Particle-Filled PHPS Silazane-Based Coatings on Steel

Precursor‐based composite coatings were developed as barrier coatings on steel against oxidation and corrosion using a silazane in the system SiN as a polymer material and BN particles as a passive filler. After thermal treatment in air up to 800°C, dense and very well adhered ceramic composite SiNO...

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Bibliographic Details
Published in:International journal of applied ceramic technology Vol. 6; no. 3; pp. 373 - 380
Main Authors: Günthner, Martin, Kraus, Tobias, Krenkel, Walter, Motz, Günter, Dierdorf, Andreas, Decker, Daniel
Format: Journal Article
Language:English
Published: Malden, USA Blackwell Publishing Inc 01-05-2009
Online Access:Get full text
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Summary:Precursor‐based composite coatings were developed as barrier coatings on steel against oxidation and corrosion using a silazane in the system SiN as a polymer material and BN particles as a passive filler. After thermal treatment in air up to 800°C, dense and very well adhered ceramic composite SiNO/BN coatings with a thickness of 12 μm were achieved. These were investigated by means of scanning electron microscopy, energy‐dispersive spectrum, glow discharge optical emission spectroscopy, and adhesion measurements. Static oxidation tests on coated mild steel substrates up to 700°C displayed parabolic oxidation kinetics and a reduced weight gain by two orders in magnitude compared with uncoated substrates.
Bibliography:istex:6E47AB56C2AD61D84D91BC8E2074CE039A70680A
ArticleID:IJAC02346
ark:/67375/WNG-KBKSN0DL-2
*
Member, The American Ceramic Society.
This work was financially supported by the Stiftung Industrieforschung, Cologne, Germany and by the DFG (Deutsche Forschungsgemeinschaft), Bonn, Germany.
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ISSN:1546-542X
1744-7402
DOI:10.1111/j.1744-7402.2008.02346.x