Scanning probe microscopy tip–sample interactions in primary alcohols of varying chain length
Interactions between chemically functionalized tips and substrates in scanning probe microscopy are usually investigated by utilizing an intervening liquid medium, however the results may be influenced in various ways by the medium itself. In this study the chain length of a series of primary alcoho...
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| Published in: | Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films Vol. 18; no. 4; pp. 1345 - 1348 |
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| Main Authors: | , , , |
| Format: | Conference Proceeding Journal Article |
| Language: | English |
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01-07-2000
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| Abstract | Interactions between chemically functionalized tips and substrates in scanning probe microscopy are usually investigated by utilizing an intervening liquid medium, however the results may be influenced in various ways by the medium itself. In this study the chain length of a series of primary alcohols is shown to affect adhesion measurements. The measurements are performed between a layer of phosphonic acid adsorbed on an aluminum substrate and an aluminum-coated silicon nitride tip. The phosphonic acid/oxidized aluminum system has been characterized previously by vibrational spectroscopy and forms a stable, well-defined system for studying the effects of the medium on adhesion. Adhesion forces between the tip and sample are observed to decrease as the alcohol chain length is increased, and to increase as the dielectric constant of the medium increases. The experimental results of this study cannot be explained by the use of a single model for the role of solvents in force-curve measurements, indicating that a combination of mechanisms may be responsible for adhesion in this system. |
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| AbstractList | Interactions between chemically functionalized tips and substrates in scanning probe microscopy are usually investigated by utilizing an intervening liquid medium, however the results may be influenced in various ways by the medium itself. In this study the chain length of a series of primary alcohols is shown to affect adhesion measurements. The measurements are performed between a layer of phosphonic acid adsorbed on an aluminum substrate and an aluminum-coated silicon nitride tip. The phosphonic acid/oxidized aluminum system has been characterized previously by vibrational spectroscopy and forms a stable, well-defined system for studying the effects of the medium on adhesion. Adhesion forces between the tip and sample are observed to decrease as the alcohol chain length is increased, and to increase as the dielectric constant of the medium increases. The experimental results of this study cannot be explained by the use of a single model for the role of solvents in force-curve measurements, indicating that a combination of mechanisms may be responsible for adhesion in this system. The impact of alcohol solvent on adhesion measurements using atomic force microscopy (AFM) force-distance data was examined. The pull-off force between a SiN AFM tip coated with Al sub(2)O sub(3) and an Al sub(2)O sub(3) substrate covered with phosphonic acid was measured in methanol, ethanol, 1-butanol, 1-pentanol, 1-hexanol, 1-octanol and 1-nonanol. The permittivity of the medium and the average rupture force were reduced by increasing alkyl chain length. |
| Author | Ralich, R. M. Ramsier, R. D. Henriksen, P. N. Wu, Y. |
| Author_xml | – sequence: 1 givenname: R. M. surname: Ralich fullname: Ralich, R. M. organization: Department of Physics, University of Akron, Akron, Ohio 44325-4001 – sequence: 2 givenname: Y. surname: Wu fullname: Wu, Y. organization: Department of Physics, University of Akron, Akron, Ohio 44325-4001 – sequence: 3 givenname: R. D. surname: Ramsier fullname: Ramsier, R. D. organization: Department of Physics, University of Akron, Akron, Ohio 44325-4001 – sequence: 4 givenname: P. N. surname: Henriksen fullname: Henriksen, P. N. organization: Department of Physics, University of Akron, Akron, Ohio 44325-4001 |
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| Cites_doi | 10.1016/S0167-5729(97)80003-9 10.1063/1.1146018 10.1021/la9800304 10.1006/jtbi.1998.0774 10.1021/la9620869 10.1021/la980344r 10.1021/la981094h 10.1021/la980683k 10.1016/0039-6028(88)90195-1 10.1021/la981003g 10.1021/ja961295c 10.1006/jcis.1999.6139 10.1103/PhysRevB.45.11226 10.1007/BF00585742 10.1063/1.1143970 |
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| Snippet | Interactions between chemically functionalized tips and substrates in scanning probe microscopy are usually investigated by utilizing an intervening liquid... The impact of alcohol solvent on adhesion measurements using atomic force microscopy (AFM) force-distance data was examined. The pull-off force between a SiN... |
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| StartPage | 1345 |
| SubjectTerms | Adhesion Alumina Composition effects Ethanol Methanol Molecular structure Organic solvents Permittivity Silicon nitride |
| Title | Scanning probe microscopy tip–sample interactions in primary alcohols of varying chain length |
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