The effect of addition of different elastomers upon the crystalline nature of PP

Thermal and morphological studies have been performed on polymer blends based on ethylene–octene copolymer (PEE)/PP and ethylene–propylene–diene copolymer (EPDM)/PP. The thermal and morphological behavior of PEE, EPDM, PEE/PP, and EPDM/PP systems were analyzed by differential scanning calorimetry (D...

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Published in:	Journal of applied polymer science Vol. 81; no. 14; pp. 3530 - 3537
Main Authors:	Da Silva, Ana Lúcia N., Rocha, Marisa C. G., Lopes, Léa, Chagas, Beatriz S., Coutinho, Fernanda M. B.
Format:	Journal Article
Language:	English
Published:	New York John Wiley & Sons, Inc 29-09-2001 Wiley
Subjects:	Applied sciences Crystallization crystallization kinetics elastomers Exact sciences and technology Organic polymers Physicochemistry of polymers Properties and characterization Polymer blends Property composition relationship Propylene polymer Dispersion reinforced material Experimental study Heterogeneous mixture Structure composition relationship EPDM rubber Melt crystallization Spherulites Ethylene copolymer Kinetics Isothermal crystallization
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Abstract	Thermal and morphological studies have been performed on polymer blends based on ethylene–octene copolymer (PEE)/PP and ethylene–propylene–diene copolymer (EPDM)/PP. The thermal and morphological behavior of PEE, EPDM, PEE/PP, and EPDM/PP systems were analyzed by differential scanning calorimetry (DSC) and polarizing light microscopy, respectively. It was observed that the behaviors of crystallization kinetics of PEE/PP and EPDM/PP blends were similar. It was also observed that addition up to 10–20% (w/w) of elastomers resulted in increasing of spherulite size. The heat of fusion (ΔHf) and crystallinity degree of PEE/PP and EPDM/PP systems decreased when the elastomer contents were increased. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 3530–3537, 2001
AbstractList	Thermal and morphological studies have been performed on polymer blends based on ethylene–octene copolymer (PEE)/PP and ethylene–propylene–diene copolymer (EPDM)/PP. The thermal and morphological behavior of PEE, EPDM, PEE/PP, and EPDM/PP systems were analyzed by differential scanning calorimetry (DSC) and polarizing light microscopy, respectively. It was observed that the behaviors of crystallization kinetics of PEE/PP and EPDM/PP blends were similar. It was also observed that addition up to 10–20% (w/w) of elastomers resulted in increasing of spherulite size. The heat of fusion (ΔHf) and crystallinity degree of PEE/PP and EPDM/PP systems decreased when the elastomer contents were increased. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 3530–3537, 2001 Thermal and morphological studies have been performed on polymer blends based on ethylene-octene copolymer (PEE)/PP and ethylene-propylene-diene copolymer (EPDM)/PP. The thermal and morphological behavior of PEE, EPDM, PEE/PP, and EPDM/PP systems were analyzed by differential scanning calorimetry (DSC) and polarizing light microscopy, respectively. It was observed that the behaviors of crystallization kinetics of PEE/PP and EPDM/PP blends were similar. It was also observed that addition up to 10-20% (w/w) of elastomers resulted in increasing of spherulite size. The heat of fusion ( Delta H sub f ) and crystallinity degree of PEE/PP and EPDM/PP systems decreased when the elastomer contents were increased. Thermal and morphological studies have been performed on polymer blends based on ethylene–octene copolymer (PEE)/PP and ethylene–propylene–diene copolymer (EPDM)/PP. The thermal and morphological behavior of PEE, EPDM, PEE/PP, and EPDM/PP systems were analyzed by differential scanning calorimetry (DSC) and polarizing light microscopy, respectively. It was observed that the behaviors of crystallization kinetics of PEE/PP and EPDM/PP blends were similar. It was also observed that addition up to 10–20% (w/w) of elastomers resulted in increasing of spherulite size. The heat of fusion (Δ H f ) and crystallinity degree of PEE/PP and EPDM/PP systems decreased when the elastomer contents were increased. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 3530–3537, 2001
Author	Coutinho, Fernanda M. B. Rocha, Marisa C. G. Chagas, Beatriz S. Lopes, Léa Da Silva, Ana Lúcia N.
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Snippet	Thermal and morphological studies have been performed on polymer blends based on ethylene–octene copolymer (PEE)/PP and ethylene–propylene–diene copolymer... Thermal and morphological studies have been performed on polymer blends based on ethylene-octene copolymer (PEE)/PP and ethylene-propylene-diene copolymer...
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SubjectTerms	Applied sciences Crystallization crystallization kinetics elastomers Exact sciences and technology Organic polymers Physicochemistry of polymers Properties and characterization
Title	The effect of addition of different elastomers upon the crystalline nature of PP
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