Synthesis and Optoelectronic Properties of Threaded BODIPYs

Synthesis and Optoelectronic Properties of Threaded BODIPYs

We report on the synthesis of two new threaded BODIPYs 5 and 6 in good yields using boron as a gathering atom and a macrocycle with a 2,2’‐biphenol unit. In addition to usual techniques, they were characterized by X‐ray crystallography. Their electrochemical and optical properties were investigated....

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Bibliographic Details
Published in:ChemistryOpen (Weinheim) Vol. 13; no. 11; pp. e202400196 - n/a
Main Authors: Hicguet, Matthieu, Mongin, Olivier, Leroux, Yann R., Roisnel, Thierry, Berrée, Fabienne, Trolez, Yann
Format: Journal Article
Language:English
Published: Germany John Wiley & Sons, Inc 01-11-2024
Wiley
Wiley-VCH
Subjects:
BODIPY
Boron
Chemical bonds
Chemical Sciences
Crystallography
fluorescence
Optical properties
Optoelectronics
Oxidation
Photoluminescence
Synthesis
fluorescence
boron
BODIPY
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Summary:We report on the synthesis of two new threaded BODIPYs 5 and 6 in good yields using boron as a gathering atom and a macrocycle with a 2,2’‐biphenol unit. In addition to usual techniques, they were characterized by X‐ray crystallography. Their electrochemical and optical properties were investigated. In particular, both compounds are highly emissive with photoluminescence quantum yields of 54 and 81 % respectively. In addition, they both show a high photostability. The synthesis of two new threaded BODIPYs in good yields using boron as a gathering atom is reported. In addition to usual techniques, they were characterized by X‐ray crystallography. Their electrochemical and optical properties were investigated. Both compounds are highly emissive with photoluminescence quantum yields up to 81 %.
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ISSN:2191-1363
2191-1363
DOI:10.1002/open.202400196