High-frequency and intrinsically stretchable polymer diodes

• Published in: Nature (London) Vol. 600; no. 7888; pp. 246 - 252
• Main Authors: Matsuhisa, Naoji, Niu, Simiao, O’Neill, Stephen J. K., Kang, Jiheong, Ochiai, Yuto, Katsumata, Toru, Wu, Hung-Chin, Ashizawa, Minoru, Wang, Ging-Ji Nathan, Zhong, Donglai, Wang, Xuelin, Gong, Xiwen, Ning, Rui, Gong, Huaxin, You, Insang, Zheng, Yu, Zhang, Zhitao, Tok, Jeffrey B.-H., Chen, Xiaodong, Bao, Zhenan
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 09-12-2021; Nature Publishing Group
• Subjects: 140/131; 140/146; 639/166/987; 639/301/923/3931; Carrier frequencies; Circuits; Conductors; Cracks; Diodes; Electrochromism; Electrodes; Electronic circuits; Electronic devices; Electronic equipment; Electronics - instrumentation; Humanities and Social Sciences; Humans; multidisciplinary; Nanomaterials; Nanotechnology; Nanowires - chemistry; Optoelectronic devices; Pixels; Polymers; Polymers - chemistry; Radio frequency; Science; Science & Technology - Other Topics; Science (multidisciplinary); Semiconductors; Sensors; Silver - chemistry; Skin; Wearable Electronic Devices; Wireless Technology - instrumentation
• ISSN: 0028-0836; 1476-4687
• DOI: 10.1038/s41586-021-04053-6

Skin-like intrinsically stretchable soft electronic devices are essential to realize next-generation remote and preventative medicine for advanced personal healthcare
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. The recent development of intrinsically stretchable conductors and semiconductors has enabled highly mechanically robust and skin-conformable electronic circuits or optoelectronic devices
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. However, their operating frequencies have been limited to less than 100 hertz, which is much lower than that required for many applications. Here we report intrinsically stretchable diodes—based on stretchable organic and nanomaterials—capable of operating at a frequency as high as 13.56 megahertz. This operating frequency is high enough for the wireless operation of soft sensors and electrochromic display pixels using radiofrequency identification in which the base-carrier frequency is 6.78 megahertz or 13.56 megahertz. This was achieved through a combination of rational material design and device engineering. Specifically, we developed a stretchable anode, cathode, semiconductor and current collector that can satisfy the strict requirements for high-frequency operation. Finally, we show the operational feasibility of our diode by integrating it with a stretchable sensor, electrochromic display pixel and antenna to realize a stretchable wireless tag. This work is an important step towards enabling enhanced functionalities and capabilities for skin-like wearable electronics.
A stretchable anode, cathode, semiconductor and current collector have been developed to create stretchable diodes that can operate at megahertz frequencies for use in wirelessly operated, skin-like wearable electronics.