Adsorption Morphologies of Polyethylene Glycol and Cationic Surfactants in HCl-containing H2SO4 Aqueous Solutions

We characterized the adsorption morphologies of polyethylene glycol (PEG) and cationic surfactants on gold in H2SO4 aqueous solutions in the presence and absence of Cl− ions. The addition of Cl− ions resulted in the formation of globular aggregates on a smooth adsorption film for PEG, whereas in the...

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Published in:	Chemistry letters Vol. 49; no. 8; pp. 952 - 955
Main Authors:	Fukui, Takahiro, Kubota, Kenji, Tarutani, Yoshie, Akamatsu, Masaaki, Sakai, Kenichi, Sakai, Hideki
Format:	Journal Article
Language:	English
Published:	Tokyo The Chemical Society of Japan 05-08-2020 Chemical Society of Japan
Subjects:	Adsorption Aggregates Aqueous solutions Cations Cetyltrimethylammonium bromide Morphology Polyethylene glycol Sulfuric acid Surfactants Adsorption Atomic force microscopy Plating solution
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Abstract	We characterized the adsorption morphologies of polyethylene glycol (PEG) and cationic surfactants on gold in H2SO4 aqueous solutions in the presence and absence of Cl− ions. The addition of Cl− ions resulted in the formation of globular aggregates on a smooth adsorption film for PEG, whereas in the formation of wormlike adsorption aggregates for hexadecyltrimethylammonium bromide.
AbstractList	We characterized the adsorption morphologies of polyethylene glycol (PEG) and cationic surfactants on gold in H2SO4 aqueous solutions in the presence and absence of Cl− ions. The addition of Cl− ions resulted in the formation of globular aggregates on a smooth adsorption film for PEG, whereas in the formation of wormlike adsorption aggregates for hexadecyltrimethylammonium bromide.
Author	Kubota, Kenji Tarutani, Yoshie Akamatsu, Masaaki Sakai, Hideki Fukui, Takahiro Sakai, Kenichi
Author_xml	– sequence: 1 givenname: Takahiro surname: Fukui fullname: Fukui, Takahiro – sequence: 2 givenname: Kenji surname: Kubota fullname: Kubota, Kenji – sequence: 3 givenname: Yoshie surname: Tarutani fullname: Tarutani, Yoshie – sequence: 4 givenname: Masaaki surname: Akamatsu fullname: Akamatsu, Masaaki – sequence: 5 givenname: Kenichi surname: Sakai fullname: Sakai, Kenichi – sequence: 6 givenname: Hideki surname: Sakai fullname: Sakai, Hideki
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References	5T. Fukui, Y. Tarutani, K. Kubota, K. Nakaya, M. Akamatsu, K. Sakai, H. Sakai, J. Surf. Finish. Soc. Jpn. 2020, 71, 37. 10.4139/sfj.71.37 8M. Yokoi, S. Konishi, T. Hayashi, Electrochemistry 1984, 52, 218. 9J. N. Israelachvili, Intermolecular and Surface Forces. 3rd Edition, Academic Press, 2011, Chap. 13. 10K. E. Bremmell, G. J. Jameson, S. Biggs, Colloids Surf., A 1998, 139, 199. 10.1016/S0927-7757(98)00281-7 2J. J. Kelly, A. C. West, J. Electrochem. Soc. 1998, 145, 3472. 10.1149/1.1838829 7M. Tan, C. Guymon, D. R. Wheeler, J. N. Harb, J. Electrochem. Soc. 2007, 154, D78. 10.1149/1.2401057 1P. M. Vereecken, R. A. Binstead, H. Deligianni, P. C. Andricacos, IBM J. Res. Develop. 2005, 49, 3. 10.1147/rd.491.0003 6T. Fukui, Y. Tarutani, K. Kubota, M. Akamatsu, K. Sakai, H. Sakai, J. Surf. Finish. Soc. Jpn. 2020, 71, 356. 10.4139/sfj.71.356 3K. Kondo, T. Matsumoto, K. Watanabe, J. Electrochem. Soc. 2004, 151, C250. 10.1149/1.1649235 4K. Kubota, Y. Tarutani, K. Nakaya, K. Sakai, H. Sakai, J. Surf. Finish. Soc. Jpn. 2018, 69, 521. 10.4139/sfj.69.521
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SubjectTerms	Adsorption Aggregates Aqueous solutions Cations Cetyltrimethylammonium bromide Morphology Polyethylene glycol Sulfuric acid Surfactants
Title	Adsorption Morphologies of Polyethylene Glycol and Cationic Surfactants in HCl-containing H2SO4 Aqueous Solutions
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