Use of rice husk in waste cooking oil pretreatment

• Published in: Environmental technology Vol. 40; no. 5; pp. 594 - 604
• Main Authors: Schneider, Lara Talita, Bonassa, Gabriela, Alves, Helton José, Meier, Thompson Ricardo Weiser, Frigo, Elisandro Pires, Teleken, Joel Gustavo
• Format: Journal Article
• Language: English
• Published: England Taylor & Francis 23-02-2019; Taylor & Francis Ltd
• Subjects: Acidity; Activated carbon; Adsorbents; Adsorption; Agricultural wastes; biodiesel; Biodiesel fuels; Biofuels; Brazil; Carbon; Cooking; Cooking oils; Electron microscopes; Fatty acids; Industrial Waste; Industrial wastes; Oil wastes; Oryza; Pretreatment; Rice; rice husk; Scanning electron microscopy; Spectroscopy; waste cooking oil; Waste treatment; X-ray diffraction; Brazil; activated carbon; Adsorption; waste cooking oil; rice husk; biodiesel
• ISSN: 0959-3330; 1479-487X
• DOI: 10.1080/09593330.2017.1397772

Since industrial wastes are increasing, the development of studies to find ways for their use is urgent. Waste cooking oil is an important source for the production of biodiesel, one of the main biofuels in Brazil. However, during cooking, the oil undergoes conditions that change its properties and decrease its quality, such as its acidity value. Current research treats waste cooking oil by the adsorption process using rice husk, an agro-industrial waste, and activated carbon to compare results. The potential of the adsorbents to remove free fatty acids in waste cooking oil has been investigated by the batch technique, evaluating different operating conditions of temperature, adsorbent mass and agitation. Adsorbents were characterized by nitrogen physisorption, scanning electron microscope, energy-dispersive spectroscopy and X-ray diffraction. The maximum result obtained for activated carbon at acidity reduction was 63%, using 22.4°C, 169.64 rpm and 3.39 g of adsorbent mass. Already, using the rice husk the percentage of removal was the same, 63% using 22.4°C, 80.36 rpm and 1.61 g of adsorbent, however in shorter times. The results prove that the application of the rice husk for this purpose is advantageous, for being a low-cost material, available on a large scale and that provide results similar to activated carbon.