Tuning of catalytic properties for electrooxidation of small organic molecules on Pt-based thin films via controlled thermal treatment

• Published in: Journal of catalysis Vol. 371; no. C; pp. 96 - 105
• Main Authors: Tripković, D.V., Popović, K.Dj, Jovanović, V.M., Nogueira, J.A., Varela, H., Lopes, P.P., Strmcnik, D., Stamenkovic, V.R., Markovic, N.M.
• Format: Journal Article
• Language: English
• Published: United States Elsevier Inc 01-03-2019; Elsevier
• Subjects: Electro-oxidation; Formic acid; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Methanol; Pt thin films; Thermal treatment; Pt thin films; Formic acid; Electro-oxidation; Thermal treatment; Methanol
• ISSN: 0021-9517; 1090-2694
• DOI: 10.1016/j.jcat.2019.01.038

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•Thin film catalyst produced by electrochemical deposition of Pt on amorphous substrate.•The huge activation of the Pt-based thin-film catalyst induced by the controlled thermal treatment.•Bi and Ge selective adsorption for revealing the nature of the altered surface structure.•Improved activity without affecting the stability for formic acid and methanol oxidation.
Ability to utilize structure-function relationship in the design of electrocatalysts relies on fundamental understanding of physicochemical processes at the topmost surface. It has been demonstrated that reaction rate for majority of electrochemical reactions exhibit notable dependence on geometric arrangement of surface atoms due to varying levels of binding strength between different atomic structures and adsorbate molecules. Control of surface structure at nanoscale is being investigated here through a thin film approach. The surface characteristics of electrochemically deposited Pt thin films were probed for electrooxidation of small organic molecules such as formic acid and methanol. The low-index Pt single crystal electrodes were used for reactivity benchmarking which later guided thermal annealing processes, and ultimately, fine tuning of the ratio between (1 1 1) and (1 0 0) surface facets on Pt thin films. The tailored thin film structure is responsible for significant activation of both formic acid and methanol oxidation reactions, which justifies the approach.