Electrospinning of native and anionic corn starch fibers with different amylose contents
Through starch phosphorylation and solution aging treatments, the aim of this work was to produce electrospun fibers derived from native and anionic (modified with sodium tripolyphosphate) corn starches with amylose contents of <70% (w/w). The fibers of native and anionic corn starches (regular a...
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Published in: | Food research international Vol. 116; pp. 1318 - 1326 |
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01-02-2019
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Abstract | Through starch phosphorylation and solution aging treatments, the aim of this work was to produce electrospun fibers derived from native and anionic (modified with sodium tripolyphosphate) corn starches with amylose contents of <70% (w/w). The fibers of native and anionic corn starches (regular amylose and high amylose Hylon V/Hylon VII) were prepared by electrospinning of starch solutions dissolved in aqueous 75% formic acid (v/v) solvent. The effects of the aging (24, 48, and 72 h) on the rheology and electrical conductivity of the starch solutions, as well as the material properties (size distribution, morphology, and infrared spectrum) of the resulting electrospun fibers, were evaluated. Fibers produced from Hylon VII and Hylon V starches showed homogeneous morphologies, whereas the fibers from regular corn starches exhibited droplets and had heterogeneous morphologies, with diameter varied from 70 to 264 nm. Both native and anionic corn starches, with amylose contents of <70% (w/w), produced smooth continuous fibers. The electrospun corn starch fibers potentially can be used as carriers for the encapsulation of active components in food and packaging applications.
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•Starch fibers with different amylose contents were produced by electrospinning.•The anionic modification of starch increased the viscosity of the polymer solution.•Increased aging time of the polymer solution reduced its viscosity.•Anionic Hylon V produced more homogeneous and less beaded fibers than unmodified starches. |
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AbstractList | Through starch phosphorylation and solution aging treatments, the aim of this work was to produce electrospun fibers derived from native and anionic (modified with sodium tripolyphosphate) corn starches with amylose contents of <70% (w/w). The fibers of native and anionic corn starches (regular amylose and high amylose Hylon V/Hylon VII) were prepared by electrospinning of starch solutions dissolved in aqueous 75% formic acid (v/v) solvent. The effects of the aging (24, 48, and 72 h) on the rheology and electrical conductivity of the starch solutions, as well as the material properties (size distribution, morphology, and infrared spectrum) of the resulting electrospun fibers, were evaluated. Fibers produced from Hylon VII and Hylon V starches showed homogeneous morphologies, whereas the fibers from regular corn starches exhibited droplets and had heterogeneous morphologies, with diameter varied from 70 to 264 nm. Both native and anionic corn starches, with amylose contents of <70% (w/w), produced smooth continuous fibers. The electrospun corn starch fibers potentially can be used as carriers for the encapsulation of active components in food and packaging applications.
[Display omitted]
•Starch fibers with different amylose contents were produced by electrospinning.•The anionic modification of starch increased the viscosity of the polymer solution.•Increased aging time of the polymer solution reduced its viscosity.•Anionic Hylon V produced more homogeneous and less beaded fibers than unmodified starches. Through starch phosphorylation and solution aging treatments, the aim of this work was to produce electrospun fibers derived from native and anionic (modified with sodium tripolyphosphate) corn starches with amylose contents of <70% (w/w). The fibers of native and anionic corn starches (regular amylose and high amylose Hylon V/Hylon VII) were prepared by electrospinning of starch solutions dissolved in aqueous 75% formic acid (v/v) solvent. The effects of the aging (24, 48, and 72 h) on the rheology and electrical conductivity of the starch solutions, as well as the material properties (size distribution, morphology, and infrared spectrum) of the resulting electrospun fibers, were evaluated. Fibers produced from Hylon VII and Hylon V starches showed homogeneous morphologies, whereas the fibers from regular corn starches exhibited droplets and had heterogeneous morphologies, with diameter varied from 70 to 264 nm. Both native and anionic corn starches, with amylose contents of <70% (w/w), produced smooth continuous fibers. The electrospun corn starch fibers potentially can be used as carriers for the encapsulation of active components in food and packaging applications. |
Author | Lim, Loong-Tak de Oliveira, Patricia Diaz da Rosa Zavareze, Elessandra Dias, Alvaro Renato Guerra de Oliveira, Jean Paulo Fonseca, Laura Martins |
Author_xml | – sequence: 1 givenname: Laura Martins surname: Fonseca fullname: Fonseca, Laura Martins organization: Department of Agroindustrial Science and Technology, Federal University of Pelotas, Pelotas 96010-900, Brazil – sequence: 2 givenname: Jean Paulo surname: de Oliveira fullname: de Oliveira, Jean Paulo organization: Department of Agroindustrial Science and Technology, Federal University of Pelotas, Pelotas 96010-900, Brazil – sequence: 3 givenname: Patricia Diaz surname: de Oliveira fullname: de Oliveira, Patricia Diaz organization: Department of Agroindustrial Science and Technology, Federal University of Pelotas, Pelotas 96010-900, Brazil – sequence: 4 givenname: Elessandra surname: da Rosa Zavareze fullname: da Rosa Zavareze, Elessandra organization: Department of Agroindustrial Science and Technology, Federal University of Pelotas, Pelotas 96010-900, Brazil – sequence: 5 givenname: Alvaro Renato Guerra surname: Dias fullname: Dias, Alvaro Renato Guerra organization: Department of Agroindustrial Science and Technology, Federal University of Pelotas, Pelotas 96010-900, Brazil – sequence: 6 givenname: Loong-Tak orcidid: 0000-0002-7579-3338 surname: Lim fullname: Lim, Loong-Tak email: llim@uoguelph.ca organization: Department of Food Science, University of Guelph, 50 Stone Road East, Guelph, ON N1G2W1, Canada |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/30716921$$D View this record in MEDLINE/PubMed |
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Keywords | Phosphorylation Solution aging time Electrospun starch fibers Morphology |
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Snippet | Through starch phosphorylation and solution aging treatments, the aim of this work was to produce electrospun fibers derived from native and anionic (modified... |
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SubjectTerms | Amylopectin - chemistry Amylose - analysis Anions - chemistry Electrospun starch fibers Formates Morphology Nanofibers - chemistry Phosphorylation Rheology Shear Strength Solution aging time Solvents Starch - chemistry Viscosity Zea mays - chemistry |
Title | Electrospinning of native and anionic corn starch fibers with different amylose contents |
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