Cross-Linked Carboxymethylcellulose Adsorbtion Membranes from Ziziphus lotus for the Removal of Organic Dye Pollutants

• Published in: Materials Vol. 15; no. 24; p. 8760
• Main Authors: Saad, Sara, Dávila, Izaskun, Morales, Amaia, Labidi, Jalel, Moussaoui, Younes
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 08-12-2022; MDPI
• Subjects: Acids; Activated carbon; Adsorbents; Adsorption; Biomass; Cellulose; Citric acid; Crosslinking; Dyes; Earth; Lignin; Membranes; Pollutants; Raw materials; Wastewater; eco-friendly adsorption membrane; Ziziphus lotus; valorization; carboxymethylcellulose; methyl green
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma15248760

The goal of this study is to assess
's potential for producing carboxymethylcellulose adsorption membranes with the ability to adsorb methyl green from wastewaters by the revalorization of its cellulosic fraction. The cellulose from this feedstock was extracted by an alkaline process and TAPPI standard technique T 203 cm-99 and afterwards they were carboxymethylated. The obtained carboxymethylcelluloses were deeply characterized, being observed that the carboxymethylcellulose produced from the alkaline cellulose presented the higher solubility due to its lower crystallinity degree (53.31 vs. 59.4%) and its higher substitution degree (0.85 vs. 0.74). This carboxymethylcellulose was cross-linked with citric acid in an aqueous treatment in order to form an adsorption membrane. The citric acid provided rigidity to the membrane and although it was hydrophilic it was not soluble in water. By evaluating the potential of the produced membrane for the removal of pollutant dyes from wastewater, it was observed that the adsorption membrane prepared from the carboxymethylcellulose's produced from the
was able to remove 99% of the dye, methyl green, present in the wastewater. Thus, this work demonstrates the potential of the
for the production of a novel and cost-effective carboxymethylcellulose adsorption membrane with high capacity to treat wastewaters.