Low temperature methane sensing by electrochemically grown and surface modified ZnO thin films

• Published in: Sensors and actuators. B, Chemical Vol. 135; no. 1; pp. 81 - 88
• Main Authors: Basu, P.K., Jana, S.K., Saha, H., Basu, S.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 10-12-2008
• Subjects: Electrochemical anodization; Low operating temperature; Methane; Nanocrystalline ZnO thin films; Nanocrystals; Operating temperature; Pd–Ag catalytic metal contact; Recovery time; Resistive and MIM sensors; Response time; Sensors; Surface modification; Thin films; Zinc oxide; Pd–Ag catalytic metal contact; Surface modification; Resistive and MIM sensors; Low operating temperature; Nanocrystalline ZnO thin films; Electrochemical anodization
• ISSN: 0925-4005; 1873-3077
• DOI: 10.1016/j.snb.2008.07.021

The functional characteristics of the planar resistive and MIM (metal-insulator-metal) sensors using electrochemically grown nanocrystalline–nanoporous ZnO thin films and surface modified by dipping in an aqueous solution of PdCl
2 were investigated for methane sensing. It was found that the operating temperature was substantially reduced to 70
°C and 100
°C for the two different configurations, respectively, after this interesting and somewhat novel surface modification step. A high purity Zn was anodized to produce ZnO thin films using a Pt cathode, a calomel reference electrode and a 0.3
M oxalic acid electrolyte. Pd–Ag (26%) was used as the catalytic metal contact to ZnO to fabricate a resistive and an MIM configuration. The response of the order of ∼48, a response time of ∼4.5
s and a recovery time of ∼22.7
s were obtained for the planar resistive structures, while the MIM structures showed a response of the order of ∼32, a response time ∼2.7
s and a recovery time of ∼16
s. The sensors were studied in the presence of 1% methane in nitrogen and in synthetic air in separate experiments. The performance was somewhat reduced in synthetic air for both the sensor structures while maintaining the optimum operating temperature the same. Both the sensors were stable in 1% methane in nitrogen as well as in 1% methane in synthetic air.