Aerobic photooxidative cleavage of 1,3-diketones to carboxylic acids using 2-chloroanthraquinone

We developed direct aerobic photooxidation of 1,3-diketones to corresponding carboxylic acids in the presence of a catalytic amount of 2-chloroanthraquinone under visible light irradiation from fluorescent lamps.

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Bibliographic Details
Published in:Tetrahedron letters Vol. 54; no. 46; pp. 6218 - 6221
Main Authors: Tachikawa, Yuma, Cui, Lei, Matsusaki, Yoko, Tada, Norihiro, Miura, Tsuyoshi, Itoh, Akichika
Format: Journal Article
Language:English
Published: Elsevier Ltd 13-11-2013
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Summary:We developed direct aerobic photooxidation of 1,3-diketones to corresponding carboxylic acids in the presence of a catalytic amount of 2-chloroanthraquinone under visible light irradiation from fluorescent lamps.
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ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2013.09.015