CuxCo3-xO4 ultra-thin film as efficient anodic catalysts for anion exchange membrane water electrolysers

• Published in: Journal of power sources Vol. 415; pp. 136 - 144
• Main Authors: López-Fernández, E., Gil-Rostra, J., Espinós, J.P., González-Elipe, A.R., Yubero, F., de Lucas-Consuegra, A.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01-03-2019
• Subjects: aem water electrolysis; CuO[sbnd]Co3O4; Hydrogen production; Magnetron sputtering; OER; Magnetron sputtering; CuOCo3O4; aem water electrolysis; OER; Hydrogen production
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2019.01.056

CuxCo3-xO4 ultra-thin films, deposited by magnetron sputtering at oblique angles have been used as anodic catalysts in anion exchange membrane water electrolysers. It has been demonstrated that the used deposition procedure provides porous and amorphous samples with a strict control of the total catalyst load and Co/Cu ratio. Electrocatalytic tests showed a maximum performance for the oxygen evolution reaction at Co/Cu atomic ratio around 1.8. The optimized anodic catalyst presented a long-term stability confirmed by accelerated lifetime tests together with the chemical surface analysis of the used samples. The effect of the crystallization of a single layer CuxCo3-xO4 and a multilayer (CuO/Co3O4)n anodic catalyst samples was also investigated. The observed loss of catalytic performance found in both cases may prove that a particular local chemical environment around the Co and Cu sites acts as an efficient catalytic site for the oxygen evolution reaction. A catalyst film with the optimum Co/Cu atomic ratio was incorporated into a Membrane Electrode Assembly, using a sputtered Ni film as cathode. Current density values up to 100 mA cm−2 at 2.0 V were obtained in 1.0 M KOH electrolyte. Upon normalization by the amount of catalyst, this performance is one of the highest reported in literature.
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•CuxCo3-xO4 ultra-thin film electrodes have been prepared by magnetron sputtering.•An optimal Co/Cu atomic ratio of 1.8 was found for oxygen evolution reaction (OER).•A MEA based on ultra-thin films rendered the maximum performance for OER.•A high electrocatalytic H2 production rate (Faradaic-type evolution) was confirmed.