Polyethersulfone (PES)–silver composite UF membrane: Effect of silver loading and PVP molecular weight on membrane morphology and antibacterial activity

• Published in: Desalination Vol. 273; no. 1; pp. 72 - 80
• Main Authors: Basri, H., Ismail, A.F., Aziz, M.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01-06-2011; Elsevier
• Subjects: Antibacterial; Applied sciences; Chemical engineering; Composites; Exact sciences and technology; Membrane separation (reverse osmosis, dialysis...); Pollution; Polyethersulfone–silver; Polyvinylpyrrolidone; Composites; Polyethersulfone–silver; Polyvinylpyrrolidone; Antibacterial; Plasma; Water filtration; Stability; Escherichia coli; Dispersant; Disinfection; Phase reversal; Composite material; Membrane separation; ICP mass spectroscopy; Ultrafiltration; Loading; Morphology; Bacteria; Polyethersulfone-silver; Antibacterial agent; Enterobacteriaceae
• ISSN: 0011-9164; 1873-4464
• DOI: 10.1016/j.desal.2010.11.010

Polyethersulfone–silver composite membranes were fabricated via a simple phase inversion method by using silver nitrate (AgNO
3) as an antibacterial agent and polyvinylpyrollidone (PVP) of molecular weight 10,000, 40,000 and 360,000
Da as dispersant in the dope formulation. The effect of AgNO
3 loading on the resulting membrane was studied using field emission scanning electron microscope (FESEM), energy dispersive X-ray (EDX) and X-ray photoelectron spectroscopy (XPS) techniques. The silver loss during fabrication and pure water filtration was measured using inductive-coupled plasma mass spectrometer (ICP-MS). From XPS and EDX examinations, it was observed that the resulting membrane prepared from 2
wt.% AgNO
3 and PVP of 360,000
Da exhibited high concentration of Ag mainly due to the high Ag-particle entrapment in the membrane structure. The uniform distribution of Ag particles has contributed significantly to 100% inhibition against
Escherichia coli (
E. coli) growth within 24
h incubation. In addition, the results of pure water filtration test showed minimum silver loss during operation, indicating better stability of membrane produced in terms of Ag-entrapment in membrane structure. Based on the findings, it can be concluded that PES–silver composite membrane with PVP of 360,000
MW offers huge potential membrane for bacteria removal and disinfection.
► PVP in PES–Ag UF promotes higher Ag-entrapment on membrane matrices. ► Higher Ag concentration improves antibacterial activity with high Ag-leaching. ► The PVP 360,000
Da presence reduces Ag-leaching during fabrication and filtration. ► Membrane with 2
wt.% Ag and PVP 360,000
Da exhibits 100% inhibition against
Escherichia coli.