Neutron Larmor diffraction on powder samples
A hitherto unrecognized resolution effect in neutron Larmor diffraction (LD) is reported, resulting from small‐angle neutron scattering (SANS) in the sample. Small distortions of the neutron trajectories by SANS give rise to a blurring of the Bragg angles of the order of a few hundredths of a degree...
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Published in: | Journal of applied crystallography Vol. 53; no. 1; pp. 88 - 98 |
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01-02-2020
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Abstract | A hitherto unrecognized resolution effect in neutron Larmor diffraction (LD) is reported, resulting from small‐angle neutron scattering (SANS) in the sample. Small distortions of the neutron trajectories by SANS give rise to a blurring of the Bragg angles of the order of a few hundredths of a degree, leading to a degradation of the momentum resolution. This effect is negligible for single crystals but may be significant for polycrystalline or powder samples. A procedure is presented to correct the LD data for the parasitic SANS. The latter is accurately determined by the SESANS technique (spin–echo small‐angle neutron scattering), which is readily available on Larmor diffractometers. The analysis technique is demonstrated on LD and SESANS data from α‐Fe2O3 powder samples. The resulting d‐spacing range agrees with experimental data from high‐resolution synchrotron radiation powder diffraction on the same sample.
A method to analyse neutron Larmor diffraction data from polycrystalline samples is presented. |
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AbstractList | A method to analyse neutron Larmor diffraction data from polycrystalline samples is presented.
A hitherto unrecognized resolution effect in neutron Larmor diffraction (LD) is reported, resulting from small-angle neutron scattering (SANS) in the sample. Small distortions of the neutron trajectories by SANS give rise to a blurring of the Bragg angles of the order of a few hundredths of a degree, leading to a degradation of the momentum resolution. This effect is negligible for single crystals but may be significant for polycrystalline or powder samples. A procedure is presented to correct the LD data for the parasitic SANS. The latter is accurately determined by the SESANS technique (spin–echo small-angle neutron scattering), which is readily available on Larmor diffractometers. The analysis technique is demonstrated on LD and SESANS data from α-Fe
2
O
3
powder samples. The resulting
d
-spacing range agrees with experimental data from high-resolution synchrotron radiation powder diffraction on the same sample. A hitherto unrecognized resolution effect in neutron Larmor diffraction (LD) is reported, resulting from small‐angle neutron scattering (SANS) in the sample. Small distortions of the neutron trajectories by SANS give rise to a blurring of the Bragg angles of the order of a few hundredths of a degree, leading to a degradation of the momentum resolution. This effect is negligible for single crystals but may be significant for polycrystalline or powder samples. A procedure is presented to correct the LD data for the parasitic SANS. The latter is accurately determined by the SESANS technique (spin–echo small‐angle neutron scattering), which is readily available on Larmor diffractometers. The analysis technique is demonstrated on LD and SESANS data from α‐Fe2O3 powder samples. The resulting d‐spacing range agrees with experimental data from high‐resolution synchrotron radiation powder diffraction on the same sample. A hitherto unrecognized resolution effect in neutron Larmor diffraction (LD) is reported, resulting from small-angle neutron scattering (SANS) in the sample. Small distortions of the neutron trajectories by SANS give rise to a blurring of the Bragg angles of the order of a few hundredths of a degree, leading to a degradation of the momentum resolution. This effect is negligible for single crystals but may be significant for polycrystalline or powder samples. A procedure is presented to correct the LD data for the parasitic SANS. The latter is accurately determined by the SESANS technique (spin–echo small-angle neutron scattering), which is readily available on Larmor diffractometers. The analysis technique is demonstrated on LD and SESANS data from α-Fe 2 O 3 powder samples. The resulting d -spacing range agrees with experimental data from high-resolution synchrotron radiation powder diffraction on the same sample. A hitherto unrecognized resolution effect in neutron Larmor diffraction (LD) is reported, resulting from small-angle neutron scattering (SANS) in the sample. Small distortions of the neutron trajectories by SANS give rise to a blurring of the Bragg angles of the order of a few hundredths of a degree, leading to a degradation of the momentum resolution. This effect is negligible for single crystals but may be significant for polycrystalline or powder samples. A procedure is presented to correct the LD data for the parasitic SANS. The latter is accurately determined by the SESANS technique (spin-echo small-angle neutron scattering), which is readily available on Larmor diffractometers. The analysis technique is demonstrated on LD and SESANS data from α-Fe O powder samples. The resulting -spacing range agrees with experimental data from high-resolution synchrotron radiation powder diffraction on the same sample. A hitherto unrecognized resolution effect in neutron Larmor diffraction (LD) is reported, resulting from small‐angle neutron scattering (SANS) in the sample. Small distortions of the neutron trajectories by SANS give rise to a blurring of the Bragg angles of the order of a few hundredths of a degree, leading to a degradation of the momentum resolution. This effect is negligible for single crystals but may be significant for polycrystalline or powder samples. A procedure is presented to correct the LD data for the parasitic SANS. The latter is accurately determined by the SESANS technique (spin–echo small‐angle neutron scattering), which is readily available on Larmor diffractometers. The analysis technique is demonstrated on LD and SESANS data from α‐Fe2O3 powder samples. The resulting d‐spacing range agrees with experimental data from high‐resolution synchrotron radiation powder diffraction on the same sample. A method to analyse neutron Larmor diffraction data from polycrystalline samples is presented. |
Author | Przeniosło, Radosław Sosnowska, Izabela Keimer, Bernhard Keller, Thomas Fabrykiewicz, Piotr |
Author_xml | – sequence: 1 givenname: Thomas surname: Keller fullname: Keller, Thomas email: t.keller@fkf.mpg.de organization: Max Planck Society Outstation at the Forschungsneutronenquelle Heinz Maier-Leibnitz (FRM-II), Garching, Germany – sequence: 2 givenname: Piotr surname: Fabrykiewicz fullname: Fabrykiewicz, Piotr organization: Faculty of Physics, University of Warsaw, Poland – sequence: 3 givenname: Radosław surname: Przeniosło fullname: Przeniosło, Radosław organization: Faculty of Physics, University of Warsaw, Poland – sequence: 4 givenname: Izabela surname: Sosnowska fullname: Sosnowska, Izabela organization: Faculty of Physics, University of Warsaw, Poland – sequence: 5 givenname: Bernhard surname: Keimer fullname: Keimer, Bernhard organization: Max Planck Institute for Solid State Research, Stuttgart, Germany |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/32047407$$D View this record in MEDLINE/PubMed |
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Cites_doi | 10.1016/j.physb.2016.01.035 10.1107/S0021889803015681 10.1016/j.actamat.2010.02.020 10.1016/j.physb.2017.10.086 10.1209/epl/i2001-00248-2 10.1103/PhysRevB.87.224425 10.1143/JPSJ.81.044604 10.6028/jres.109.010 10.1103/PhysRevB.94.174406 10.1080/10448639508217694 10.1107/S1600576715010729 10.1016/0168-583X(96)00213-3 10.1107/S0021889808026770 10.1103/PhysRevB.84.184430 10.1103/PhysRevLett.114.157002 10.1016/0375-9601(87)90760-2 10.1107/S1600576718005307 10.1007/s003390201612 10.1016/j.physb.2016.05.002 10.1051/jphys:019880049070119500 10.1107/S2052520616017935 10.1088/1742-6596/340/1/012012 10.17815/jlsrf-1-41 10.1038/s41467-018-05529-2 10.1107/S205252061500342X 10.1103/PhysRevLett.116.047001 10.1107/S2052520618014968 10.1016/S0921-4526(99)01325-3 10.1103/PhysRevLett.104.106406 10.1016/j.physb.2014.04.074 10.1063/1.4908167 10.1038/s41598-017-00740-5 10.1126/science.1142644 |
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Keywords | polycrystalline samples neutron Larmor diffraction neutron spin–echo powder diffraction |
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Snippet | A hitherto unrecognized resolution effect in neutron Larmor diffraction (LD) is reported, resulting from small‐angle neutron scattering (SANS) in the sample.... A hitherto unrecognized resolution effect in neutron Larmor diffraction (LD) is reported, resulting from small-angle neutron scattering (SANS) in the sample.... A method to analyse neutron Larmor diffraction data from polycrystalline samples is presented. A hitherto unrecognized resolution effect in neutron Larmor... |
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SubjectTerms | Blurring Crystals Diffraction Diffractometers neutron Larmor diffraction Neutron scattering neutron spin–echo Neutrons polycrystalline samples Powder powder diffraction Radiation Research Papers Single crystals Synchrotron radiation |
Title | Neutron Larmor diffraction on powder samples |
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