Neutron Larmor diffraction on powder samples

A hitherto unrecognized resolution effect in neutron Larmor diffraction (LD) is reported, resulting from small‐angle neutron scattering (SANS) in the sample. Small distortions of the neutron trajectories by SANS give rise to a blurring of the Bragg angles of the order of a few hundredths of a degree...

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Published in:Journal of applied crystallography Vol. 53; no. 1; pp. 88 - 98
Main Authors: Keller, Thomas, Fabrykiewicz, Piotr, Przeniosło, Radosław, Sosnowska, Izabela, Keimer, Bernhard
Format: Journal Article
Language:English
Published: 5 Abbey Square, Chester, Cheshire CH1 2HU, England International Union of Crystallography 01-02-2020
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Abstract A hitherto unrecognized resolution effect in neutron Larmor diffraction (LD) is reported, resulting from small‐angle neutron scattering (SANS) in the sample. Small distortions of the neutron trajectories by SANS give rise to a blurring of the Bragg angles of the order of a few hundredths of a degree, leading to a degradation of the momentum resolution. This effect is negligible for single crystals but may be significant for polycrystalline or powder samples. A procedure is presented to correct the LD data for the parasitic SANS. The latter is accurately determined by the SESANS technique (spin–echo small‐angle neutron scattering), which is readily available on Larmor diffractometers. The analysis technique is demonstrated on LD and SESANS data from α‐Fe2O3 powder samples. The resulting d‐spacing range agrees with experimental data from high‐resolution synchrotron radiation powder diffraction on the same sample. A method to analyse neutron Larmor diffraction data from polycrystalline samples is presented.
AbstractList A method to analyse neutron Larmor diffraction data from polycrystalline samples is presented. A hitherto unrecognized resolution effect in neutron Larmor diffraction (LD) is reported, resulting from small-angle neutron scattering (SANS) in the sample. Small distortions of the neutron trajectories by SANS give rise to a blurring of the Bragg angles of the order of a few hundredths of a degree, leading to a degradation of the momentum resolution. This effect is negligible for single crystals but may be significant for polycrystalline or powder samples. A procedure is presented to correct the LD data for the parasitic SANS. The latter is accurately determined by the SESANS technique (spin–echo small-angle neutron scattering), which is readily available on Larmor diffractometers. The analysis technique is demonstrated on LD and SESANS data from α-Fe 2 O 3 powder samples. The resulting d -spacing range agrees with experimental data from high-resolution synchrotron radiation powder diffraction on the same sample.
A hitherto unrecognized resolution effect in neutron Larmor diffraction (LD) is reported, resulting from small‐angle neutron scattering (SANS) in the sample. Small distortions of the neutron trajectories by SANS give rise to a blurring of the Bragg angles of the order of a few hundredths of a degree, leading to a degradation of the momentum resolution. This effect is negligible for single crystals but may be significant for polycrystalline or powder samples. A procedure is presented to correct the LD data for the parasitic SANS. The latter is accurately determined by the SESANS technique (spin–echo small‐angle neutron scattering), which is readily available on Larmor diffractometers. The analysis technique is demonstrated on LD and SESANS data from α‐Fe2O3 powder samples. The resulting d‐spacing range agrees with experimental data from high‐resolution synchrotron radiation powder diffraction on the same sample.
A hitherto unrecognized resolution effect in neutron Larmor diffraction (LD) is reported, resulting from small-angle neutron scattering (SANS) in the sample. Small distortions of the neutron trajectories by SANS give rise to a blurring of the Bragg angles of the order of a few hundredths of a degree, leading to a degradation of the momentum resolution. This effect is negligible for single crystals but may be significant for polycrystalline or powder samples. A procedure is presented to correct the LD data for the parasitic SANS. The latter is accurately determined by the SESANS technique (spin–echo small-angle neutron scattering), which is readily available on Larmor diffractometers. The analysis technique is demonstrated on LD and SESANS data from α-Fe 2 O 3 powder samples. The resulting d -spacing range agrees with experimental data from high-resolution synchrotron radiation powder diffraction on the same sample.
A hitherto unrecognized resolution effect in neutron Larmor diffraction (LD) is reported, resulting from small-angle neutron scattering (SANS) in the sample. Small distortions of the neutron trajectories by SANS give rise to a blurring of the Bragg angles of the order of a few hundredths of a degree, leading to a degradation of the momentum resolution. This effect is negligible for single crystals but may be significant for polycrystalline or powder samples. A procedure is presented to correct the LD data for the parasitic SANS. The latter is accurately determined by the SESANS technique (spin-echo small-angle neutron scattering), which is readily available on Larmor diffractometers. The analysis technique is demonstrated on LD and SESANS data from α-Fe O powder samples. The resulting -spacing range agrees with experimental data from high-resolution synchrotron radiation powder diffraction on the same sample.
A hitherto unrecognized resolution effect in neutron Larmor diffraction (LD) is reported, resulting from small‐angle neutron scattering (SANS) in the sample. Small distortions of the neutron trajectories by SANS give rise to a blurring of the Bragg angles of the order of a few hundredths of a degree, leading to a degradation of the momentum resolution. This effect is negligible for single crystals but may be significant for polycrystalline or powder samples. A procedure is presented to correct the LD data for the parasitic SANS. The latter is accurately determined by the SESANS technique (spin–echo small‐angle neutron scattering), which is readily available on Larmor diffractometers. The analysis technique is demonstrated on LD and SESANS data from α‐Fe2O3 powder samples. The resulting d‐spacing range agrees with experimental data from high‐resolution synchrotron radiation powder diffraction on the same sample. A method to analyse neutron Larmor diffraction data from polycrystalline samples is presented.
Author Przeniosło, Radosław
Sosnowska, Izabela
Keimer, Bernhard
Keller, Thomas
Fabrykiewicz, Piotr
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BackLink https://www.ncbi.nlm.nih.gov/pubmed/32047407$$D View this record in MEDLINE/PubMed
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Issue 1
Keywords polycrystalline samples
neutron Larmor diffraction
neutron spin–echo
powder diffraction
Language English
License Attribution
Thomas Keller et al. 2020.
This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
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Snippet A hitherto unrecognized resolution effect in neutron Larmor diffraction (LD) is reported, resulting from small‐angle neutron scattering (SANS) in the sample....
A hitherto unrecognized resolution effect in neutron Larmor diffraction (LD) is reported, resulting from small-angle neutron scattering (SANS) in the sample....
A method to analyse neutron Larmor diffraction data from polycrystalline samples is presented. A hitherto unrecognized resolution effect in neutron Larmor...
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StartPage 88
SubjectTerms Blurring
Crystals
Diffraction
Diffractometers
neutron Larmor diffraction
Neutron scattering
neutron spin–echo
Neutrons
polycrystalline samples
Powder
powder diffraction
Radiation
Research Papers
Single crystals
Synchrotron radiation
Title Neutron Larmor diffraction on powder samples
URI https://onlinelibrary.wiley.com/doi/abs/10.1107%2FS160057671901611X
https://www.ncbi.nlm.nih.gov/pubmed/32047407
https://www.proquest.com/docview/2350293981
https://search.proquest.com/docview/2354160532
https://pubmed.ncbi.nlm.nih.gov/PMC6998774
Volume 53
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