Germanium at high pressures
X-ray diffraction experiments have been carried out on Ge in a diamond anvil cell to 26 GPa. The pressure at the transition to the metallic phase (II) has been studied in different pressurizing media, giving 10.6 plus/minus 0.05 GPa in a quasihydrostatic medium (4:1 methanol:ethanol mixture), 9.8 pl...
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| Published in: | Physical review. B, Condensed matter Vol. 34; no. 1; pp. 362 - 368 |
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| Main Authors: | , , |
| Format: | Journal Article |
| Language: | English |
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Woodbury, NY
American Physical Society
01-07-1986
American Institute of Physics |
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| Abstract | X-ray diffraction experiments have been carried out on Ge in a diamond anvil cell to 26 GPa. The pressure at the transition to the metallic phase (II) has been studied in different pressurizing media, giving 10.6 plus/minus 0.05 GPa in a quasihydrostatic medium (4:1 methanol:ethanol mixture), 9.8 plus/minus 0.1 GPa in NaCl, and 8.1 plus/minus 0.3 GPa when the sample was compressed directly between the anvils. The compression curve for phase II has been fitted to a modified Murnaghan equation. Upon release of pressure the transformation from phase II to III (tetragonal) was found at 7.6 plus/minus 0.05 GPa. It was found that the details of the transition depended on the stress condition and rate of decompression. 50 ref.--AA |
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| AbstractList | X-ray diffraction experiments have been carried out on Ge in a diamond anvil cell to 26 GPa. The pressure at the transition to the metallic phase (II) has been studied in different pressurizing media, giving 10.6 plus/minus 0.05 GPa in a quasihydrostatic medium (4:1 methanol:ethanol mixture), 9.8 plus/minus 0.1 GPa in NaCl, and 8.1 plus/minus 0.3 GPa when the sample was compressed directly between the anvils. The compression curve for phase II has been fitted to a modified Murnaghan equation. Upon release of pressure the transformation from phase II to III (tetragonal) was found at 7.6 plus/minus 0.05 GPa. It was found that the details of the transition depended on the stress condition and rate of decompression. 50 ref.--AA |
| Author | SPAIN, I. L MENONI, C. S JING ZHU HU |
| Author_xml | – sequence: 1 givenname: C. S surname: MENONI fullname: MENONI, C. S organization: Colorado state univ., dep. physics, Fort Collins CO 80523, United States – sequence: 2 surname: JING ZHU HU fullname: JING ZHU HU organization: Colorado state univ., dep. physics, Fort Collins CO 80523, United States – sequence: 3 givenname: I. L surname: SPAIN fullname: SPAIN, I. L organization: Colorado state univ., dep. physics, Fort Collins CO 80523, United States |
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| Copyright | 1987 INIST-CNRS |
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| Keywords | Non metal Phase transformation Germanium Electronic transition Experimental study X ray diffraction High pressure Semiconductor metal transition |
| Language | English |
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| PublicationTitle | Physical review. B, Condensed matter |
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| References | J. Wittig (PhysRevB.34.362Cc4R1) 1965; 17 C. S. Menoni (PhysRevB.34.362Cc41R1) 1984; 16 D. L. Decker (PhysRevB.34.362Cc27R1) 1973; 1 G. L. Kinsland (PhysRevB.34.362Cc49R1) 1977; 48 J. S. Kasper (PhysRevB.34.362Cc12R1) 1964; 77 M. T. Yin (PhysRevB.34.362Cc20R1) 1982; 26 R. Alben (PhysRevB.34.362Cc50R1) 1974; 9 F. P. Bundy (PhysRevB.34.362Cc2R1) 1963; 139 R. Grover (PhysRevB.34.362Cc29R1) 1982 G. Piermarini (PhysRevB.34.362Cc34R1) 1973; 44 S. B. Qadri (PhysRevB.34.362Cc10R1) 1983; 54 J. Z. Hu (PhysRevB.34.362Cc22R1) 1984; 51 Y. Fujii (PhysRevB.34.362Cc38R1) 1980; 13 P. W. Bridgman (PhysRevB.34.362Cc45R1) 1949; 77 M. J. Baublitz (PhysRevB.34.362Cc9R1) 1982; 53 M. N. Pavlovskii (PhysRevB.34.362Cc17R1) 1968; 9 K. Takemura (PhysRevB.34.362Cc37R1) 1979; 11 J. A. Van Vechten (PhysRevB.34.362Cc42R1) 1973; 7 B. Welber (PhysRevB.34.362Cc14R1) 1977; 15 D. Decker (PhysRevB.34.362Cc35R1) 1971; 42 G. J. Piermarini (PhysRevB.34.362Cc36R1) 1975; 46 K. Asaumi (PhysRevB.34.362Cc15R1) 1978; 45 B. Okai (PhysRevB.34.362Cc6R1) 1978; 45 S. Minomura (PhysRevB.34.362Cc1R1) 1962; 23 J. Wittig (PhysRevB.34.362Cc5R1) 1966; 195 R. J. Needs (PhysRevB.34.362Cc23R1) 1984; 30 R. A. Graham (PhysRevB.34.362Cc16R1) 1966; 27 A. K. McMahan (PhysRevB.34.362Cc21R1) 1983; 27 A. Werner (PhysRevB.34.362Cc8R1) 1982; 44 J. Barnett (PhysRevB.34.362Cc26R1) 1973; 44 M. M. Dacorogna (PhysRevB.34.362Cc28R1) 1985; 32 I. L. Spain (PhysRevB.34.362Cc30R1) 1981 H. J. McSkimmin (PhysRevB.34.362Cc43R1) 1963; 34 G. L. Kinsland (PhysRevB.34.362Cc49R2) 1977; 48 C. Bates (PhysRevB.34.362Cc13R1) 1965; 147 M. Baublitz (PhysRevB.34.362Cc40R1) 1981; 52 K. J. Chang (PhysRevB.34.362Cc24R1) 1985; 31 R. Forman (PhysRevB.34.362Cc25R1) 1972; 176 G. L. Kinsland (PhysRevB.34.362Cc48R1) 1978; 10 W. H. Gust (PhysRevB.34.362Cc18R1) 1972; 43 J. Jamieson (PhysRevB.34.362Cc7R1) 1963; 139 I. L. Spain (PhysRevB.34.362Cc39R1) 1984; 16 F. P. Bundy (PhysRevB.34.362Cc3R1) 1964; 41 H. Olijnyk (PhysRevB.34.362Cc11R1) 1984; 103A A. K. Singh (PhysRevB.34.362Cc47R1) 1974; 45 M. T. Yin (PhysRevB.34.362Cc19R1) 1980; 45 |
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| Snippet | X-ray diffraction experiments have been carried out on Ge in a diamond anvil cell to 26 GPa. The pressure at the transition to the metallic phase (II) has been... |
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| SubjectTerms | Condensed matter: electronic structure, electrical, magnetic, and optical properties Electron states Exact sciences and technology Excitons and related phenomena Physics |
| Title | Germanium at high pressures |
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