Electrospinning of native and anionic corn starch fibers with different amylose contents

Through starch phosphorylation and solution aging treatments, the aim of this work was to produce electrospun fibers derived from native and anionic (modified with sodium tripolyphosphate) corn starches with amylose contents of <70% (w/w). The fibers of native and anionic corn starches (regular a...

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Published in:Food research international Vol. 116; pp. 1318 - 1326
Main Authors: Fonseca, Laura Martins, de Oliveira, Jean Paulo, de Oliveira, Patricia Diaz, da Rosa Zavareze, Elessandra, Dias, Alvaro Renato Guerra, Lim, Loong-Tak
Format: Journal Article
Language:English
Published: Canada Elsevier Ltd 01-02-2019
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Abstract Through starch phosphorylation and solution aging treatments, the aim of this work was to produce electrospun fibers derived from native and anionic (modified with sodium tripolyphosphate) corn starches with amylose contents of <70% (w/w). The fibers of native and anionic corn starches (regular amylose and high amylose Hylon V/Hylon VII) were prepared by electrospinning of starch solutions dissolved in aqueous 75% formic acid (v/v) solvent. The effects of the aging (24, 48, and 72 h) on the rheology and electrical conductivity of the starch solutions, as well as the material properties (size distribution, morphology, and infrared spectrum) of the resulting electrospun fibers, were evaluated. Fibers produced from Hylon VII and Hylon V starches showed homogeneous morphologies, whereas the fibers from regular corn starches exhibited droplets and had heterogeneous morphologies, with diameter varied from 70 to 264 nm. Both native and anionic corn starches, with amylose contents of <70% (w/w), produced smooth continuous fibers. The electrospun corn starch fibers potentially can be used as carriers for the encapsulation of active components in food and packaging applications. [Display omitted] •Starch fibers with different amylose contents were produced by electrospinning.•The anionic modification of starch increased the viscosity of the polymer solution.•Increased aging time of the polymer solution reduced its viscosity.•Anionic Hylon V produced more homogeneous and less beaded fibers than unmodified starches.
AbstractList Through starch phosphorylation and solution aging treatments, the aim of this work was to produce electrospun fibers derived from native and anionic (modified with sodium tripolyphosphate) corn starches with amylose contents of <70% (w/w). The fibers of native and anionic corn starches (regular amylose and high amylose Hylon V/Hylon VII) were prepared by electrospinning of starch solutions dissolved in aqueous 75% formic acid (v/v) solvent. The effects of the aging (24, 48, and 72 h) on the rheology and electrical conductivity of the starch solutions, as well as the material properties (size distribution, morphology, and infrared spectrum) of the resulting electrospun fibers, were evaluated. Fibers produced from Hylon VII and Hylon V starches showed homogeneous morphologies, whereas the fibers from regular corn starches exhibited droplets and had heterogeneous morphologies, with diameter varied from 70 to 264 nm. Both native and anionic corn starches, with amylose contents of <70% (w/w), produced smooth continuous fibers. The electrospun corn starch fibers potentially can be used as carriers for the encapsulation of active components in food and packaging applications. [Display omitted] •Starch fibers with different amylose contents were produced by electrospinning.•The anionic modification of starch increased the viscosity of the polymer solution.•Increased aging time of the polymer solution reduced its viscosity.•Anionic Hylon V produced more homogeneous and less beaded fibers than unmodified starches.
Through starch phosphorylation and solution aging treatments, the aim of this work was to produce electrospun fibers derived from native and anionic (modified with sodium tripolyphosphate) corn starches with amylose contents of <70% (w/w). The fibers of native and anionic corn starches (regular amylose and high amylose Hylon V/Hylon VII) were prepared by electrospinning of starch solutions dissolved in aqueous 75% formic acid (v/v) solvent. The effects of the aging (24, 48, and 72 h) on the rheology and electrical conductivity of the starch solutions, as well as the material properties (size distribution, morphology, and infrared spectrum) of the resulting electrospun fibers, were evaluated. Fibers produced from Hylon VII and Hylon V starches showed homogeneous morphologies, whereas the fibers from regular corn starches exhibited droplets and had heterogeneous morphologies, with diameter varied from 70 to 264 nm. Both native and anionic corn starches, with amylose contents of <70% (w/w), produced smooth continuous fibers. The electrospun corn starch fibers potentially can be used as carriers for the encapsulation of active components in food and packaging applications.
Author Lim, Loong-Tak
de Oliveira, Patricia Diaz
da Rosa Zavareze, Elessandra
Dias, Alvaro Renato Guerra
de Oliveira, Jean Paulo
Fonseca, Laura Martins
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  givenname: Laura Martins
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  givenname: Jean Paulo
  surname: de Oliveira
  fullname: de Oliveira, Jean Paulo
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  givenname: Patricia Diaz
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  givenname: Elessandra
  surname: da Rosa Zavareze
  fullname: da Rosa Zavareze, Elessandra
  organization: Department of Agroindustrial Science and Technology, Federal University of Pelotas, Pelotas 96010-900, Brazil
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  givenname: Alvaro Renato Guerra
  surname: Dias
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  surname: Lim
  fullname: Lim, Loong-Tak
  email: llim@uoguelph.ca
  organization: Department of Food Science, University of Guelph, 50 Stone Road East, Guelph, ON N1G2W1, Canada
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Keywords Phosphorylation
Solution aging time
Electrospun starch fibers
Morphology
Language English
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Snippet Through starch phosphorylation and solution aging treatments, the aim of this work was to produce electrospun fibers derived from native and anionic (modified...
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SubjectTerms Amylopectin - chemistry
Amylose - analysis
Anions - chemistry
Electrospun starch fibers
Formates
Morphology
Nanofibers - chemistry
Phosphorylation
Rheology
Shear Strength
Solution aging time
Solvents
Starch - chemistry
Viscosity
Zea mays - chemistry
Title Electrospinning of native and anionic corn starch fibers with different amylose contents
URI https://dx.doi.org/10.1016/j.foodres.2018.10.021
https://www.ncbi.nlm.nih.gov/pubmed/30716921
https://search.proquest.com/docview/2179543299
Volume 116
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