022-1360; 1521-3900
• DOI: 10.1002/masy.200951211

Although the petrochemical polymers have revolutionized the technological development, the intensive use of these materials have contributed to the global pollution. In this context, researches involving ecofriendliness materials are growing up, as well as, a current interest in developing materials from inexpensive and renewable resources, such as vegetable oils. In this work, is described the synthesis of polymeric materials by thermal polymerization from linseed oil (Linum usitatissimum L.) and passion fruit oil (Passiflora edulis) and their characterization by gas chromatographic (GC), Fourier transform infrared (FTIR) spectroscopy, solubility in organic solvents, thermogravimetry (TG), differential scanning calorimetry (DSC) and Raman spectroscopy. The TG curve shows that those polymeric materials present two stages of decomposition. DSC plots of the vegetable oils showed some endothermic and exothermic transitions which are not present in the DSC curves corresponding to oil-based polymers. The Raman spectra of the polymers indicate declining of absorbance in the region of C==C stretching (~1600 cm⁻¹). This absorption was used to estimate the degree of polymerization (79% and 67.5% for linseed and passion fruit oils, respectively).