Thermal emissivity of silicon heterojunction solar cells

• Published in: Solar energy materials and solar cells Vol. 201; no. C; p. 110051
• Main Authors: Alonso-Álvarez, D., Augusto, A., Pearce, P., Llin, L. Ferre, Mellor, A., Bowden, S., Paul, D.J., Ekins-Daukes, N.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01-10-2019; Elsevier BV; Elsevier
• Subjects: Aluminum; Amorphous silicon; Ellipsometry; Emissivity; Heterojunction; Heterojunctions; Indium tin oxides; Modelling; Optimization; Photovoltaic cells; Photovoltaics; Silicon; Silicon wafers; Solar cells; Tin; Transfer matrices; Solar cells; Emissivity; Silicon; Modelling; Heterojunction
• ISSN: 0927-0248; 1879-3398
• DOI: 10.1016/j.solmat.2019.110051

The aim of this work is to evaluate whether silicon heterojunction solar cells, lacking highly emissive, heavily doped silicon layers, could be better candidates for hybrid photovoltaic thermal collectors than standard aluminium-diffused back contact solar cells. To this end, the near and mid infrared emissivity of full silicon heterojunction solar cells, as well as of its constituent materials – crystalline silicon wafer, indium tin oxide, n-, i- and p-type amorphous silicon – have been assessed by means of ellipsometry and FTIR. The experimental results show that the thermal emissivity of these cells is actually as high as in the more traditional structures, ~80% at 8 μm. Detailed optical modelling combining raytracing and transfer matrix formalism shows that the emissivity in these cells originates in the transparent conductive oxide layers themselves, where the doping is not high enough to result in a reflection that exceeds the increased free carrier absorption. Further modelling suggests that it is possible to obtain lower emissivity solar cells, but that a careful optimization of the transparent conductive layer needs to be done to avoid hindering the photovoltaic performance.
•Hybrid photovoltaic-solar thermal systems require low thermal emissivity.•High doping combined with textures are responsible for high emissivity.•Silicon heterojunction solar cells have no highly doped silicon layers.•Experiment and modelling prove that emissivity of silicon layers is very low.•Transparent conductive oxide layers still result in overall high thermal emissivity.